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81.
Oxidation Kinetics of an Amorphous Silicon Carbonitride Ceramic 总被引:4,自引:0,他引:4
Rishi Raj Linan An Sandeep Shah Ralf Riedel Claudia Fasel Hans-Joachim Kleebe 《Journal of the American Ceramic Society》2001,84(8):1803-1810
The oxidation kinetics of amorphous silicon carbonitride (SiCN) was measured at 1350°C in ambient air. Two types of specimens were studied: one in the form of thin disks, the other as a powder. Both specimens contained open nanoscale porosity. The disk specimens exhibited weight gain that saturated exponentially with time, analogous to the oxidation behavior of reaction-bonded Si3 N4 . The saturation value of the weight gain increased linearly with specimen volume, suggesting the nanoscale pore surfaces oxidized uniformly throughout the specimen. This interpretation was confirmed by high-resolution electron microscopy and secondary ion mass spectroscopy. Experiments with the powders (having a particle size much larger than the scale of the nanopores) were also consistent with measurements of the disks. However, the powder specimens, having a high surface-to-volume ratio, continued to show measurable weight gain due to oxidation of the exterior surface. The wide range of values for the surface-to-volume ratio, which included all specimens, permitted a separation of the rate of oxidation of the free surface and the oxidation of the internal surfaces of the nanopores. Surface oxidation data were used to obtain the rate constant for parabolic growth of the oxidation scale. The values for the rate constant obtained for SiCN lay at the lower end of the spectrum of oxidation rates reported in the literature for several Si3 N4 and SiC materials. Convergence in the behavior of SiCN and CVD-SiC is ascribed to the purity of both materials. Conversely, it is proposed that the high rates of oxidation of sintered polycrystalline silicon carbides and nitrides, as well as the high degree of variability of these rates, might be related to the impurities introduced by the sintering aids. 相似文献
82.
83.
G. Britto Joseph G. NarendraKumar G. Mageshwaran Jeya Jeevahan V. Sriram R. B. Durai Raj 《国际自然能源杂志》2013,34(8):863-867
Nowadays, refrigeration systems are important for industrial and domestic applications. The coefficient of performance of a vapour compression refrigeration system can be improved if a reduction in the work of compression can be achieved by a suitable technique for a specified heat removal rate. The present study investigates the effect of material coating of electroless nickel (EN) plating. The friction and wear experiments were performed using a four-ball machine tribo tester. Controlling the EN plating parameters plays an important role in the quality of coating. It depends on the wear scar rate of the coated material. So it is necessary to optimise the process parameters of EN plating. The experimental studies have been conducted under varying pressure, load and time on quality characteristics. In this paper, optimisation of process parameters using response surface methodology technique for EN plating was discussed. 相似文献
84.
Additive Manufacturing of Ceramics Enabled by Flash Pyrolysis of Polymer Precursors with Nanoscale Layers
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Luca Zoli Diletta Sciti Li‐Anne Liew Kalvis Terauds Setareh Azarnoush Rishi Raj 《Journal of the American Ceramic Society》2016,99(1):57-63
We show that a polymer‐based route to ceramics can be implemented into additive manufacturing by reducing the time for pyrolysis to about a second, which we call flash pyrolysis. Repetitive deposition of nanometer scale coatings of the ceramic, in this way, is employed to create defect‐free infiltrations of carbon fiber composites. The mechanical strength of the fibers is retained in the composite. Excellent wetting properties of the polymer precursor permits three‐dimensional, conformal coating through the three stages of infiltration: nanoscale coating of the single fibers, filling of interstitial spaces between the fibers, and a buildup of the coating over the entire composite. The flash pyrolysis method will enable a new genre of polymer‐derived ceramics made into net shape by this unusual method of additive manufacturing. 相似文献
85.
The Change of X‐ray Diffraction Peak Width During in situ Conventional Sintering of Nanoscale Powders
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Jean‐Marie Lebrun Shikhar K. Jha Kiran S. Naik Kevin C. Seymour Waltraud M. Kriven Rishi Raj 《Journal of the American Ceramic Society》2016,99(3):765-768
Diffraction peaks of nanoscale particles of 3 mol% yttria‐stabilized zirconia become sharper as the powder sinters. The reduction in the peak width is correlated with the increase in density. The sharpening of the peak agrees reasonably well with the remaining free surface area as the sample sinters. Therefore, high curvature of the free surface of the pores is assumed to lead to peak broadening (the grain boundaries that grow at the expense of the free surfaces of the pores do not have this curvature). The change in the grain size during sintering does not make a significant contribution to peak width. 相似文献
86.
Water scarcity increases alarmingly as the population increases. Over the years, a number of salt water desalination techniques have been proposed and reached limitations. The requirement of minimum energy is very well satisfied by an adsorption system, since it can operate with low-grade energy and waste heat exhaust from most industries. The first part of this work discusses the effect of condenser and evaporator temperatures on the performance of silica-gel adsorption cycle mathematically. The second part discusses the performance variations due to mass recovery in the two-bed adsorption system mathematically. It was found that the reduction in condenser temperature and increase in the evaporator temperature both increase the fresh water productivity and cooling capacity of a plant. A desalination plant with mass recovery assistance is superior in performance than the conventional plant. Portable water productivity of 8?m3/day/ton is achieved with the condenser temperature of 15°C and the evaporator temperature of 30°C. 相似文献
87.
