Syngas production via combined oxy-CO2 reforming of methane over Gd2O3-modified Ni/SiO2 catalysts in a fluidized-bed reactor

In this research, Ni/SiO₂ catalyst was modified with different amount of Gd₂O₃ and characterized with temperature-programmed desorption of CO₂ (CO₂-TPD) and NH₃ (NH₃-TPD), temperature-programmed reduction with H₂ (H₂-TPR) and X-ray diffraction (XRD). It was found that Gd₂O₃-modified Ni/SiO₂ catalysts possessed higher CO₂ adsorption and activation ability due to the formation of surface carbonate species. H₂-TPR and XRD characterizations found that the strong interaction among nickel, Gd₂O₃ and SiO₂ took place, which improved the dispersion of Ni. Gd₂O₃-modified Ni/SiO₂ catalysts exhibited higher activity and stability for the combined oxy-CO₂ reforming of methane in fluidized-bed reactor. The H₂/CO ratio in produced syngas could be controlled via controlling reaction temperature and CO₂/O₂ ratio in feed.     

"JDS-音频化渣微机综合检测系统"的应用与效果

简要介绍“JDS-音频化渣微机综合检测系统”的工作原理和应用效果，证明使用该装置是提高炼钢操作水平的一条较好途径。     

西气东输工程用X70热轧板卷屈服强度检测值波动大的探讨

对西气东输工程用X70热轧板卷检验过程中出的屈服强度σ0.5波动大的情况进行了分析，认为拉伸试样弯曲是主要原因。这一问题可通过反复压平试样，确保试样的平直度以及适当提高钢的强度的方法加以解决。     

现场总线控制系统浅谈

简述了现场总线控制系统的结构及其显优点。现场总线控制系统的结构包括：主控器、总线接口、电源、输入／输出接点、总线电揽和终端电阻。另外对其显优点做了逐一介绍。现场总线控制系统可在工业自动化控制系统中推广应用。     

Studies on the treatment of brilliant green solution by combination microwave induced oxidation with CoFe2O4

In this work the synergistic effects of microwave (MW) irradiation induced oxidation processes and CoFe₂O₄ were studied for the degradation of brilliant green (BG) from aqueous solutions. Under the optimum condition, the ratio of solid to liquid was 1:167 (0.3 g CoFe₂O₄ mixed with 50 mL of 20 mg L⁻¹ BG solution), MW power 600 W, and the time of the irradiation 2 min. And the decolorization rate could reach up to 100%. Further investigation showed that BG was degraded by MW-induced oxidation combined with CoFe₂O₄ surface adsorption. The CoFe₂O₄ could increase the efficiencies of MW degradation and be used repeatedly. The experimental results indicated that the method of MW degradation BG in the presence of CoFe₂O₄ could reduce reaction time and increase product yield.     

基于网格的知识资源挖掘研究

为满足网络上不同用户群体对个性化资源的要求,文章从网格与服务网格的概念出发,引入知识挖掘技术,提出了网格环境下的个性化知识资源挖掘实现框架,并对其实现功能与应用加以分析.     

固体超强酸S_2O_8~(2-)/SnO_2-SiO_2催化合成环己酮1,2-丙二醇缩酮

采用沉淀-浸渍法制备了固体超强酸S2O28-/SnO2-SiO2,以它为催化剂催化环己酮和1,2-丙二醇合成了环己酮1,2-丙二醇缩酮;考察了带水剂种类及用量、酮醇摩尔比、催化剂用量、反应时间对产品收率的影响,并用正交实验对反应条件进行了优化。实验结果表明,适宜的反应条件为:n(环己酮)∶n(1,2-丙二醇)=1∶1.6、催化剂用量为反应物料总质量的2.0%、带水剂环己烷用量5.0mL、反应时间50min。在此条件下,环己酮1,2-丙二醇缩酮收率达到91.47%;催化剂的稳定性良好,在重复使用5次后环己酮1,2-丙二醇缩酮收率为82.20%,活性下降的主要原因为催化剂表面积碳和吸附了有机物;经傅里叶变换红外光谱和气相色谱质谱分析表明,产物为环己酮1,2-丙二醇缩酮,纯度为100%。     

旋转式伽玛刀的辐射剂量学

旋转式伽玛刀的辐射剂量学指标的物理测试在放射性医疗设备投放医院正式临床使用前是必不可少的，是对设备及其附件的设计、加工制造、安装以及电气控制系统等的全面综合性检定。用电离室作辐射剂量学的绝对测量，用胶片法进行相对测量，给出了测量结果并进行了讨论。     

Ahch, the mouse homologue of DAX1: cloning, characterization and synteny with GyK, the glycerol kinase locus

We cloned the murine full-length cDNA encoding Ahch, the mouse homologue of DAX1 (DSS-AHC Region on Human X Chromosome, Gene1) which is the gene responsible for human X-linked adrenal hypoplasia congenita (AHC) and hypogonadotropic hypogonadism (HH). Sequence analysis revealed that the murine and human cDNAs have 65% aa identity and 75% aa similarity overall. The cysteine residues in the putative DNA binding domain, which may interact with Zn2+ ions to form zinc fingers, are 100% conserved between the two species, indicating that the novel zinc-finger structures in DAX1 may be functional. In addition, mouse interspecific backcrosses show that the Ahch gene is closely linked to the glycerol kinase locus, GyK, on the mouse X chromosome, indicating that the order of the loci is conserved in this syntenic region between mouse and human.