Improved chemical stability and proton selectivity of semi-interpenetrating polymer network amphoteric membrane for vanadium redox flow battery application

In this work, semiinterpenetrating polymer network (semi-IPN), consisting of sulfonated poly (arylene ether sulfone) (SPAES) and crosslinked vinyl imidazole grafted polysulfone (VMPSU), is prepared and characterized. FTIR, EDS, and solubility test indicate the successful preparation of amphoteric membranes. The semi-IPN amphoteric membranes exhibit better stability than pure SPAES membrane, as demonstrated by thermogravimetric analysis and ex situ immersion testing results. More importantly, it is shown that the amphoteric membrane can effectively hinder vanadium ion crossover through the membrane, which is attributed to the semi-IPN structure and Donnan exclusion. As expected, the amphoteric membrane containing 20% VMPSU exhibits the highest proton selectivity (6.86 × 10⁴ S min cm⁻³), comparing to pristine SPAES (1.90 × 10⁴ S min cm⁻³) as well as Nafion117 (1.31 × 10⁴ S min cm⁻³).     

提高组串光伏发电效率的直流动态重构控制策略

针对均匀低光照下组串式逆变器效率低的问题,提出一种提高组串逆变器并行效率的直流侧开关重构策略.基于一种光伏直流开关拓扑结构对多光伏串和多逆变器的连接进行控制.考虑光伏系统效率和并行开关电气寿命等系统运行指标,控制逆变器运行台数使系统效益指标函数最优.提出防止逆变器功率越限策略,利用最小二乘回归算法预测天气短时间变化范围,确定光伏系统允许的开关重构方案;对比不同时刻其他最佳开关连接方式,选出最终连接方案最小化开关切换次数.最后,利用控制决策决定直流开关重构的最终方案,将提出的策略与常规光伏发电和仅考虑目标函数发电作数据对比,验证该策略的有效性与可行性.     

计及源荷不确定性的独立型交直流混合微网多能源协调优化调度

传统独立型交直流混合微网的可再生能源供电比例高,但储能和其他可控电源容量有限,易出现切负荷或弃风弃光现象.首先,为提高系统的供能可靠性和可再生能源的消纳水平,设计出一种基于氢储系统实现交流、直流、氢气、热力与天然气能源系统深度耦合的能量枢纽结构;其次,为实现设计系统的多能源协调优化调度,构建出一种计及源荷不确定性的两阶段鲁棒优化模型,模型中第一阶段确定所有能源转换和存储设备的运行状态,第二阶段确定最恶劣场景及各设备出力方案,并且可利用不确定度参数灵活调整调度结果的保守性;然后,基于强对偶理论和大M法将优化模型转换为具有混合整数线性形式的主问题和子问题,并采用列与约束生成算法求解;最后,算例分析结果表明所建模型的合理性,求解算法的有效性以及调度结果的鲁棒性和经济性.     

考虑经济成本的微电网调度运行

为提高微电网经济运行水平,首先以微电网发电成本最小为目标,考虑微电网运行实际约束条件,将蜂群算法运用到并网状态下的微电网经济调度模型中;其次,将对立学习策略初始化种群,改善初始种群质量,同时将Metropolis准则引入蜂群算法,提高跳出局部最优解的概率;最后,以并网状态下的微电网为例,比较未改进蜂群算法与改进蜂群算法优化结果.结果 表明,改进蜂群算法的调度方案降低了微电网的日调度综合成本,同时验证了所改进算法在求解微电网调度优化问题上的有效性与优越性.     

基于局部间隙状况电火花磨削周期的伺服策略

分析了现有的一些电火花磨削伺服策略存在的问题，提出了基于周期性和局部性特点的伺服策略。该策略以回转周期为控制周期，以局部间隙状况为控制的依据，通过极端局部间隙状况控制极端局部表面加工状态，从而控制整个表面优质高效的加工，具有快速修圆和一定的自动寻优功能。     

Hot-Corrosion Resistance of a Sputtered K38G Nanocrystalline Coating in Molten Sulfate at 900°C

The hot-corrosion behavior of a nanocrystalline coating of K38G alloy, prepared by magnetron sputtering and cast K38G in molten 75 wt.% Na₂SO₄+25 wt.% K₂SO₄ at 900°C was studied. The coating eliminated internal sulfidation during the early stage of corrosion as a result of the formation of a continuous and compact Al₂O₃ scale. The nanocrystallization of K38G alloy prolonged the incubation of breakaway corrosion and improved the corrosion resistance of K38G. The relevant corrosion mechanism is discussed.     

Charge-discharge process of MnO2 supercapacitor

Mechanochemical synthesis of α-MnO2 was carried out with KMnO4 and Mn（CH3COO）2 in 1：1 mole ratio. The electrochemical performance of MnO2 electrode was investigated by cyclic voltammograms and alternating current impedance. The charge-discharge process of MnO2 supercapacitor in 6 mol/L KOH was studied within 1.2 V at 200 mA/g, suggesting that it displays double-layer capacibility in low potential scope and pseudo-capacitance properties in high potential scope. It is found that Mn3O4, an electrochemical inert, mainly forms in the initial 40 charge-discharge cycles. During cycling, the pseudo-capacitance properties disappear and the discharge curves are close to ideal ones, indicating double-layer capability. The maximum capacitance of MnO2 electrode is as high as 416 F/g, and retains 240 F/g after 200 cycles. The equivalent series resistance increases from 17 to 41Ω.     

等径角挤压法制备超细晶的研究现状

总结了等径角挤压(Equal Channel Angular Pressing，ECAP)过程中的影响因素、晶粒细化的机理等方面的研究进展，讨论了挤压温度、挤压速度在ECAP过程中对材料的影响，简述了ECAP的变形途径、变形次数对材料晶粒、材料变形量的影响。论述了由等径角挤压方法制备超细晶材料的发展现状并提出了一些需要进一步深入研究的方面。     

Si复合Al2O3-SiC材料热机械性能的研究

通过应力-应变关系、高温抗折强度等高温试验，研究了金属硅复合Al2O3-SiC材料的热机械性能，结合SEM和XRD，对金属硅复合Al2O3-SiC材料高温显微结构和物相进行分析。结果表明：金属硅作为一个组元，不仅能缓解Al2O3-SiC材料由于热膨胀系数不匹配产生的内应力，而且使Al2O3-SiC材料兼具有金属塑性的特点，从而改善了Al2O3-SiC无机材料热机械性能。     

氧气喷头的热挤压工艺及模具设计

在设备吨位和闭合高度有限的情况下，设计结构新颖的组合成挤压模具，使315t油压机设备能力得到了有效的发挥；本文所述氧气喷头毛坯生产工艺，具有节材优质高效的特点；对类似零部件挤压工艺及模具结构设计具有重要的参考价值。