Application of homogenization heat treatments to improve continuous-annealing furnace roller fractures

In this work, several cycles of homogenization heat treatments were employed to improve continuous-annealing furnace roller fractures at Mobarakeh Steel Company. Previous studies revealed that roller fractures were caused by sigma phase embrittlement and an increase of precipitations in the microstructure. Therefore, impact samples were prepared from failed rollers and homogenization treatments were carried out at temperatures ranging from 950 to 1100 °C in increments of 50 °C for 2 h. After cooling the samples in different mediums (furnace, air, oil and water), the impact energy was experimentally determined. In order to investigate the microstructures, the sigma phase and precipitation contents, and fractured surfaces, optical microscopy metallography, X-ray and SEM examinations were performed respectively on fractured samples. The results of these investigations indicate that homogenization treatment at 1100 °C for 2 h, followed by cooling in air, resulted in a significant increase in impact energy, a decrease in sigma phase and other precipitation contents, and produced a ductile fracture surface.     

Minimizing the number of tardy jobs under piecewise-linear deterioration

In this paper, we consider a single machine scheduling problem with piecewise-linear deterioration where its objective is to minimize the number of tardy jobs, in which the processing time of each job depends on its starting time where all the jobs have a specific deterioration rate. The problem is known to be NP-hard; therefore a Branch and Bound algorithm and a heuristic algorithm with O(n²) are proposed. The proposed heuristic algorithm has been utilized for solving large scale problems and upper bound of the B&B algorithm. Computational experiments on 1840 problems demonstrate that the Branch and Bound procedure can solve problems with 28 jobs and 85.4% of all the sample problems optimally showing the high capability of the proposed procedure. Also it is shown that the average value of the ratio of optimal answer to the heuristic algorithm result with the objective ∑(1-_Ui)$\sum (1-U_i)$ is at last 1.08 which is more efficient in contrast to other proposed algorithms in related studies in the literature. According to high efficacy of the heuristic algorithm, large scale samples are also being solved and the results are presented. A specific form of this problem is also being considered and it is proven that the B&B procedure can handle problems with more jobs even up to 44 jobs.     

Nanomechanical study of polycarbonate/boehmite nanoparticles/epoxy ternary composite and their interphases

Thermoplastic modified thermosets are of great interest especially due to their improved fracture toughness. Comparable enhancements have been achieved by adding different nanofillers including inorganic particles such as nanosized boehmite. Here, we present a nanomechanical study of two composite systems, the first comprising a polycarbonate (PC) layer in contact with epoxy resin (EP) and the second consisting of a PC layer containing boehmite nanoparticles (BNP) which is also in contact with an EP layer. The interaction between PC and EP monomer is tested by in situ Fourier transformed infrared (FT-IR) analysis, from which a reaction induced phase separation of the PC phase is inferred. Both systems are explored by atomic force microscopy (AFM) force spectroscopy. AFM force-distance curves (FDC) show no alteration of the mechanical properties of EP at the interface to PC. However, when a PC phase loaded with BNP is put in contact with an epoxy system during curing, a considerable mechanical improvement exceeding the rule of mixture was detected. The trend of BNP to agglomerate preferentially around EP dominated regions and the stiffening effect of BNP on EP shown by spatial resolved measurements of Young's modulus, suggest the effective presence of BNP within the EP phase.     

Fuzzy absolute error distance measure based on a generalised difference operation

The main goal of this paper is to introduce a notion of fuzzy absolute error distance measure between two fuzzy numbers. For this purpose, a notion of generalised difference operation between two fuzzy numbers and absolute value of a fuzzy number was first introduced. The proposed methods were conducted on the basis of α-values of fuzzy numbers. Main properties of the proposed fuzzy distance measure was also verified in the space of fuzzy numbers. The proposed fuzzy distance measure evaluates the fuzzy distance between the two fuzzy numbers as a fuzzy number. Notably, the main advantage of such generalised difference operation is that it always exists. Therefore, it improves the shortcoming of a well-known generalised difference operation called Hakuhara difference. Some of the main properties of the proposed fuzzy absolute error distance measure including robustness were also studied in the space of fuzzy numbers. Several fuzzy distance measures, especially fuzzy absolute error distance, have been proposed so far. However, none of them save all reasonable properties required for an absolute error distance measure in fuzzy environment. Shortcomings relevant to other methods and advantages of the proposed method were also discussed.     

