全文获取类型
收费全文 | 20861篇 |
免费 | 1578篇 |
国内免费 | 679篇 |
专业分类
电工技术 | 985篇 |
技术理论 | 4篇 |
综合类 | 1263篇 |
化学工业 | 3764篇 |
金属工艺 | 1000篇 |
机械仪表 | 1270篇 |
建筑科学 | 1615篇 |
矿业工程 | 436篇 |
能源动力 | 554篇 |
轻工业 | 1483篇 |
水利工程 | 332篇 |
石油天然气 | 1069篇 |
武器工业 | 155篇 |
无线电 | 2181篇 |
一般工业技术 | 3093篇 |
冶金工业 | 1161篇 |
原子能技术 | 260篇 |
自动化技术 | 2493篇 |
出版年
2024年 | 74篇 |
2023年 | 286篇 |
2022年 | 450篇 |
2021年 | 596篇 |
2020年 | 497篇 |
2019年 | 453篇 |
2018年 | 478篇 |
2017年 | 598篇 |
2016年 | 536篇 |
2015年 | 709篇 |
2014年 | 848篇 |
2013年 | 1099篇 |
2012年 | 1179篇 |
2011年 | 1258篇 |
2010年 | 1061篇 |
2009年 | 1034篇 |
2008年 | 1105篇 |
2007年 | 1055篇 |
2006年 | 1139篇 |
2005年 | 1108篇 |
2004年 | 699篇 |
2003年 | 653篇 |
2002年 | 608篇 |
2001年 | 523篇 |
2000年 | 677篇 |
1999年 | 730篇 |
1998年 | 630篇 |
1997年 | 557篇 |
1996年 | 493篇 |
1995年 | 458篇 |
1994年 | 335篇 |
1993年 | 249篇 |
1992年 | 209篇 |
1991年 | 172篇 |
1990年 | 133篇 |
1989年 | 117篇 |
1988年 | 90篇 |
1987年 | 45篇 |
1986年 | 48篇 |
1985年 | 43篇 |
1984年 | 18篇 |
1983年 | 5篇 |
1982年 | 15篇 |
1981年 | 13篇 |
1980年 | 11篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1970年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
Wenshu Chen Jiajun Gu Yongping Du Fang Song Fanxing Bu Jinghan Li Yang Yuan Ruichun Luo Qinglei Liu Di Zhang 《Advanced functional materials》2020,30(25)
Large‐scale production of hydrogen from water‐alkali electrolyzers is impeded by the sluggish kinetics of hydrogen evolution reaction (HER) electrocatalysts. The hybridization of an acid‐active HER catalyst with a cocatalyst at the nanoscale helps boost HER kinetics in alkaline media. Here, it is demonstrated that 1T–MoS2 nanosheet edges (instead of basal planes) decorated by metal hydroxides form highly active / heterostructures, which significantly enhance HER performance in alkaline media. Featured with rich / sites, the fabricated 1T–MoS2 QS/Ni(OH)2 hybrid (quantum sized 1T–MoS2 sheets decorated with Ni(OH)2 via interface engineering) only requires overpotentials of 57 and 112 mV to drive HER current densities of 10 and 100 mA cm?2, respectively, and has a low Tafel slope of 30 mV dec?1 in 1 m KOH. So far, this is the best performance for MoS2‐based electrocatalysts and the 1T–MoS2 QS/Ni(OH)2 hybrid is among the best‐performing non‐Pt alkaline HER electrocatalysts known. The HER process is durable for 100 h at current densities up to 500 mA cm?2. This work not only provides an active, cost‐effective, and robust alkaline HER electrocatalyst, but also demonstrates a design strategy for preparing high‐performance catalysts based on edge‐rich 2D quantum sheets for other catalytic reactions. 相似文献
12.
Guo-Yu Li Ya-Xin Zheng Fu-Zhou Sun Jian Huang Meng-Meng Lou Jing-Kai Gu Jin-Hui Wang 《International journal of molecular sciences》2015,16(9):22190-22204
This study aimed at investigating the possible mechanisms of hepatic protective activity of Cichorium intybus L. (chicory) in acute liver injury. Pathological observation, reactive oxygen species (ROS) detection and measurements of biochemical indexes on mouse models proved hepatic protective effect of Cichorium intybus L. Identification of active compounds in Cichorium intybus L. was executed through several methods including ultra performance liquid chromatography/time of flight mass spectrometry (UPLC-TOF-MS). Similarity ensemble approach (SEA) docking, molecular modeling, molecular docking, and molecular dynamics (MD) simulation were applied in this study to explore possible mechanisms of the hepato-protective potential of Cichorium intybus L. We then analyzed the chemical composition of Cichorium intybus L., and found their key targets. Furthermore, in vitro cytological examination and western blot were used for validating the efficacy of the selected compounds. In silico analysis and western blot together demonstrated that selected compound 10 in Cichorium intybus L. targeted Akt-1 in hepatocytes. Besides, compound 13 targeted both caspase-1 and Akt-1. These small compounds may ameliorate liver injury by acting on their targets, which are related to apoptosis or autophagy. The conclusions above may shed light on the complex molecular mechanisms of Cichorium intybus L. acting on hepatocytes and ameliorating liver injury. 相似文献
13.
