Catalytic activities and properties of mesoporous sulfated Al2O3–ZrO2

Mesoporous sulfated Al₂O₃–ZrO₂ (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher Al₂O₃ content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), ²⁷Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed desorption of ammonia (NH₃-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al₂O₃–ZrO₂ samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed reactions.     

Kinetics of epoxy resins formation from bisphenol-A,bisphenol-S,and epichlorohydrin

The kinetics of formation of epoxy resins derived from bisphenol-A, bisphenol-S, and epichlorohydrin under stoichiometric conditions was considered. The kinetics of reaction was studied by taking into account the consumption of the added alkali and epoxide value of epoxide oligomers. The obtained results satisfactorily explained that the reactivity of bisphenol-A with epichlorohydrin is higher than that of bisphenol-S, the rate of dehydrochlorination of chlorohydrin ether in the presence of alkali and water is much higher than that of the rate of condensation of phenolic hydroxyl group with epichlorohydrin. The apparent reaction order of phenolic groups with epichlorohydrin and terminal epoxide group in the oligomer are all second order. The rate constants and activation energy were determined. The results are discussed. © 1993 John Wiley & Sons, Inc.     

乳白玻璃条纹解决方案

对乳白玻璃瓶表面产生条纹的原因进行分析,通过耐火材料选用、稳定熔制工艺、工作池中层取料和供料道加搅拌的方法消除条纹缺陷。     

Preparation and Photoluminescence of Partially Filled ZnO Microtubes Using Block Copolymers

Partially filled ZnO microtubes were synthesized in large scale using block copolymers. The growth mechanism of this unique construction is proposed on the basis of adsorption of block copolymers on {0002} plane of wurtzite ZnO. The photoluminescence property of these unique ZnO microtubes is also studied using a Xe lamp as the excitation source at room temperature. Blue emission band at 425 nm is a much stronger ultraviolet emission band, which is due to laminar structure of ZnO microtubes.     

Formation Mechanisms of Platelet Sr3Ti2O7 Crystals Synthesized by the Molten Salt Synthesis Method

The molten salt synthesis (MSS) method is utilized to synthesize the anisotropic platelet Sr₃Ti₂O₇ (S3T2) single-crystal particles. The aim of this study is to identify the essence of platelet Sr₃Ti₂O₇ crystal growth and guide the synthesis of anisotropic platelet SrTiO₃ crystals as well as various technologically important materials. Based on the results of X-ray diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy, the formation mechanism of platelet Sr₃Ti₂O₇ crystals conforms to a nucleation–structure rearrangement–dissolution–diffusion in situ epitaxial growth mechanism model. First, SrCO₃ reacts with TiO₂ to form submicrometer SrTiO₃ nuclei. Then, most of the nuclei surrounded by salt ions aggregate and rearrange to form a large SrTiO₃ matrix. The structural rearrangement and the subsequent in situ epitaxial growth processes control the morphology, composition, and size of the final Sr₃Ti₂O₇ crystals. In the synthesis process, the conversion between SrTiO₃ and Sr₃Ti₂O₇ is as follows: and the crystallographic orientation relationship between Sr₃Ti₂O₇ and SrTiO₃ in the interface is (100)_S3T2//{100}_ST, (010)_S3T2//{010}_ST, and (001)_S3T2//{001}_ST.     

现场总线技术在电力自动化中的应用

现场总线(Fieldbus)是当前自动化领域的热门话题，被誉为自动化领域的计算机局域网。信息技术的飞速发展．引起了自动化系统结构的变革，随着工业电网的日益复杂，人们对电网的安全要求也越来越高。现场总线控制技术作为一门新兴的控制技术必将取代过去的控制方式而应用在电力自动化中。     

累托石矿物提纯工艺探讨

以B03作分散剂,对湖北省钟祥县杨榨累托石粘土矿物进行了机械搅拌擦洗,使累托石矿物微粒较充分地分散解离,然后通过离心力场的作用,使累托石与水云母、叶腊石、绿泥石、石英等脉石矿物分离,累托石精矿纯度达90％左右,B03的使用为工业生产高纯累托石产品奠定了基础。     

国内外型焦生产工艺及发展前景

介绍了国内外型焦技术的生产工艺、型煤碳化的过程和影响因素,以及国内目前几种碳化窑炉,通过对型焦和焦炭的对比分析,指出洁净型焦生产技术的优势必然会使它在未来具有巨大的发展空间。     

Fabrication and amplification of Rhodamine B‐doped step‐index polymer optical fiber

A step‐index polymer optical fiber (SI POF) containing Rhodamine B in poly(methyl methacrylate) (PMMA) has been fabricated by a preform technique. Fluorescence of different fiber lengths were observed and discussed. A high gain (23 dB) for a SI POF with 60‐cm length, 400‐μm diameter was obtained. The Rhodamine B content of the doped SI POF is 5 ppm‐wt. The signal wavelength providing the highest gain for a 60 cm SI POF is around 630 nm, and the optimum fiber length is about 60 cm at 10 kW launched pump power. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 681–685, 2004     

改性活性炭的表面特性及其对苯酚的吸附性能

研究了表面改性对活性炭吸附苯酚性能的影响。研究发现,硫酸氧化可增加活性炭表面酸性基团的含量,提高了活性炭的表面亲水性,降低pHPZC值,因而对吸附水中的苯酚的性能产生明显影响,降低了对苯酚的吸附。