Dispersion state and hyperelastic behavior of tire tread compounds reinforced with nanoclay: Uniaxial tensile and compression studies

Tire-tread compounds based on natural rubber, butadiene rubber, and styrene-butadiene rubber (65/20/15) were reinforced with Cloisite 15A. Clay state-of-dispersion in the ternary matrix (clay aspect ratio and clay/matrix interface yield strength) was estimated using Halpin–Tsai, Guth, and Leidner–Woodhams–Pukanszky micro-mechanical models. The aspect ratio suggested by Halpin–Tsai (9.7) and Guth (16) models both propounded partially intercalated microstructure. Transmission electron microscopy micrographs indicated higher reliability of Halpin–Tsai theory. Wetting parameter values indicated the affinity of Cloisite 15A to disperse in butadiene rubber. However, it seems that clay particles were not provided with proper compounding conditions to further stabilize their thermodynamic state. The poor matrix/clay adhesion was responsible for the decrease in matrix/clay interface strength and thickness upon increasing clay content according to Leidner–Woodhams–Pukanszky. Hyperelastic modeling was conducted using Abaqus software (five strain energy potential forms) on the basis of large deformation uniaxial tension/compression measurements. Effect of nanoclay on the crosslink-density of samples was justified by C₁₀ (Mooney–Rivlin) and locking-stretch (Van der Waals) values. The sample containing 1 phr nanoclay presented the best fit to the hyperelastic models among the rest conforming to its small value of global interaction parameter “a”(Van der Waals model) calculated explaining minimum deviations. Overall, Marlow and Ogden provided the best consistency with the experimental stress–strain results.     

Chemically and Green Synthesized ZnO Nanoparticles Alter Key Immunological Molecules in Common Carp (Cyprinus carpio) Skin Mucus

This study was conducted to compare the effects of commercially available (C) and green synthesized (GS) Zinc oxide nanoparticles (ZnO-NPs) on immunological responses of common carp (Cyprinus carpio) skin mucus. GS ZnO-NPs were generated using Thymus pubescent and characterized by UV–vis diffuse reflectance spectroscopy (DRS), Fourier-transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), scanning electron microscope (SEM), and energy-dispersive X-ray spectroscopy (EDX). Fish (n = 150) were randomly allocated into five groups in triplicate and received a waterborne concentration of 0% (control), 25%, and 50% of LC50 96 h of commercially available (C1 and C2) and green synthesized ZnO-NPs (GS1 and GS2) for 21 days. Results from XRD displayed ZnO-NPs with 58 nm in size and UV-vis DRS, EDX, and FT-IR analysis showed that some functional groups from plant extract bonded to the surface of NPs. The SEM images showed that ZnO-NPs have conical morphology. Acute toxicity study showed a higher dose of LC50_96h for green synthesized ZnO-NPs (78.9 mg.L⁻¹) compared to the commercial source (59.95 mg.L⁻¹). The highest activity of lysozyme and alternative complement activity (ACH50) were found in control and GS1 groups. A significant decrease in alkaline phosphatase activity (ALP) was found in C1 and C2 groups compared to other treatments. Protease activity (P) was significantly decreased in the C2 group compared to the control and GS groups. Total immunoglobulin (total Ig) content was the highest in the control. In addition, total Ig in the GS1 group was higher than GS2. The exposure to ZnO-NPs lowered total protein content in all experimental groups when compared to control. Present findings revealed lower induced immunosuppressive effects by green synthesized ZnO-NPs on key parameters of fish skin mucus.     

