无机超细粉体改性锂离子电池隔膜的研究进展

综述了近年来无机超细粉体改性锂离子电池隔膜的研究进展,首先介绍了已在锂电隔膜改性上商业应用的Al₂O₃和AlOOH对传统聚烯烃膜和新型静电纺丝膜的改性方法和改性效果,随后又对常规无机材料TiO₂和SiO₂粉体对锂电隔膜的改性进行了叙述,最后对BN等非常规隔膜改性无机材料进行了简介;总结和讨论了无机材料改性后隔膜的组分、结构和性能对锂离子电池综合性能的影响,并对其无机材料改性锂电池隔膜的未来发展趋势进行了展望。     

煤粉炉粉煤灰提取氧化铝活化技术研究进展

介绍了近年来采用煤粉炉粉煤灰作为原料制备氧化铝的预处理活化工艺技术,指出了粉磨法、硫酸法、氯化钙法、铵盐法、碳酸盐法、氟化盐法、物理-化学联合活化法的优缺点及在工程转化过程中需重点关注的环节。虽然部分工艺技术实现了工业化,但因成本高等因素导致项目关停,建议粉煤灰综合利用研究方向应以工程转化难点问题为导向,理论研究与工程设计相结合,逐步探索出一条经济效益好、安全环保的粉煤灰制备氧化铝工业化路线。     

Effect of Heat Treatment on Microstructure and Mechanical Properties of Extruded PM Ti–6Al–4V Alloy With Deformation Flowlines

Metallurgical and Materials Transactions A - Two heat treatments, namely 955°C/2h/AC (AC = air cooling) and 955°C/4h/FC (FC = furnace cooling), were carried out on...     

An integrated size and roundness adaptive control system for the plunge grinding process

A time variant, roundness based adaptive size and roundness control system is presented for the plunge grinding process which avoids the need for a large data processing capacity and compares favourably in performance with the large and expensive control system previously developed and therefore improves the prospect of industrial use. The non-linear control functions and adaptive model are presented and analysed. The hardware of the integrated, low cost system and the software algorithms used to reduce the computational power requirements are discussed and the results of grinding experiments are presented.     

1 500 mm x230 mm板坯结晶器液面波动与卷渣行为水力学模型试验和应用

基于相似理论,以钢厂1 500 mmx230 mm板坯结晶器为原型建立1 ：2的结晶器水力学模型。结果 表明,吹气量一定时,水口中心处到窄边的液面波动先增大后减小,吹气量大于0. 8 lymin时,开始发生卷渣现象, 并且结晶器内的气泡数量变多。浸人深度的增加使液面波动减弱,浸入深度在65 - 95 mm时对卷渣影响的效果不 显著;拉速增加使流股的冲击深度增大,拉速大于LI m/min时有大渣滴被卷入;当结晶器的拉速为1.0 ~ 1.1 m/min, 吹气量为0.6~0.8 I/min,浸入深度为75 - 85 mm时较合理。C45E钢生产实践表明,当拉速由0.9-1.2 m/min调整 至1.0 ~ 1.1 m/min,浸入深度由130 ~ 190 mm改进为150 ~ 170 mm时,铸坯缺陷率由6%降至1.9%。     

Mo的替代对FeNbBCu软磁纳米晶合金磁谱的影响

本文研究了Fe82Nb7-xMoxB10Cu1(x=0,1,3,5）系列纲伙晶软磁合金中Mo的含量对磁导率谱（频率范围1kHz-1MHz)的影响，并用畴壁钉扎理论进行了解释，在磁谱中观测到随着Mo含量的增加，弛豫频率线性地上升，μ′随外加磁场幅度变化曲线表明其原因在于Mo的替代导致了钉扎场的增强。     

水量对锐钛矿溶胶制备、结构及光催化性能的影响

选择“钛酸丁酯-水-乙醇-盐酸”的溶胶．凝胶反应体系，考察反应物水的用量变化对反应过程、溶胶结构和光催化性能的影响，并获得了含有锐钛矿晶体、具有光催化性能的氧化钛溶胶。钛酸丁酯与水的摩尔比为1：2、1：4、1：8时，会逐渐形成凝胶，溶胶常温干燥后的粉体呈无定型结构，透射电镜中只能观察到细小的成膜粒子，溶胶不能使罗丹明B溶液分解褪色。钛酸丁酯与水的摩尔比为1：40、1：100、1：200时，钛酸丁酯发生充分水解，有可能形成稳定的溶胶；溶胶常温干燥后的粉体呈锐钛矿晶型，且结晶强度随水的用量的增加而增强；透射电镜中可观察到松散的团聚体、初显正方形较为紧密的结晶体和致密规则的正方形锐钛矿晶体；各溶胶均可催化降解罗丹明B使其褪色。     

3Cr2W8V钢锻件表面裂纹的成因及预防措施

通过对难变形钢3Cr2W8V进行实验,证明了合理地选择锻造工艺参数,也是解决表面裂纹的重要途径之一。     

MICROSTRUCTURE AND PROPERTIES OF C-Cu NANOSTRUCTURE THIN FILM

Nanostructured C-Cu thin films were deposited by reactive sputtering method and co-sputtering method. The relationships between microstructures, properties, and depo-sition parameters were studied and the results obtained from TEM, AFM, and XPS.indicate that the thin films are nanostructural, and have good in-depth uniformity. Theselected area electron diffraction (SAED) found that the nanosize Cu particles havethe fcc structure and the others are amorphous carbon or nanocrystallized graphiticcarbon. The peak positions of the Cu and C in XPS indicate them to be at the ele-mental state. In the IR transmission spectrum, diamond two-phonon absorption andgraphite Raman peaks were observed, which suggests microcrystal diamond particlesand graphite components exist in the C-Cu film. The higher electrical resistivity wasobtained.     

MICROSCOPIC STUDY ON SLAGGED HIGH-ALUMINA ARC FURNACE ROOF BRICKS

本文汇集1957年以来某些电炉炉顶使用后高铝砖的显微镜观察工作,砖体主要受MgO,CaO和铁氧化物侵蚀.MgO来源于补炉镁砂和镁质炉墙在高温下的冲蚀和挥发,X射线和显微镜分析证实渣蚀带一些区域内存在粒状和针状方镁石晶体.存在铁氧化物时,基本上吸附在渣蚀带表面,形成有两个尖晶石固溶体〔(MF’)A和(F’M)F〕系列的矿物共生组合,当不存在铁氧化物时,在渣蚀带生成纯MA.其它平衡相有钙镁橄榄石和钙长石.在渣蚀带内层,反应产物为六铝酸钙和钙铝黄长石.