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排序方式: 共有10000条查询结果,搜索用时 78 毫秒
991.
992.
H.‐C. Su F.‐C. Fang T.‐Y. Hwu H.‐H. Hsieh H.‐F. Chen G.‐H. Lee S.‐M. Peng K.‐T. Wong C.‐C. Wu 《Advanced functional materials》2007,17(6):1019-1027
Highly efficient orange and green emission from single‐layered solid‐state light‐emitting electrochemical cells based on cationic transition‐metal complexes [Ir(ppy)2sb]PF6 and [Ir(dFppy)2sb]PF6 (where ppy is 2‐phenylpyridine, dFppy is 2‐(2,4‐difluorophenyl)pyridine, and sb is 4,5‐diaza‐9,9′‐spirobifluorene) is reported. Photoluminescence measurements show highly retained quantum yields for [Ir(ppy)2sb]PF6 and [Ir(dFppy)2 sb]PF6 in neat films (compared with quantum yields of these complexes dispersed in m‐bis(N‐carbazolyl)benzene films). The spiroconfigured sb ligands effectively enhance the steric hindrance of the complexes and reduce the self‐quenching effect. The devices that use single‐layered neat films of [Ir(ppy)2sb]PF6 and [Ir(dFppy)2sb]PF6 achieve high peak external quantum efficiencies and power efficiencies of 7.1 % and 22.6 lm W–1) at 2.5 V, and 7.1 % and 26.2 lm W–1 at 2.8 V, respectively. These efficiencies are among the highest reported for solid‐state light‐emitting electrochemical cells, and indicate that cationic transition‐metal complexes containing ligands with good steric hindrance are excellent candidates for highly efficient solid‐state electrochemical cells. 相似文献
993.
Various influence diagnostics in Multiple Discriminant Analysis can be found in the literature. Almost all of them are based
on the overall probability of misclassification. Two case-deletion diagnostics which evaluate the effect of the omission on
the linear functions which determine Fisher’s Linear Discriminant Rule are proposed in this paper. Both measures are based
on the L
2-norm: The first diagnostic is calculated from the data set and the second diagnostic is calculated in the minimum hypercube
which covers it. 相似文献
994.
A. D. Pogrebnyak M. V. Il’yashenko V. S. Kshnyakin V. V. Ponaryadov Sh. M. Ruzimov Yu. N. Tyurin 《Technical Physics Letters》2003,29(12):1028-1030
Chromium carbide-nickel coatings were deposited onto a technical grade copper substrate by means of a high-velocity plasma
jet of a plasmatron operating in specially selected regimes. An analysis of the coatings showed evidence of the formation
of a Ni-based solid solution, a complex chromium carbide (Cr7C3), and an fcc crystal phase with a lattice parameter of 3.614 Å. The surface of the coatings exhibits a characteristic relief
resulting from a dynamic interaction between melted and fused particles of the initial powder. The local hardness on some
areas of the surface and in depth of the coating reaches 66±4.5 HRC, while the coating adhesion strength varies from 25 to
300 MPa. 相似文献
995.
996.
Intraseptal scopolamine has differential effects on Pavlovian eye blink and heart rate conditioning.
Evaluated the effects of intraseptal scopolamine hydrobromide (40 μg) injections on Pavlovian (classical) conditioning, with tones used as the CS and a periorbital electric shock train as the UCS, using New Zealand albino rabbits. Eyeblink (EB) and heart rate (HTR) CRs were concomitantly recorded. Although injections of scopolamine into the medial septum impaired the acquisition of the Pavlovian conditioned eyelid reflex, these injections enhanced the magnitude of accompanying Pavlovian conditioned HTR decelerations. However, scopolamine applied to the lateral septal area had no effect on EB conditioning, relative to the vehicle; like medial injections, scopolamine also enhanced the magnitude of the accompanying HTR decelerations. Results are compatible with those of previous investigations indicating that medial septal dysfunction impairs somatomotor conditioning but leaves autonomic conditioning intact and that septal dysfunction produces a parasympathetic bias of the cardiovascular system. (49 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
997.
The nucleation of gas bubbles in extrusion foaming of high-pressure polyethylene is considered. Experiments show that undissolved gas microbubbles in the solution being foamed can have a significant effect on the number density of pores in the foam. A simple model for estimating the number density of supercritical nuclei is proposed. The effect of the time of mixing of gas and polymer in the extruder, the talc concentration, and the geometric characteristics of the nozzle on the number density of pores in the foam is analyzed. 相似文献
998.
MetaModel is a user-friendly program for calculating steady-state fluxes and metabolite concentrations of metabolic systems on the IBM PC and compatible computers. For any steady state that is obtained, one can then calculate a matrix of elasticity coefficients at that steady state, or a matrix of control and response coefficients. It thus offers a simple way to calculate the control structure of a pathway: it provides not only an educational tool that allows the student to verify empirically the classic summation relationships of metabolic control analysis but also a research tool for addressing 'what if?' questions about the behaviour of metabolic systems. Results can not only be printed or stored in a file, but can also be written to a special file that can be read by popular spreadsheet programs, thereby giving access to rapid, flexible and powerful methods for subsequent analysis and plotting of these results. 相似文献
999.
Specifying concurrent systems with TSL 总被引:1,自引:0,他引:1
The Task Sequencing Language (TSL), which lets programmers specify constraints on the behavior of concurrent programs, is described. The constraints, specified by high-level annotations to Ada programs, are monitored at runtime; when a violation is detected, control is returned to the user, along with information about the nature of the violation. It is argued that such a tool is a necessary crutch for human reasoning capabilities when dealing with the complexities of concurrent process interaction. The first large-scale application of TSL, the specification and validation of a distributed tasking supervisor for Ada, is described 相似文献
1000.