Borago officinalis oil: Fatty acid fractionation by immobilized Candida rugosa lipase

γ-Linolenic acid (Z,Z,Z-6,9,12-octadecatrienoic acid), a very important polyunsaturated fatty acid is found in the free fatty acid fraction prepared by the hydrolysis of borage oil. Our aim was to enrich this fraction in γ-linolenic acid using selective esterification. Candida rugosa lipase was used as catalyst after immobilization on the following ion-exchange resins: Amberlite IRC50, IRA35, IRA93, and Duolite A7, A368, A568. In every case, immobilization modified the lipae’s specificity: palmitic, stearic, oleic, and linoleic acids were preferentially esterified compared to γ-linolenic acid, thus allowing a γ-linolenic acid enrichment of 3.0.     

3Gmap L-systems: an application to the modelling of wood

In this paper an extension of L-systems is proposed, based on three-dimensional (3D) generalized maps that allow an easier control of the internal structure of 3D objects. A first and original application of this extension is also proposed: wood modelling by growth simulation. Numerous other applications of our work are possible, in the area of computer graphics, as well as in botanical science.     

Thermo-mechanical characteristics of concrete at elevated temperatures up to 310 °C

Both, the normal strength concretes (NSC) and high strength concretes (HSC) have been used in structures which may be exposed to elevated temperatures. Concretes have also been used in the construction of radiation shielding structures. Data on the behaviour of concrete at high temperature is of prime concern in predicting the constructions and safety of buildings in response to certain accidents or particular service conditions. Prediction of mechanical behaviour, thermo-mechanical deformations and moisture migration in non-uniformly heated concrete is important for safe operation of concrete containment.This paper presents the results of an experimental investigation carried out to predict the behaviour of concrete intended for nuclear applications. For this purpose, normal concrete having compressive strength of 40 MPa was designed using limestone aggregates. Cylindrical specimens (110 mm × 22 mm) were made and subjected to heating-cooling cycles at 110, 210 and 310 °C. Measurements were taken for thermal gradient, mass loss, deformations, residual mechanical properties, thermal conductivity, and porosity. This investigation developed some important data on the properties of concrete exposed to elevated temperatures up to 310 °C. Comparisons and interesting conclusions were drawn about the thermal stability at high temperature and the residual mechanical properties of the tested concrete.     

Physical market determinants of the price of crude oil and the market premium

We analyze the determinants of the real price of crude oil by means of an equilibrium correction model over the last two decades where we focus on the aspects of the physical market that impact on the clearing price. We find that two cointegrating relations affect the changes in prices: one refers to OPEC's behavior, attempting to control prices using its market power and quotas; the other to the coverage rate of OECD expected future demand using inventory behaviors. We derive a forecasting equation for the change in oil prices which we use to assess the speculative elements of the price increases of the period 2000–05. We show that worries alien to the physical markets were the causes of the increase in oil prices and we quantify their overall impact.     

Elimination protocols in atopic dermatitis

Both dacryocystography and dacryoscintigraphy are well established in the evaluation of stenoses of the lacrimal drainage system. They provide limited information about the ductal anatomy itself and about periductal structures. MR imaging was evaluated for its capability to directly visualize the lacrimal drainage system in detail and simultaneously provide functional characterization of dacryostenosis. SUBJECTS AND METHODS: Twenty-seven lacrimal drainage systems of 23 patients suffering from epiphora were examined in an MR unit before and after conjunctival and intravenous application of Gd-DTPA using a surface coil. RESULTS: Dacryostenosis was found in 23 of 27 lacrimal systems. Stenoses were localized to the canalicular (n = 3), saccular (n = 8), and ductal (n = 12) level, and were classified as stenosis or occlusion. CONCLUSION: MR imaging with conjunctival contrast application allows within one examination both detailed morphological and functional assessment of the lacrimal drainage system with depiction of surrounding structures. Limitations arise mainly from demands on technical and patient-related preconditions.     