Padmanapan Rao Raj N. Singh 《International Journal of Applied Ceramic Technology》2022,19(6):3149-3157
A sealant is required for the solid oxide fuel cell (SOFC) to maintain hermeticity at high operating temperatures, keep fuel and oxidant from mixing, and avoid shorting of the cell stack. Glass and glass–ceramic materials are widely used as a sealant because their properties can be tailored to meet the stringent requirements of SOFC stack, but they are susceptible to cracking. In contrast, a promising concept of self-repairable glass for seals is pursued for making reliable seals that can self-repair cracks at the SOFC operating temperatures. This concept is studied through measuring crack-healing kinetics and independent measurement of glass viscosity for relating to the observed self-repair. The cracks on the glass surface are created using a Vickers indenter to achieve a well-defined crack geometry, and then the glass is exposed to elevated temperatures for different length of times to study the crack-healing kinetics. The crack-healing kinetics is compared with the predictions of our theoretical model and found to be in good agreement. In addition, glass viscosity is extracted from the healing kinetics and compared with the independent measurement of viscosity measured from the dilatometry and sintering data to further validate the crack-healing theoretical model. These results are presented and discussed. 相似文献
88.
Sudhan Raj Jeganmohan Darius Gnanaraj Solomon T. V. Christy 《Tribology - Materials, Surfaces & Interfaces》2018,12(2):71-84
Binder provides structural integrity by holding all ingredients in the composition of a brake friction material. The modified binders have played a major role in improving the frictional performance and thermal resistance of the friction material. The present research work evaluates the influence of secondary binders (Nitrile Butadiene rubber (NBR) and Styrene Butadiene rubber (SBR)) on the tribological performance of the friction material using a full-scale inertia brake dynamometer as per JASO C406 standard. Three brake pads were developed by varying the type and composition of secondary rubber binder (5%NBR, 5%SBR and 2.5%NBR + 2.5%SBR) with rest of the ingredients kept unaltered. It was found that the quantity of SBR rubber powder present as secondary binder improved dry and wet recovery. Friction coefficient (μ) exhibited better stability during the fade with the inclusion of both the rubber powders. The friction material with the inclusion of both the NBR and SBR rubber powders exhibited overall better performance than compared to the inclusion of only one secondary binder rubber in the composition. The worn-out surface of the developed friction materials and the counter discs were characterised using FESEM. 相似文献
89.
Thomas G. Howell Cory P. Kuhnell Thomas L. Reitz Bryan C. Eigenbrodt Raj N. Singh 《Journal of the American Ceramic Society》2014,97(11):3636-3642
The objective of this effort is to synthesize and characterize a series of lanthanum‐(La) doped Sr2MgMoO6 (SMMO) and La‐doped Sr2MgNbO6 (SMNO) anode materials which can be used in combination with lanthanum‐containing electrolytes to mitigate the effects of lanthanum poisoning in solid oxide fuel cells (SOFCs). Currently, an La0.4Ce0.6O1.8 (LDC) buffer layer is used with many perovskite‐based anode materials to prevent La diffusion into the anode from the La0.8Sr0.2Ga0.8Mg0.2O2.8 (LSGM) electrolyte which can create a resistive La species that impedes electrochemical performance. The LDC buffer layer, with diminished electronic conductivity, adds an extra level of complexity in the SOFC manufacturing process. Further, this extraneous layer presents an added experimental challenge when assessing anode material performance. Overall electrochemical performance could be improved if the resistive buffer layer could be removed, thereby allowing the anode material to have direct contact with the electrolyte. To accomplish this, a new class of anode materials was synthesized with the goal of balancing “La” chemical potential between these neighboring materials. La‐doped SMMO and SMNO were prepared and studied. It was hypothesized that by incorporating La into the anode, the gradient of chemical activity between the anode and electrolyte would decrease, which would prevent La diffusion. These anode materials were synthesized via a sol–gel methodology and characterized with X‐ray diffraction to assess phase purity. The conductivity of the materials was analyzed in the presence of both H2 and 100 ppm H2S/H2 to determine the stability and performance of these materials during device operation. The stability experiments demonstrated that 40% La‐doped SMNO is stable in all pertinent environments while not reacting with the LSGM electrolyte. 相似文献
90.
Mamta Latwal Prakash Chandra Shah Raj Ali 《Journal of Applied Electrochemistry》2014,44(10):1127-1134
Nanostructured copper hexacyanidoferrate has been synthesized and characterized using elemental analysis, atomic absorption spectroscopy, thermal and infrared spectral studies. The transmission electron microscopic studies of the synthesized material showed that it consisted of irregular oval and rod shaped particles with a size range 70–100 nm. Nanostructured copper hexacyanidoferrate modified glassy carbon electrode was characterized by cyclic voltammetery and nanostructured copper hexacyanidoferrate–carbon nanotube composite material modified glassy carbon electrode has been used for electrocatalytic oxidation of salbutamol. The electrode modified with composite material was found to reduce the peak potential of oxidation of salbutamol by nearly 90 mV. 相似文献