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41.
In the present study the possibility of using nicotine in house dust as an index of environmental tobacco smoke (ETS) exposure was evaluated in an environmental investigation of 23 children with asthma. A standardized procedure for house dust sampling of nicotine with a filter holder connected to a vacuum cleaner, for a defined time and area was developed (F-nicotine). Also, house dust sampling was carried out from the vacuum cleaner bags of the homes (VC-nicotine). There was a larger variation in VC-nicotine (13-655, median 66 microg/g) compared with F-nicotine (15-393 median 156 microg/g). There were statistically significant associations between an inquiry data based ETS exposure index on the one hand, and urinary cotinine concentrations in children (U-cotinine), F-nicotine and VC-nicotine of their homes, on the other. The strong correlation between U-cotinine and F-nicotine (rs = 0.93; P < 0.0001) indicates that the new standardized house dust sampling method should be useful in ETS exposure assessment. However, further validation by a larger sample size with repeated measurements in the same homes is needed.  相似文献   
42.
Sediments were collected on a grid from Lake St. Clair in 1970 and 1974 and from Lake Erie in 1971 and analysed for organochlorine insecticides and PCBs. Suspended solids were centrifuged from pumped water in the Detroit River in 1974. Residues of DDE, TDE and DDT were highest in sediment from the Western Basin (70.3 ppb) Lake Erie and lowest in sediment from Lake St. Clair (6.6 ppb in 1970 and 2.6 ppb in 1974). The Central and Eastern Basins of Lake Erie contained residues that fell about mid-way between these means. TDE was the predominant component of ΣDDT and was followed by DDE at approximately half this residue. While DDT represented the lowest component in lake sediments, it was the highest component in suspended solids from the Detroit River.HEOD was present in the entire lake system but at only a fraction of the level of ΣDDT. The mean residue in Lake St. Clair was only 0.1 ppb while Lake Erie sediments contained 1–2 ppb. The highest mean residue (3.6 ppb) was in suspended solids in the Detroit River. Other organochlorine insecticides were only occasionally identified.PCB residues in sediment were approximately 3 times higher than the total organochlorine insecticide residue, being highest in the Western Basin (252 ppb) and lowest in Lake St. Clair (19 ppb in 1970 and 10 ppb in 1974). The Detroit River and Central and Eastern Basins of Lake Erie had intermediate residues.Residues in Lake St. Clair indicated a decline in ΣDDT, HEOD, and PCB residues between 1970 and 1974, and this coincided with the restrictions on the materials. A core sample from the Western Basin of Lake Erie indicated that ΣDDT, HEOD and PCB began to accumulate in sediments in 1958, 1953, and 1956, respectively. This appeared to indicate a lag period of 2–5 years after wide-spread use occurred.  相似文献   
43.
The biodegradation of urea in river waters has been evaluated under laboratory conditions. Urea will degrade to ammonia at a rate depending on the bacterial state of the river water and on the water temperature. Under normal conditions no breakdown may be expected to occur at temperatures below 8°C for 14 days contact. In river waters with a high suspended solids content, simulating extreme winter river conditions, a maximum breakdown of 3–6 per cent daily of the original urea levels was found for temperatures not exceeding 8°C during the first 7 days contact.  相似文献   
44.
Fang HH  Zhang M  Zhang T  Chen J 《Water research》2008,42(4-5):903-908
Using a novel and simple method based on horizontal attenuated total reflection (HATR) by Fourier transform infrared (FTIR) spectrometry, the effective diffusion coefficient, De, of nitrate in a contaminated anthropogenic sediment was estimated as 7.34 x 10(-6)cm2 s(-1). This method, which requires as little as 1 mL of sediment sample, was able to measure the De of a chemical species with a reproducibility of +/-3% in about 5h. Based on this De and a pre-determined nitrate reduction rate, the profiles of nitrate concentration in two sediment columns were satisfactorily predicted from a mathematical model. Results showed that the profile in this aged sediment depended mainly on the diffusion of nitrate and, only to a much lesser degree, the rate of nitrate reduction. Measurements in 55 anthropogenic sediment samples collected from five locations and various depths of a contaminated site further showed that the De of nitrate increased linearly with the water content of the sediment, but decreased with the sediment density. The technique demonstrated in this study shall be applicable for the risk assessment of toxic pollutants in contaminated sediments, and for planning the spatial and time intervals of nitrate injection strategy in bioremediation.  相似文献   
45.