Effect of carbon nanotube on PA6/ECO composites: Morphology development,rheological, and thermal properties

Thermoplastic elastomer (TPE) nanocomposites based on polyamide‐6 (PA6)/poly(epichlorohydrin‐co‐ethylene oxide) (ECO)/multiwall carbon nanotube (MWCNTs) were prepared by melt compounding process. Different weight ratios of ECO (20, 40, and 60 wt %) and two kinds of functionalized and non‐functionalized MWCNTs were employed to fabricate the nanocomposites. The morphological, rheological, and mechanical properties of MWCNTs‐filled PA6/ECO blends were studied. The scanning electron microscopy of PA6/ECO blends showed that the elastomer particles, ECO, are well‐dispersed within the PA6 matrix. The significant improvement in the dispersibility of the carboxylated carbon nanotubes (COOH‐MWCNTs) compared to that of non‐functionalized MWCNTs (non‐MWCNTs) was confirmed by transmission electron microscopy images. The tensile modulus of samples improved with the addition of both types of MWCNTs. However, the effect of COOH‐MWCNTs was much more pronounced in improving mechanical properties of PA6/ECO TPE nanocomposites. Crystallization results demonstrated that the MWCNTs act as a nucleation agent of the crystallization process resulted in increased crystallization temperature (T_c) in nanocomposites. Rheological characterization in the linear viscoelastic region showed that complex viscosity and a non‐terminal storage modulus significantly increased with incorporation of both types of MWCNTs particularly at low frequency region. The increase of rheological properties was more pronounced in the presence of carboxylic (COOH) functional groups, in the other words by addition of COOH‐MWCNTs. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45977.     

Correlation between irregular surface geometry and certain electrochemical quantities in poly-ortho-aminophenol

The relationship between the fractal dimension of poly-ortho-aminophenol film and its thickness in the presence of different anions was studied using the peak current scaling in cyclic voltammetry (CV). There is a meaningful relation between the inner and outer cutoff (minimum and maximum length scale of the surface seen by the diffusing species, respectively) distinction in the polymer sensed by anions and the film charge transport resistance. The constant phase element exponent at low frequency was found to depend on the thickness of the poly-ortho-aminophenol film and on the applied potential during the impedance measurements. The constant phase element exponent dependence on the thickness of the film is explained by the film morphology and its dependence on the applied potential is interpreted by a change in the charge transport mechanism in the poly-ortho-aminophenol films.     

Preparation of thermoplastic elastomer nanocomposites based on polyamide‐6/polyepichlorohydrin‐co‐ethylene oxide

This work is aimed at determining the effect of nanoclay and polyepichlorohydrin‐co‐ethylene oxide (ECO) content on the microstructure and mechanical properties of PA6/ECO thermoplastic elastomers (TPEs). TPE nanocomposites were prepared in a laboratory mixer using polyamide 6 (PA6), ECO, and an organoclay by a two‐step melt mixing process. First, the PA6 was melt blended with Cloisite 30B and then mixed by ECO rubber. X‐ray diffraction results and transmission electron microscopy image showed that the nanoclay platelets were nearly exfoliated in both the phases. The SEM photomicrograph of PA6 with ECO showed that the elastomer particles are dispersed throughout the polyamide matrix and the size of rubber particles is less than 3 μm. Introduction of organoclay in the PA6 matrix increased the size of dispersed rubber particles in comparison with the unfilled but otherwise similar blends. The nanoscale dimension of the dispersed clay results in an improvement of the tensile modulus of the nanocomposites. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers     

Naturally occurring halloysite nanotubes for enhanced durability of natural rubber/ethylene propylene diene monomer rubber vulcanizate

A facile approach of using halloysite nanotubes (HNTs) was proposed to address the durability performance demands of natural rubber (NR)/ethylene propylene diene monomer rubber (EPDM) blends and to protect them from the deleterious effects of the service environment including ozone, chemicals, abrasion, and cyclic loading. The introduction of HNTs substantially improved the stability of NR/EPDM when exposed to ozone (over fourfold enhancement with the addition of 5 phr HNTs). Moreover, the HNT-filled NR/EPDM vulcanizates offered approximately 66% reduction in the solvent-mediated swelling in comparison to the unfilled sample. Fatigue life studies showed that the HNT-reinforced NR/EPDM composite could withstand 30% more cycles to failure than the un-reinforced NR/EPDM blend. The effect of various HNT loading on the morphological, mechanical, physical, and rheological properties of nanocomposite vulcanizates based on NR/EPDM was also investigated. The morphological investigations revealed that the introduction of HNT into the NR/EPDM rubber matrix caused a rough morphology in fracture surface and a well-dispersed structure was obtained with the addition of up to 5 phr of HNTs. These findings were further supported by rheological, mechanical, and thermodynamical results.