Self-assembling of atomic vacancies at an oxide/intermetallic alloy interface

Oxide layers grown on the surface provide an effective way of protecting metallic materials against corrosion for sustainable use in a broad range of applications. However, the growth of cavities at the metal/oxide interface weakens the adherence of the protective layer and can promote its spallation under service conditions, as observed for alumina layers formed by selective oxidation of aluminide intermetallic alloys used in high-temperature applications. Here we show that direct atomic-scale observations of the interface between an ultrathin protective oxide layer (alumina) grown on an intermetallic titanium aluminide substrate (TiAl) can be performed with techniques sensitive to the topmost atomic layers at the surface. Nanocavities resulting from the self-assembling of atomic vacancies injected at the interface by the growth mechanism of the protective oxide are observed for the first time, bringing new insight into the understanding of the fate of injected cavities in oxidation processes.     

Generalized diffusion model in optical tomography with clear layers

We introduce a generalized diffusion equation that models the propagation of photons in highly scattering domains with thin nonscattering clear layers. Classical diffusion models break down in the presence of clear layers. The model that we propose accurately accounts for the clear-layer effects and has a computational cost comparable to that of classical diffusion. It is based on modeling the propagation in the clear layer as a local tangential diffusion process. It can be justified mathematically in the limit of small mean free paths and is shown numerically to be very accurate in two- and three-dimensional idealized cases. We believe that this model can be used as an accurate forward model in optical tomography.     

The impact of print exposure quality and inference construction on syllogistic reasoning.

This study extended the work of S. Siddiqui, R. F. West, and K. E. Stanovich (1998), who studied the link between general print exposure and syllogistic reasoning. It was hypothesized that exposure to certain text structures that contain well-delineated logical forms, such as popularized scientific texts, would be a better predictor of deductive reasoning skill than general print exposure, which is not sensitive to the quality of an individual's reading activity. Furthermore, it was predicted that the ability to generate explanatory bridging inferences while reading would also be predictive of syllogistic reasoning. Undergraduate students (N = 112) were tested for vocabulary, nonverbal cognitive ability, exposure to general print, exposure to popularized scientific literature, and the ability to comprehend texts distinguished by the number of inferences that must be generated to support comprehension. Hierarchical multiple regression analyses showed that a combined measure of exposure to general and scientific literature was a significant predictor of syllogistic reasoning ability. Additionally, the ability to comprehend high-inference-load texts was related to solving syllogisms that were inconsistent with world knowledge, indicating an overlap in deductive reasoning skill and text comprehension processes. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Sintering Behavior and Optical Properties of Yttria

Sintering in air of a pure yttria powder was investigated on green samples shaped by slip casting. The "relative density/grain size" trajectory has been drawn and hypotheses concerning the mechanisms controlling grain growth and densification were formulated. Samples were fully densified by an additional hot isostatic pressing step on pre-sintered samples. After optimal polishing, optical properties were measured in the UV, visible, and infrared ranges.     

Application of neural-fuzzy controller for streaming video over Bluetooth 1.2

This paper is to introduce an application of Computational Intelligence (CI) to Moving Picture Expert Group-4 (MPEG-4) video compression over IEEE.802.15.1 wireless communication, known as Bluetooth 1.2, in order to improve picture quality. The 2.4 GHz Industrial, Scientific and Medical frequency band is used for the IEEE.802.15.1 standard. IEEE.802.15.1 can be affected by noise and interference due to other neighboring wireless devices sharing the same frequency carrier. The noise and interference create difficulties in ascertaining an accurate real-time transmission rate at the receiving end. Furthermore, the MPEG-4 codec is an object-oriented compression system and demands a high bandwidth. It is therefore difficult to avoid excessive delay, image quality degradation and/or data loss during MPEG-4 video transmission over standard systems. A new buffer entitled ‘buffer added’ has been introduced at the input of the Bluetooth 1.2 device. This buffer is controlled by a Rule-Based Fuzzy (RBF) logic controller at the input and a neural-fuzzy controller (NFC) at the output. The two new fuzzy rules manipulate and supervise the flow of video over the Bluetooth 1.2 standard. The computer simulation results illustrate the comparison between a non-CI video transmission over Bluetooth 1.2 and the proposed design, confirming that the applications of RBF and NFC do improve the image quality, reduce data loss and reduce time delay.