Inorganic-organic hybrid membranes with anhydrous proton conduction prepared from tetramethoxysilane/methyl-trimethoxysilane/trimethylphosphate and 1-ethyl-3-methylimidazolium-bis (trifluoromethanesulfonyl) imide for H2/O2 fuel cells

Anhydrous proton-conducting inorganic-organic hybrid membranes were prepared by sol-gel process with tetramethoxysilane/methyl-trimethoxysilane/trimethylphosphate and 1-ethyl-3-methylimidazolium-bis (trifluoromethanesulfonyl) imide [EMI][TFSI] ionic liquid as precursors. These hybrid membranes were studied with respect to their structural, thermal, proton conductivity, and hydrogen permeability properties. The Fourier transform infrared spectroscopy (FT-IR) and ³¹P, ¹H, and ¹³C nuclear magnetic resonance (NMR) measurements have shown good chemical stability, and complexation of PO(OCH₃)₃ with [EMI][TFSI] ionic liquid in the studied hybrid membranes. Thermal analysis including TG and DTA confirmed that the membranes were thermally stable up to 330 °C. Thermal stability of the hybrid membranes was significantly enhanced by the presence of inorganic SiO₂ framework and high stability of [TFSI] anion. The effect of [EMI][TFSI] ionic liquid addition on the microstructure of the membranes was studied by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX) micrographs and no phase separation at the surfaces of the prepared membranes was observed and also homogeneous distribution of all elements was confirmed. Proton conductivity of all the prepared membranes was measured from −20 °C to 150 °C, and high conductivity of 5.4 × 10⁻³ S/cm was obtained for 40 wt% [EMI][TFSI] doped 40TMOS-50MTMOS-10PO(OCH₃)₃ (mol%) hybrid membrane, at 150 °C under anhydrous conditions. The hydrogen permeability was found to decrease from 1.61 × 10⁻¹¹ to 1.39 × 10⁻¹² mol/cm s Pa for 40 wt% [EMI][TFSI] doped hybrid membrane as the temperature increases from 20 °C to 150 °C. For 40 wt% [EMI][TFSI] doped hybrid membrane, membrane electrode assemblies were prepared and a maximum power density value of 0.22 mW/cm² at 0.47 mA/cm² as well as a current density of 0.76 mA/cm² were obtained at 150 °C under non-humidified conditions when utilized in a H₂/O₂ fuel cell.     

Encapsulation of Single Plasmonic Nanoparticles within ZIF‐8 and SERS Analysis of the MOF Flexibility

Hybrid nanostructures composed of metal nanoparticles and metal‐organic frameworks (MOFs) have recently received increasing attention toward various applications due to the combination of optical and catalytic properties of nanometals with the large internal surface area, tunable crystal porosity and unique chemical properties of MOFs. Encapsulation of metal nanoparticles of well‐defined shapes into porous MOFs in a core–shell type configuration can thus lead to enhanced stability and selectivity in applications such as sensing or catalysis. In this study, the encapsulation of single noble metal nanoparticles with arbitrary shapes within zeolitic imidazolate‐based metal organic frameworks (ZIF‐8) is demonstrated. The synthetic strategy is based on the enhanced interaction between ZIF‐8 nanocrystals and metal nanoparticle surfaces covered by quaternary ammonium surfactants. High resolution electron microscopy and tomography confirm a complete core–shell morphology. Such a well‐defined morphology allowed us to study the transport of guest molecules through the ZIF‐8 porous shell by means of surface‐enhanced Raman scattering by the metal cores. The results demonstrate that even molecules larger than the ZIF‐8 aperture and pore size may be able to diffuse through the framework and reach the metal core.     

