The influence of NaCl and CO2 on the atmospheric corrosion of magnesium alloy AZ91

The influence of NaCl and CO₂ on the atmospheric corrosion of magnesium alloy AZ91 is studied in the laboratory. Samples were exposed under carefully controlled air and flow conditions; the relative humidity was 95%, the temperature was 22.0°C and the concentration of CO₂ was < 1 ppm or 350 ppm. Different amounts of sodium chloride (0–70 μg/cm²) were added before exposure. The corrosion products were analyzed by gravimetry, ion chromatography, X‐ray diffraction and scanning electron microscopy. Mass gain and metal loss results are reported. The combination of high humidity and NaCl is very corrosive towards AZ91. However, the NaCl‐induced corrosion is inhibited by ambient concentrations of CO₂. Exposure in the absence of CO₂ gives rise to heavy pitting, with brucite, Mg(OH)₂, being the dominant corrosion product. In the presence of CO₂ a layer of hydrated magnesium hydroxy carbonate, Mg₅(CO₃)₄(OH)₂ · 5 H₂O forms. A tentative corrosion mechanism is presented that explains the behavior in the two environments.     

Effect of Oxygen Partial Pressure during Sintering on the Microstructure of Mg-PSZ with Strontia and Silica Additions

The microstructure, average grain size, and density of Mg-PSZ sintered with SrO and SiO₂ additions are found to depend on the partial pressure of oxygen in the sintering atmosphere. Over the range of 10⁻¹ to 10° atm, both the average grain size and the density increase with oxygen partial pressure, for a constant SrO/SiO₂ ratio. The partial pressure of oxygen also affects the microstructural distribution of the remnant liquid phase. At high partial pressures the liquid phase is uniformly distributed, whereas at lower oxygen pressures it is preferentially located near the surface. It is proposed that the microstructure produced by sintering is the result of a competition between liquid-phase-enhanced densification and the migration of the liquid phase to the free surface. The migration is attributed to vaporization of MgO from the liquid phase which increases with decreasing partial pressure of oxygen.     

Does the Youth Corrections System Work? Tracking the Effectiveness of Intervention Efforts With Delinquent Boys in State Custody.

This study adopted a systemic approach to studying intervention efforts with delinquent youth, examining the association between several youth corrections programs and adult criminal outcomes. Two studies were designed to use juvenile and adult court records to evaluate the effectiveness of treatment programs provided to delinquent youth in state custody. The results of Study 1 suggested that court-recorded delinquent charges can be used to estimate delinquency severity. The results of Study 2 presented a discouraging but not entirely unexpected illustration of the effectiveness of intervention efforts among delinquent youth. It was found that time spent in juvenile detention facilities, work programs, and group homes was associated with negative adult criminal outcomes. No links between time spent in youth corrections programs and positive outcomes were identified. Implications for future program evaluation efforts are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

An Analog Front‐End Circuit for ISO/IEC 14443‐Compatible RFID Interrogators

An analog front‐end circuit for ISO/IEC 14443‐compatible radio frequency identification (RFID) interrogators was designed and fabricated by using a 0.25 µm double‐poly CMOS process. The fabricated chip was operated using a 3.3 Volt single‐voltage supply. The results of this work could be provided as reusable IPs in the form of hard or firm IPs for designing single‐chip ISO/IEC 14443‐compatible RFID interrogators.     

Pseudorandomness of Basic Structures in the Block Cipher KASUMI

The notion of pseudorandomness is the theoretical foundation on which to consider the soundness of a basic structure used in some block ciphers. We examine the pseudorandomness of the block cipher KASUMI, which will be used in the next‐generation cellular phones. First, we prove that the four‐round unbalanced MISTY‐type transformation is pseudorandom in order to illustrate the pseudorandomness of the inside round function FI of KASUMI under an adaptive distinguisher model. Second, we show that the three‐round KASUMI‐like structure is not pseudorandom but the four‐round KASUMI‐like structure is pseudorandom under a non‐adaptive distinguisher model.     

Determination of Boundary Shear Stress and Reynolds Shear Stress in Smooth Rectangular Channel Flows

A method for computing three-dimensional Reynolds shear stresses and boundary shear stress distribution in smooth rectangular channels is developed by applying an order of magnitude analysis to integrate the Reynolds equations. A simplified relationship between the lateral and vertical terms is hypothesized for which the Reynolds equations become solvable. This relationship has the form of a power law with an exponent of n = 1, 2, or infinity. The semiempirical equations for the boundary shear distribution and the distribution of Reynolds shear stresses are compared with measured data in open channels. The power-law exponent of 2 gave the best overall results while n=infinity gave good results near the boundary.     

Network model approach for calculating oscillating frequency of thermoacoustic prime mover

The network model is given and used to calculate the oscillating frequency of thermoacoustic prime mover. Theoretically calculated frequency by the model is plural, whose real part denotes actual frequency of the system, and imaginary part means attenuation coefficient of acoustic pressure. Numerical calculation is made under different conditions including different acoustic cavities, spacing between each parallel plate, gas pressures and system lengths. Theoretically calculated frequency and experimentally measured frequency are in quite good agreement.     

Near‐Infrared Light‐Emitting Diodes (LEDs) Based on Poly(phenylene)/Yb‐tris(β‐Diketonate) Complexes

Near‐infrared‐emitting electroluminescent (EL) devices using blue‐light‐emitting polymers blended with the Yb complexes Yb(DBM)₃phen (DBM = dibenzoylmethane), Yb(DNM)₃phen (DNM = dinaphthoylmethane), and Yb(TPP)L(OEt) (L(OEt) = [(C₅H₅)Co{P(O)Et₂}₃]^–) have been studied. EL devices composed of Yb(DNM)₃phen blended with PPP‐OR11 showed enhanced near‐IR output at 977 nm when compared to those fabricated with Yb(DBM)₃phen/PPP‐OR11 blends. The maximum near‐IR external efficiencies of the devices with Yb(DBM)₃phen and Yb(DNM)₃phen are, respectively, 7 × 10^–5 (at 6 V and at 0.81 mA mm^–2) and 4 × 10^–4 (at 7 V, and 0.74 mA mm^–2). The optimal blend composition for EL device performance consisted of PPP‐OR11 blended with 10–20 mol‐% Yb(DNM)₃phen. A device fabricated using Yb‐(TPP)L(OEt)/PPP‐OR11 showed significantly enhanced near‐IR output efficiency, and future efforts will focus on devices fabricated using porphyrin‐based materials.