Preparation,characterization and salt-resistance of a coal based super absorbent composite

Potassium humate was extracted from brown coal.A novel super absorbent composite,poly (acrylic acid-co-acrylamide)/potassium humate (PAA-AM/KHA),was prepared by graft polymerization of acrylic acid,acrylamide and coal based potassium humate using N,N'-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator.The effects of reaction temperature,degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker,initiator and potassium humate were investigated.Salt resistance tests were also carried out.The composite prepared under optimal conditions had a potassium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water,and 349,286 and 41 g/g in 0.5 mol/L KC1,MgCl2 and AlCl3 solutions respectively.The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate.The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy.Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments.The salt resisting property of the composite is improved,production costs are reduced and the growth stimulant effect is still present.     

浅析江西农民增收的影响因素

江西农民收入在新世纪以来有了可喜的变化,但必须看到,江西农民人均纯收入与江西生产总值的增长,以及与城镇居民可支配收入的增加相比,与东部发达省份的农民收入相比,甚至与中部地区大部分省份相比,其增加还是缓幔的。江西省委、省政府历来十分重视“三农”问题。新时期江西农民收入增长比较快,但幅度不大,具体情况是工资性纯收入和外出务工收入增加较快,一产纯收入仍占主要份额,地区发展不平衡。影响江西农民收入的因素有：二、三产的比重太少,农民非企业组织收入少,农民家庭收入增长慢。     

金融危机下的LED产业发展及结构分析——以江西为例

目前,金融危机已对全球实体经济产生了巨大的冲击,2008年世界经济已明显放缓,下行风险逐步加大,前景更加不确定。中国经济虽一支独秀,但毫无疑问也会受到外部因素冲击从而影响国内经济发展,以投资和外向型贸易为特点的中国经济急需新技术和高科技领域经济增长来改变现有传统经济增长模式,而LED行业就是这样的代表性行业。本论文立足于当前世界金融危机整体发展局势,重点分析了当前金融危机对LED行业的影响,并对江西LED行业发展的整体环境及发展趋势进行了探讨和分析。     

An improvement to the simulation of phase-change heat-transfer during soil freezing and thawing

A new variable time step method, which is called the backwards calculating time step method, is presented in this paper. It allows numerical simulation of soil freezing and thawing while avoiding "phase change missing and overflowing". A sensitive heat capacity model is introduced through which the calculation errors are analyzed. Then the equation using the self-adjusted time step is presented and solved using finite differences. Through this equation, the time needed for a space cell to reach the phase change point temperature is calculated. Using this time allows the time step to be adjusted so that errors caused by "phase change missing and overflowing" are successfully eliminated. Above all, the obvious features of this method are an accelerated rate for adjusting the time step and simplifing the computations. An actual example proves that this method can accurately calculate the temperature fields during soil freezing and thawing. It is an improvement over traditional methods and can be widely used on com- plicated multi-dimensional phase change problems.     

基于Kanai-Tajimi模型的地震作用荷载新型识别方法

目的研究一种识别地震作用荷载的方法,为地震作用荷载的识别与相应结构的动力特性、损伤的识别提供一种新的途径,进一步为结构的安全性、损伤进程和耐久性等研究提供理论参考.方法利用Kanai-Tajimi模型将单位强度白噪声过程模拟为未知的地震作用,并将其作用在结构上,然后根据数值模拟计算得到的结构体系响应作为观测量,采用Kalman滤波对未知荷载状态加以识别.结果最终可以利用结构的加速度响应反演得出地震作用的等效荷载,在人工添加5%观测噪声的条件下,最大误差率为7%左右,而在人工添加10%观测噪声的条件下,最大误差率为8%左右.结论通过算例的验证,说明笔者所采用的方法精度较高,获得了较好的识别效果.     