Photochromic films prepared by solid state processing of disentangled ultrahigh molecular weight polyethylene and photochromic dyes composites

Disentangled ultrahigh molecular weight polyethylene (DPE) is a special grade of polyethylene (molecular weight, >10⁶ Da) which can be processed by an environment friendly solid state process on counter rotating two roll mill (TRM) below the melt temperature of the polymer. This unique processing property of DPE was utilized to develop smart DPE photochromic films. Photochromic dye like 'Spirooxazine' or 'Spiropyran' has been mixed with DPE resin powder prior to film formation without altering the DPE properties. These films could change their optical appearances on exposure to UV-light of wavelength 365 nm and the color change phenomenon of the films could also be replicated by sunlight. The color change observed is found to be reversible, that is, films could return to colorless form either spontaneously in dark or by thermal stimuli. Such smart property was imparted to DPE even at very low concentration (2,000 ppm) of photochromic dyes. Spectrophotometric studies were used to measure the rate of forward reaction with UV radiation and the rate of backward reaction in dark. In fact, DPE powder and photochromic dye composite was used to produce the compression molded disc to understand the color change phenomena. Moreover, it was observed that the photo-degradation rate of dye, could be retarded ~30% by using amphoteric Zinc phthalate salt. TGA and DSC studies confirmed that the characteristics of DPE film remained almost unaltered even after with preparation of film photochromic dyes.     

Statistical Delay Fault Coverage Estimation for Synchronous Sequential Circuits

We present a technique to statistically estimate path-delay fault coverage for synchronous sequential circuits. We perform fault-free simulation using a multivalue algebra and accumulate signal transition statistics, from which we calculate controllabilities of all signals and sensitization probabilities for all gates and flip-flops. We use a rated clock testing model where all time frames operate at the rated clock. We obtain path observabilities either by enumerating paths in the all-paths method, or by a nonenumerative method considering only the longest paths. The path-delay fault detectability is the product of observabilities of signals on paths from primary inputs (PIs) or pseudo-primary inputs (PPIs) to primary outputs (POs) or pseudo-primary outputs (PPOs), and the controllability on the corresponding PI or PPI. We use the optimistic update rule of Bose et al. for updating latches during logic simulation. When compared with exact fault simulation, the average absolute deviation in our statistical fault coverage estimation technique is 1.23% and the very worst absolute deviation was 6.59%. On average, our method accelerates delay fault coverage computation four times over an exact path delay fault simulator.     

Growth and thermal studies of SnSe single crystals

Single crystals of SnSe have been grown by a direct vapour transport (DVT) technique. The confirmation of single crystallinity and lattice parameter determination of the grown crystals have been made by using electron and X-ray diffraction techniques respectively. The thermal analysis of the crystals has been studied by the well known TGA and DTA techniques. The results obtained during the analysis showed the stability of SnSe phase at higher temperatures. The implications of the results have been discussed.     

Three dimensional flow field due to a vortex and source line spanning an annulus

A theoretical investigation of the three dimensional potential flow field due to a vortex and source line spanning an annulus is carried out in this paper. The three dimensional effects due to finite radius hub and annulus walls are found to be appreciable, especially for a low hub/tip ratio configuration. The discrepancy between the two and three dimensional solutions are found to be large near the hub, moderate at the tip and negligibly small at the mid radius.     

Changes in fatty acids during maturation of Coriandrum sativum seeds

Changes in fatty acids were studied during maturation ofCoriandrum sativumseeds. The seeds matured in 50 days after flowering. Lipid synthesis proceeded at a steady rate up to 40 days after flowering. Reductive ozonolysis of the monoenes followed by gas liquid Chromatographic analysis of the aldehydic fragments as dioxolanes of 1,3-propanediol was employed to estimate petroselenate (octadeca-cis-6-enoate) in the presence of oleate (octadeca-cis-9-enoate). Petroselenic acid was the major fatty acid at all stages.     

Changes in the coliform populations of the shoreline waters,Shediac, New Brunswick

This paper presents the results of a survey of the changes in the coliform populations of the shoreline waters, Shediac, New Brunswick. The sanitary quality of these waters showed more than 1000 organisms/100 ml of coliforms thereby indicating post-winter and pre-summer contamination of these waters. The membrane filter method is found to be equally efficient to that of the MPN method. The sanitary quality of these waters in relation to other ecological parameters like temperature, pH salinity and availability of oxygen are considered.