塑料包装应用及技术进展

塑料在包装领域有着广泛的应用，其中聚酯（PET）性能优良，应用领域不断扩大。介绍了塑料包装不断通现的新技术，以及塑料包装环保问题的几点思路。     

Insights into the intrinsic interaction between series of C1 molecules and surface of NiO oxygen carriers involved in chemical looping processes

Understanding and modulating the interaction between various reactive molecules and oxygen carriers are the key issue to achieve process intensification of chemical looping technology. C1 chemical molecules play an important role in many reactions involved with chemical looping processes. However, up to now, there is still a lack of systematic and in-depth understanding of the adsorption mechanism of C1 molecules on the surface of oxygen carriers (OCs). In this work, the intrinsic interaction between a series of C1 molecules composed of CH₄, CO, CO₂, CH₃OH, HCHO and HCOOH and surface of NiO OCs in the chemical looping process have been studied using density functional theory calculations. Various adsorption configurations of C1 molecules and also different adsorption sites of NiO have been considered. The structural features of stable configuration of C1 molecules on the surface of NiO OCs have been obtained. Further, the interacted sites, types and strengths of C1 molecules on the surface of NiO have been directly pictured by the independent gradient model methods. Also, the nature of the interaction between C1 molecule and NiO surface has been investigated with the aid of energy decomposition analysis from a quantitative view.     

Rapid Reactive Synthesis and Sintering of Submicron TiC/SiC Composites through Spark Plasma Sintering

Submicrometer TiC/SiC composites were fabricated by a rapid reactive sintering process through spark plasma sintering (SPS) technique using the carbon, titanium, and nanosized-SiC powders without any additive. It was found that the composite could be sintered in a relatively short time (8 min at 1480°C) to 97.9% of theoretical density. After sintering, the phase constituents and microstructures of the samples were analyzed by X-ray diffraction techniques and observed by scanning electron microscopy. The effect of nanosized and microsized SiC additives on the microstructure of TiC/SiC composites was investigated.     

快闪存储器大有可为

快闪存储器经历过高速发展时间,由于供过于求,目前行情看跌,但发展前景无疑是远大的。重点介绍了英特尔、AMD和三星的最新产品和重大市场举措。最后简要介绍了当前快闪存储器的技术发展趋势。     

FeS2@TiO2 nanorods as high-performance anode for sodium ion battery

Sodium-ion battery (SIB) is an ideal device that could replace lithium-ion battery (LIB) in grid-scale energy storage system for power because of the low cost and rich reserve of raw material. The key challenge lies in developing electrode materials enabling reversible Na⁺ insertion/desertion and fast reaction kinetics. Herein, a core-shell structure, FeS₂ nanoparticles encapsulated in biphase TiO₂ shell (FeS₂@TiO₂), is developed towards the improvement of sodium storage. The diphase TiO₂ coating supplies abundant anatase/rutile interface and oxygen vacancies which will enhance the charge transfer, and avoid severe volume variation of FeS₂ caused by the Na⁺ insertion. The FeS₂ core will deliver high theoretical capacity through its conversion reaction mechanism. Consequently, the FeS₂@TiO₂ nanorods display notable performance as anode for SIBs including long-term cycling performance (637.8 mA·h·g^-1 at 0.2 A·g^-1 after 300 cycles, 374.9 mA·h·g^-1 at 5.0 A·g^-1 after 600 cycles) and outstanding rate capability (222.2 mA·h·g^-1 at 10 A·g^-1). Furthermore, the synthesized FeS₂@TiO₂ demonstrates significant pseudocapacitive behavior which accounts for 90.7% of the Na⁺ storage, and efficiently boosts the rate capability. This work provides a new pathway to fabricate anode material with an optimized structure and crystal phase for SIBs.     

Improvement of structural stability and electrochemical activity of a cathode material LiNi0.7Co0.3O2 by chlorine doping

In the process of Li⁺ intercalation-deintercalation, electron removal is accompanied simultaneously. Oxygen was found to compensate electron removal both in theoretical calculations and practical experiments. Chlorine addition to LiNi_0.7Co_0.3O₂ was expected to exchange electrons in that Cl⁻ was easier to lose electrons than O²⁻. LiNi_0.7Co_0.3O_2−xCl_x was identified as a pure hexagonal lattice of α-NaFeO₂ type by X-ray diffraction. X-ray photoelectron spectroscopy was used to analyze the influence of chlorine substitution on the oxidation state of transition-metal ions. Charge-discharge experiments and cyclic voltammetry confirmed that chlorine addition was an effective way to improve reversible capacity and structural stability in cycles.     

SO_4~(2-)/TiO_2-MoO_3催化合成己二酸二丁酯

以固体超强酸SO2 -4/TiO2 MoO3 为催化剂 ,通过己二酸和正丁醇反应合成了己二酸二丁酯 ,并探讨了诸因素对产率的影响。正交实验结果表明 :SO2 -4/TiO2 MoO3 具有良好的催化活性 ,醇酸物质的量比为 6∶1,催化剂用量为反应物料总质量的 3.3% ,反应时间 1.5h ,反应温度 10 6～ 10 9℃ ,酯收率可达 77.6 %。     

Multiple Random Forests Modelling for Urban Water Consumption Forecasting

The precise forecasting of water consumption is the basis in water resources planning and management. However, predicting water consumption fluctuations is complicated, given their non-stationary and non-linear characteristics. In this paper, a multiple random forests model, integrated wavelet transform and random forests regression (W-RFR), is proposed for the prediction of daily urban water consumption in southwest of China. Raw time series were first decomposed into low- and high-frequency parts with discrete wavelet transformation (DWT). The random forests regression (RFR) method was then used for prediction using each subseries. In the process, the input and output constructions of the RFR model were proposed for each subseries on the basis of the delay times and the embedding dimension of the attractor reconstruction computed by the C-C method, respectively. The forecasting values of each subseries were summarized as the final results. Four performance criteria, i.e., correlation coefficient (R), mean absolute percentage error (MAPE), normalized root mean square error (NRMSE) and threshold static (TS), were used to evaluate the forecasting capacity of the W-RFR. The results indicated that the W-RFR can capture the basic dynamics of the daily urban water consumption. The forecasted performance of the proposed approach was also compared with those of models, i.e., the RFR and forward feed neural network (FFNN) models. The results indicated that among the models, the precision of the predictions of the proposed model was greater, which is attributed to good feature extractions from the multi-scale perspective and favorable feature learning performance using the decision trees.     

造纸黑液制水煤浆添加剂成浆性能的研究

针对淮化德士古气化炉所用的义马煤和鲁南化肥厂使用的配煤 ,进行了造纸黑液制添加剂实验室和工业制浆性能的考察。结果表明 ,其在工业应用中的添加量范围在 1.2 %～ 1.6 % (浆基 ,添加剂含固量 2 0 % ) ,对义马煤和鲁南配煤分别可以制出浓度在 6 4 .5 %和 6 9%之间 ,稳定性能良好 ,满足工业生产要求的水煤浆     

甲醇技术发展现状及生产规模经济分析

本文介绍了国内外甲醇生产消费情况及生产工艺路线，并对目前普遍应用的ＩＣＩ低压法和鲁奇低压法进行了综合分析和对比。同时，还就采用ＩＣＩ工艺或鲁奇工艺建１０万吨／年甲醇装置进行了经济分析。