This study provides information on the long-term evolutions of the atmospheric methane (CH4) concentrations in Nagoya City, Japan, which were analyzed by using the continuous monitoring data observed at the eight observatory stations for 1983-1997. The 15-year records of the atmospheric CH4 concentrations were examined by means of a time-series analysis using a fast Fourier transform with a low-pass filter to elucidate the seasonal cycles and the long-term trends. The annual averages of the CH4 concentrations in Nagoya were 1.85 ppmv (parts per million by volume), 1.91 ppmv, and 1.90 ppmv in 1988, 1995 and 1997, respectively. Moreover, the annual average growth rate showed a drastic decrease from 17 ppbv (parts per billion by volume) year(-1) in 1992 to 2 ppbv year(-1) in 1993, and further down to 7 ppbv year(-1) in 1997. Comparison of the atmospheric CH4 records in Nagoya with those in global air of the northern hemisphere observed at Mauna Loa observatory in Hawaii, USA, allows us to estimate the excess concentration of CH4 in the urban atmosphere of Nagoya, which was 0.17 ppmv in 1988 and 0.15 ppmv in 1997. On a local scale, the atmospheric CH4 concentrations in the northern part of Nagoya City increased until 1992 and then gradually decreased from 1993 to 1997, although those in the south-western urban areas constantly increased at the averaged growth rate of 13 ppbv year(-1) for 1988-1997. The variation of the long-term trends of the CH4 concentrations in Nagoya may be ascribed to the emission changes from the CH4 sources due to the human activities such as waste dumping and landfills.  相似文献   
46.
The amounts of total Hg in the soils and the edible parts of seven vegetable plant crops grown in unpolluted and polluted soils were studied.The highly polluted soils contained higher levels of Hg (495 ppb) than those in the unpolluted (35 ppb). The topsoil was highly enriched with Hg than the subsoil as the result of the deposition of Hg particulates produced from the industries.Plants grown in soils near industries contained high levels of Hg up to 362 ppb. The amounts of Hg in the plant species which grown in winter were higher than those grown in summer.  相似文献   
47.
48.
"This paper assesses some of the recent attempts to explain the perceived growth reversal between metropolitan and nonmetropolitan areas in the United States during the 1970s. The paper argues that the reversal in population trends was not a one-time, radical shift in settlement trends, but rather the result of more continuous underlying industrial trends. Indeed, since 1979, population growth has again become faster in metropolitan than nonmetropolitan areas." The paper includes three sections. Regional and area population and industrial earnings growth patterns are first summarized for the 1960s, 1970s, and 1980s. Theories of polarization and polar reversal are then evaluated and found to be inadequate. Finally, a reconstruction of the neoclassical model is proposed.  相似文献   
49.
For at least two decades, expansion of low-density residential development at the wildland–urban interface has been widely recognized as a primary factor influencing the management of US national forests. We estimate the location, extent, and trends in expansion of the wildland–urban interface (WUI) in the continental United States. We mapped the WUI by determining the intersection of housing density classes computed from refined US Census data with a map of wildfire hazards based on broad forest types using definitions of WUI from the Federal Register. Our methods allowed us to provide a more spatially precise estimation of the WUI that better reflects development patterns of interest to forest land managers. We defined three wildfire hazard classes based on vegetation type. “High” severity applies to vegetation types in which stand-replacing fires dominate both historical and recent fire regimes, e.g., lodgepole pine forest. “Low” severity applies where fuels and climate foster mostly low-intensity fires, e.g., aspen-birch forest. “High (historically low or variable)” applies to vegetation types in which fires historically were of low or variable intensity, but recently have often burned at high intensity because of a century of fire exclusion, e.g., southwestern ponderosa pine forest. In 2000, the WUI that includes a 3.2 km community protection zone occupied 465,614 km2, and contained over 12.5 million housing units. This is an expansion of over 52% from 1970, and by 2030 the WUI is likely to expand to at least 513,670 km2 with the greatest expansion occurring in the intermountain west states. Roughly 89% of the WUI is privately owned land and about 65% of the WUI occurs in high or high (historically low or variable) severity fire regime classes.  相似文献   
50.
Bulletin of Engineering Geology and the Environment - La fermeture de l'Escaut oriental constitute le couronnement des travaux du Plan Delta aux Pays-Bas. Le danger de l'érosion et de...  相似文献   
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