Sensory evaluation of drinking water by consumer panels

The human senses play an important role in assessing the quality of food and of the environment. Particularly the chemical senses of taste and smell determine the pleasantness of foods and drinks and may provide a warning mechanism for the presence of more or less toxic contaminants. Even after the recent rapid development of powerful analytical techniques the human nose can easily detect trace amounts of chemicals at levels manytimes lower than the analytical detection limits.Although taste and odour assessment of drinking water has been practized inmany waterworks laboratories by small panels, relatively unreliable results were obtained and such sensory data played up till now only a minor role in the management of the water treatment plant. More sophisticated and reliable methods for sensory water quality evaluation are discussed. Special attention is given to the characteristics of the human senses of taste and smell, to which the methodology of sensory assessment should be better adapted. High numbers of observations on a sample are generally needed, for which purpose the use of large panels has to be realized. In this respect the help of large consumer panels is an alternative for the presently often used small laboratory groups. As an example the preliminary results of a large ongoing experiment of sensory water quality assessment by 2 consumer panels of 100 persons each in the Rotterdam area are discussed. Drinking water quality is judged at the consumer homes every week. The experiment started September 1979 and will be continued for one year.     

The direct measurement of ppm levels of uranium in soils using high-resolution Ge(Li) gamma-ray spectroscopy

The direct determination of ²³⁸U in various soil samples was done by measuring the 63.3-keV transition from the decay of the first daughter ²³⁴Th. Potential errors resulting from the chemical non-equilibrium of ²³⁸U with its daughters are thus avoided. The method sensitivity is 1 ppm compared to the 35 ppm obtainable by employing the 1001-keV gamma ray. A Ge(Li) gamma-ray spectrometer is the only analytical tool required. Examples are offered that demonstrate the usefulness of the technique for routine, inexpensive environmental monitoring of uranium. The technique also has the capability of providing information on the ²³⁸U/²³⁵U isotopic ratio.     

Online Documentation for Engineering Software: A Hypertext Application

Abstract: This article describes the use of 'hypertext' as a means to document engineering software online. An extensive hypertext document can be built with relative ease using an authoring tool. Hypertext documents enhance the learning process through the association of facts. The user has the freedom to arrange his/her own study sequence in a particular session. The article provides a brief introduction to the hypertext technology and authoring tools, and describes a Mohr's Circle program, which has been developed to explore the use of hypertext for online users' manuals. The strengths and weaknesses of the software tool, KnowledgePro, as well as the development techniques, are discussed.     

Hybrid reactor for priority pollutant-trichloroethylene removal

The present study was initiated to explore the potential of a hybrid biological reactor, combining trickling filter (TF) and activated sludge process (ASP), to treat wastewater containing trichloroethylene (TCE) at ambient temperature at different hydraulic retention time (HRT). The biofilm acclimation was achieved in 55-60 days with gradual increase in TCE concentration from 1 mg/l to 100 mg/l with a parallel increase in the concentration of substrate sodium acetate and other nutrients. COD and TCE concentration were taken as prime parameters for monitoring the growth of biofilm. During acclimation COD removal varied between 54.6-97.5% while TCE was removed 72.6-99.9%. HRT study was performed after acclimation. The removal efficiency increased with decreasing flow rate with maximum TCE removal (99.99%) at 6 l/d corresponding to an HRT of 28 h (TF 18 h + ASP 10 h). This was followed by a C:N:P ratio study. A ratio of 100:20:1 led to the sustenance of maximum TCE removal. Maximum TCE removal (99.99%) was observed at a substrate:cosubstrate ratio of 100:1. A pH of 7.4 +/- 0.2 was found to be optimum for degradation. Finally, volatilization losses were estimated to be 18.5%. A mass balance gave an efficiency of 81.51% for biological removal of TCE.     

Treatment of poultry manure wastewater using a rotating biological contactor

A pilot scale, six stage rotating biological contactor was used to evaluate the feasibility of this process for the stabilization of liquid animal manures. Total disc surface area was approx. 16.7 m². Treatment efficiencies were determined at various waste strengths and influent flow rates.With loading rates of 14.7–322 g m⁻² day⁻¹, the average COD reduction was 61%. With loading rates of 4.88-24.4 g m⁻² day⁻¹, the average BOD₅ reduction was 87%. Total nitrogen removal averaged approximately 30% for the entire study. Mixed liquor oxygen uptake rates were generally in excess of 80 mg 1⁻¹ h⁻¹.Clarified effluent was non-odorous and suitable to be reused for manure flushing or spray irrigation. Treatment was not sufficient to permit effluent discharge to surface waters.     