Bone Tissue Response to the Bone-like Tissue Coating on Titanium

The objective of this study was to investigate the effects of mineralized bone nodules, formed in vitro by bone marrow stromal cells(BMSCs), on the new bone formation in bone defect and on implant surface. The mineralized bone nodules were generated by culture of Lewis rats BMSCs on titanium disks in osteogenic induction medium. The gap-healing animal model was used to create the bone defect facing the disk. The titanium disks in the presence of B group or in the absence of NB group bone nodules were randomly placed into one of the rat distal femurs. This self-control design was used to compare the bone formation in defects and on titanium surface, by Micro-CT, fluorescence staining, histological and histomorphometric analysis. The new bone formation parameters in bone defect area of B group were significantly higher than those of NB group at 2 weeks, including bone volume fraction, trabecular thickness and bone area ratio. The bone nodules pre-stained with Alizarin red disappeared mostly at 2 weeks, while the red fluorescence reappeared in the newly formed bone away from the disk surface. For the bone-implant contact, B group showed lower values than NB group at 2 weeks, but no significant difference was found at 4 weeks. Our results indicate that the mineralized bone nodules can be resorbed in vivo and promote the early osteogenesis in the bone defects, and bone nodules may be applicable for new bone generation in bone defect or modification of tissue engineering scaffold.     

民族传统体育项目引入高校体育课的研究

在高校开展少数民族传统优秀体育项目教学,不仅能使少数民族传统体育走向规范化、科学化,较好地展现学生的运动能力,培养民族文化情感,激发民族热情,更重要的是还能提高学生的身心健康和综合素质,有利于对民族传统体育的继承、发展和广泛地传播。     

红色文化:马克思主义中国化的文化棱镜

马克思主义基本原理的理论自觉、中国传统文化的文化自觉、人民群众的实践自觉的三者和谐互动与有机统一,创造与发展了中国主流意识形态与文化的特殊形态,二者构成了马克思主义中国化历程中的两个主要面相,在此进程中,生成了两种主要形态,即中国化的马克思主义理论形态和以革命遗迹为"底板"的红色文化形态。作为一种特殊的文化形态,红色文化不仅是马克思主义中国化的文化自觉和文化再造的产物,也是继续推进马克思主义中国化的文化展望的对象。     

Oxidation behavior and mechanism of aluminum oxynitride (AlON) at elevated temperatures

The oxidation behavior and mechanism of aluminum oxynitride (AlON) powder exposed to air at elevated temperatures between 800°C and 1300°C was investigated by X-ray diffractometry (XRD), scanning electron microscope (SEM), electron spin resonance (ESR), nuclear magnetic resonance (NMR), and simultaneous thermogravimetry, differential thermal analysis, and mass spectrometry techniques (TG-DTA-MS). The weight of AlON gradually increases to a maximum value at 1150°C and then decreases with further heating. Meanwhile, AlON powder undergoes chemical changes, as evidenced by lattice expansion, and turns eventually into alumina. ESR spectra reveal the occurrence of lone pair electrons in the oxidized products and the intensity of corresponding resonance signal increases before disappearing with the increase in temperature. Combined with the results of NMR and TG-DTA-MS, the measured data suggest that Al-N in [AlO₃N] tetrahedron and [AlO₅N] octahedron are gradually oxidized into Al-O-N group with lone pair electrons, which causes continuous weight gain and lattice expansion. Further oxidation at higher temperatures results in alumina and N₂.     

Engineering all-aromatic polyamide surface from hydrophilic to superhydrophobic and the accelerated strategy

Being a new kind of nanomaterials, aromatic polyamide nanofibers (ANF) have been much highlighted in recent studies. We here demonstrate an isopropyl alcohol (IPA) accelerated chemical cleavage on poly (p-phenylene terephthalamide) chopped fibers, which provides an efficient preparation method of ANF. The comprehensive study on the processes accelerated by different alcohols revealed that the preparation time of ANF in the mixed medium of dimethyl sulfoxide (DMSO)-alcohol (20:1 in volume) was shorten to 45 min and 75 min for methanol (ethanol) and isopropanol, respectively. However, the nanofibers prepared in DMSO-IPA exhibited the minimum in axial and radial dimensions, providing the finest and most uniform diameter of 16 nm. The corresponding ANF films through vacuum assisted filtration also showed the highest tensile strength of 150 MPa, in comparison with those of the ANF films prepared using other alcohols, which were about 110 MPa. Furthermore, ANF/silicon hybrid films were prepared by the ionic ring-opening reaction followed by the alkoxysilane condensation and nanoparticle fabrication. By changing the organo functional groups in the alkoxysilane, the surface of the films were adjustable in a wide contact angle range from 56° (hydrophilic) to 150° (superhydrophobic), suggesting the amendable interfacial properties potential applicable to composite fabrication with most of the resin matrix.