Xiaohui Hu Li Cheng Yan Hong Zhaofeng Li Caiming Li Zhengbiao Gu 《International Journal of Food Science & Technology》2021,56(8):4149-4158
Incorporating high level of potato flour into wheat flour enhances nutritional values of bread but induces a series of problems that lead to the decline of the bread quality. To overcome the barrier, wheat gluten and carboxymethylcellulose (CMC) were added into potato–wheat composite flour to improve dough machinability and bread quality. The rheological properties, thermo-mechanical properties and microstructures of dough were investigated. The results showed that the interaction between gluten and CMC mitigated the discontinuity of gluten matrix and gluten protein aggregation caused by the addition of potato flour, which yielded a more branched and compact gluten network. The compact three-dimensional viscoelastic structure induced improvements of gas retention capacity and dough stability, making it mimic the machinability properties of wheat flour dough. Bread qualities were apparently improved with the combined use of 4% gluten and 6% CMC, of which specific volume increased by 42.86%, and simultaneously, hardness reduced by 75.93%. 相似文献
14.
15.
Manjin Kim Qinfen Gu Tanveer Hussain Yahia Ali Trevor B. Abbott Kazuhiro Nogita 《International Journal of Hydrogen Energy》2021,46(53):27096-27106
With superior properties of Mg such as high hydrogen storage capacity (7.6 wt% H/MgH2), low price, and low density, Mg has been widely studied as a promising candidate for solid-state hydrogen storage systems. However, a harsh activation procedure, slow hydrogenation/dehydrogenation process, and a high temperature for dehydrogenation prevent the use of Mg-based metal hydrides for practical applications. For these reasons, Mg-based alloys for hydrogen storage systems are generally alloyed with other elements to improve hydrogen sorption properties. In this article, we have added Na to cast Mg–La alloys and achieved a significant improvement in hydrogen absorption kinetics during the first activation cycle. The role of Na in Mg–La has been discussed based on the findings from microstructural observations, crystallography, and first principles calculations based on density functional theory. From our results in this study, we have found that the Na doped surface of Mg–La alloy systems have a lower adsorption energy for H2 compared to Na-free surfaces which facilitates adsorption and dissociation of hydrogen molecules leading to improvement of absorption kinetic. The effect of Na on the microstructure of these alloys, such as eutectic refinement and a density of twins is not highly correlated with absorption kinetics. 相似文献
16.
As the development of cloud computing and the convenience of wireless sensor netowrks, smart devices are widely used in daily life, but the security issues of the smart devices have not been well resolved. In this paper, we present a new NTRU-type public-key cryptosystem over the binary field. Specifically, the security of our scheme relies on the computational intractability of an unbalanced sparse polynomial ratio problem (DUSPR). Through theoretical analysis, we prove the correctness of our proposed cryptosystem. Furthermore, we implement our scheme using the NTL library, and conduct a group of experiments to evaluate the capabilities and consuming time of encryption and decryption. Our experiments result demonstrates that the NTRU-type public-key cryptosystem over the binary field is relatively practical and effective. 相似文献
17.
Shengyue Gu Shouyang Zhang Fei Liu Wei Li 《Journal of the European Ceramic Society》2018,38(15):5082-5091
Y2Hf2O7 possesses low thermal conductivity and high melting point, which make it promising for a new anti-ablation material. For evaluating the thermal stability and the potential applications of Y2Hf2O7 on anti-ablation protection of C/C composites, Y2Hf2O7 ceramic powder was synthesized by solution combustion method and Y2Hf2O7 coating was prepared on the surface of SiC coated C/C composites using SAPS. Results shown that the coating exhibits good ablation resistance under the heat flux of 2.4?MW/m2 with the linear and mass ablation rates are 0.16?μm?s?1 and ?0.028?mg?s?1, respectively, after ablation for 40?s. With the prolonging of the ablation time, the increasing thermal stress causes the increase of cracks. Moreover, the chemical erosion from SiO2 and the physical volatilization of low temperature molten products aggravate failure of the Y2Hf2O7 coating. 相似文献
18.
19.
20.
High‐performance thermosets with tailored properties derived from methacrylated eugenol and epoxy‐based vinyl ester
下载免费PDF全文
![点击此处可从《Polymer International》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Yuehong Zhang Yuzhan Li Vijay Kumar Thakur Zhenhua Gao Jiyou Gu Michael R Kessler 《Polymer International》2018,67(5):544-549
A renewable chemical, eugenol, is methacrylated to produce methacrylated eugenol (ME) employing the Steglich esterification reaction without any solvent. The resulting ME is used as a low‐viscosity co‐monomer to replace styrene in a commercial epoxy‐based vinyl ester resin (VE). The volatility and viscosity of ME and styrene are compared. The effect of ME loading and temperature on the viscosity of the VE–ME resin is investigated. Moreover, the thermomechanical properties, curing extent and thermal stability of the fully cured VE–ME thermosets are systematically examined. The results indicate that ME is a monomer with low volatility and low viscosity, and therefore the incorporation of ME monomer in VE resins allows significant reduction of viscosity. Moreover, the viscosity of the VE–ME resin can be tailored by adjusting the ME loadings and processing temperature to meet commercial liquid molding technology requirements. The glass transition temperatures of VE–ME thermosets range from 139 to 199 °C. In addition, more than 95% of the monomer is incorporated and fixed in the crosslinked network structure of VE–ME thermosets. Overall, the developed ME monomer exhibits promising potential for replacing styrene as an effective low‐viscosity co‐monomer. The VE–ME resins show great advantages for use in polymer matrices for high‐performance fiber‐reinforced composites. This work is of great significance to the vinyl ester industry by providing detailed experimental support. © 2018 Society of Chemical Industry 相似文献