Haloacetic acids and trihalomethanes in finished drinking waters from heterogeneous sources

Trihalomethanes (THM) and haloacetic acids (HAA) are the most frequent chlorination by-products (CBP) in finished drinking waters. Traditionally, THM have been used as surrogates for CBP although the quantitative association between THM and other CBP is not well established. This problem is addressed in the present study from the analysis of THM and HAA in drinking water samples from four Spanish regions, representing areas with very different CBP composition, e.g. between 86 and 8.0 microg/l of THM and 50-3.0 microg/l of HAA.The resulting dataset exhibit a statistically significant correlation between total THM and HAA (Pearson's correlation coefficient, r(p)=0.815,p<0.0005). Furthermore, specific HAA are highly correlated with specific THM or their combinations. Accordingly, multivariate linear regression analysis of the concentrations observed show that the levels in total and specific HAA can be predicted from the THM content. These results are relevant for epidemiological studies on health effects from CBP exposure since they usually involve comparison of populations consuming waters of very distinct quality.     

A new mathematical model to evaluate simazine removal in three different immobilized-biomass reactors

A new mathematical model based on the cinetical Langmuir equation is developed to interpret and predict the effectiveness of simazine (SZ) removal in immobilized-biomass reactor (IBR), to consider herbicide-support affinity (Cx), and herbicide-cell affinity (Cy). Three solid supports: sepiolite monolith, granular sepiolite, and alginate were used in pilot-scale reactors that were inoculated with Klebsiella planticola DSZ. The abiotic process was analysed by measuring the SZ sorption capacity of the reactor supports. Sepiolite monolith showed the maximum value for herbicide-support affinity (28.02+/-0.9%). The effectiveness of the biotic process was estimated considering the formation of biomass and SZ biodegradation. Granular sepiolite showed either higher affinity with SZ and viability rate (0.90) throughout the process, and SZ removal rate was 3.39+/-0.06 mg/h. The mathematical model presented in this paper provides useful insights into the interpretation of experimental data as well as prediction for the implementation of biological reactors.     

The effect of depositional history on contaminated bed sediment stability

Experiments were conducted in an annular flume using a commercially available kaolinite clay as well as contaminated bed sediment from Hamilton Harbour (Ontario) to assess their stability against erosion. Critical shear stress for erosion was measured under different conditions of bed formation (quiescently deposited beds and shear deposited beds) as well as with and without the presence of a biostabilized bed. Results suggest that a biostabilized bed and a bed formed under a flowing condition, similar to a river scenario, will be more resistant against erosion than will a non-biostabilized bed and a bed formed under quiescent conditions. Up to three cycles of erosion and flocculation/deposition were observed to occur within one experiment. These results suggest that the depositional history and biostabilization of river bed sediments need to be seriously considered within sediment and contaminant transport models if meaningful estimates of sediment and contaminant source, fate and effect are to be generated and used for the management of our aquatic ecosystems.     

Analysis of point load test as a method for preliminary geotechnical classification of rocks

This paper deals with the analysis of the point load compression test made on irregular-shaped rock fragments, proposed in the late 50’s by Protodiakonov. An ample revision of the literature on the subject has been made, and a series of tests, using seven different types of rock materials, has been developed. The results obtained from these tests showed that parameters generally used in literature to relate the unconfined compressive (or tensile) strength of materials, resulting from point load tests, can lead to scattered results, due mainly to the scale effect, of great evidence in such tests. It seems possible to obtain compressive (and tensile) strength of rocks, if the ratio between failure load and the distance between load application poins, with a 3/2 exponent, is considered, in field work, as being the "point load strength index".

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Resume L’article présente une analyse critique de l’essai de compression sur échantillons irréguliers de roche, proposé par Protodiakonov vers la fin des années 50. Tout d’abord on a fait une révision de la littérature disponible sur le sujet et, après, une série d’essais sur sept types différents de matériaux. Les résultats obtenus ont montré que les paramètres plus utilisés, dans la littérature, pour définir la résistance à la compression (ou traction) des roches, d’après les essais ponctuels, peuvent provoquer une dispersion très importante des résultats. Cependant, il nous semble valable de suggérer la possibilité de déterminer, sur le chantier, la résistance à la compression (ou traction) des roches, si l’on considère le quotient entre la charge de rupture et la distance entre les deux points d’application de cette charge, le dénominateur à la puissance 3/2, comme "l’indice de charge ponctuelle".