Further studies on polyamides from bisacid a2

Earlier work on the low temperature solution polyamidation of bisacid A2 has raised a number of structural problems. Work carried out more recently showed that the problem of apparent nonisostoichiometry could be reasonably satisfactorily explained. The present paper reports the synthesis and investigates the properties of a further series of polyamides based upon Bisacid A2. More importantly, however, a detailed characterization and evaluation of the new polymers with respect to their structures is presented. This enabled us to compare the various structures in the light of the experimental evidence provided by a number of analytical and spectroscopic techniques, solution behavior, molecular weight, and thermal, morphological, and mechanical properties. Some work was also done on the effect of incorporating a small amount of a trifunctional monomer into the polyamide system.     

Dynamics of hydrated iron(II) cations in nafion polymer membranes

Mössbauer studies of Fe²⁺ in water-soaked nafion polymer membranes in the temperature range between 90 K and 250 K have been performed. Above a critical temperature (～ 180 K) the spectra exhibit both elastic narrow absorption lines and quasielastic broad lines. These spectra are typical of bounded diffusion phenomena observed by Mössbauer spectroscopy in macromolecular systems like haemoglobin, myoglobin and ferritin. Similar spectral shapes have been observed by quasielastic neutron scattering from water in nafion membranes. Within 50 K above the critical temperature the total Mössbauer absorption area decreases by an order of magnitude whereas the narrow absorption line decreases by two orders of magnitude. The results are interpreted in terms of bounded diffusive motion of the iron. Using a model based on overdamped harmonically bound Brownian motion, the essential parameters of the iron motion can be derived as a function of temperature. The iron motion most probably reflects the motion of a large Fe²⁺ complex, e.g. Fe(H₂O)²⁺₆, which is attached to the polymer side chains via the sulphonic group.     

Radiation safety of a population inhabiting the area where a nuclear facility is situated

Translated from Atomnaya Énergiya, Vol. 67, No. 2, pp. 81–83, August, 1989.     

Scrubbing Hydrogen Sulfide from Gases. A Rational Approach

Worsening of the environmental situation in many regions of Russia in recent decades is to a great degree due to production and refining of oil and gas with a high hydrogen sulfide content. Industrial methods of utilization of hydrogen sulfide are extremely irrational: it is either burned in flares or used for production of sulfur whose quality and quantity pose new problems related to its use.     

Transition temperature of anisotropic superconductors with Kondo impurities: Square well model

The Eliashberg equations for an anisotropic superconductor containing Kondo impurities are approximated analytically using the square well model for the electron-phonon interaction. Anisotropy is incorporated via a separable model and the impurities are treated within the Matsuura, Ichinose, and Nagaoka (MIN) formalism. Explicit expressions for the reduction of the superconducting transition temperature are obtained. The derived formulas are generalizations of the MIN results to include both anisotropy and weak electron-phonon coupling effects.     

Simultaneous a posteriori detection and identification of a predetermined number of quasi-periodic fragments in a sequence based on their segments

An a posteriori (off-line) approach to the simultaneous detection and identification of quasi-periodic fragments in a numerical sequence using their segments is analyzed. The solution of the problem is proposed for the case when the number of the desired fragments is known. The following assumptions are made. (i) Each desired fragment of the numerical sequence coincides with an element of the given alphabet of the reference sequences that have equal lengths (i.e., number of elements). (ii) Only a segment (part) of the desired fragment can be processed; unprocessable parts of the fragment are interpreted as lost data. (iii) The numbers of the elements in the sequence that correspond to the beginning of the desired fragment and the boundaries of the segment in the fragment represent deterministic (rather than random) quantities; the boundaries of the segments are different for different fragments; and the desired fragments are quasi-periodic in the sequence. (iv) Gaussian uncorrelated noise impedes the observation of the sequence that contains quasi-periodic segments of the reference sequences. It is demonstrated that the essence of the problem under study lies in the verification of a set of hypotheses on the mean value of a random Gaussian vector (the power of this set exponentially increases with an increase in the dimension of the vector—the sequence length). An effective a posteriori algorithm that provides for maximum-likelihood detection and identification is validated. The estimates of the time and space complexity are related to the parameters of the problem. The results of the numerical simulation are presented. This work was supported by the Russian Foundation for Basic Research, project no. 03-01-00036 and 06-01-00058. Aleksandr V. Kel’manov. Born April 25, 1952. Graduated from Izhevsk State Technical University in 1974. Received candidate’s degree in 1980 and doctoral degree in 1994. Leading researcher of the Sobolev Institute of Mathematics, Siberian Division, Russian Academy of Sciences. Scientific interests: mathematical methods for pattern recognition; discrete optimization; effective algorithms for the analysis and recognition of random sequences; algorithms for the solution of applied problems; and methods and algorithms for the processing, recognition, and synthesis of voice signals. Author of more than 120 papers. Sergei A. Khamidullin. Born March 28, 1952. Graduated from Novosibirsk State University in 1974. Received candidate’s degree in 1997. Senior researcher of the Sobolev Institute of Mathematics, Siberian Division, Russian Academy of Sciences. Scientific interests: mathematical methods for pattern recognition; discrete optimization; effective algorithms for the analysis and recognition of random sequences; algorithms for the solution of applied problems; and methods and algorithms for the processing, recognition, and synthesis of voice signals. Author of more than 80 papers.     

Simplified steady-state model of an SCR-inverter-basedload-commutated commutatorless series motor

This paper presents a simplified analytical model of a silicon-controlled-rectifier based, load-commutated inverter driven, commutatorless series motor to predict its speed-current, torque-current and torque-speed characteristics. The model has been formulated, keeping in view the steady state equivalent circuit of a conventional DC series motor. The proposed analytical expressions relating torque and current with speed are found to follow an inverse law and that relating torque and current is found to be parabolic, as is expected in a "series" machine. The drive has been implemented, loaded with a DC generator and experimentally similar characteristics have been obtained, as predicted by the analytical model. The characteristics obtained experimentally are seen to follow the ones, predicted by the analytical model closely     

A correlation between the microhardness and the mobility of twinning dislocations in bismuth crystals exposed to constant magnetic field and pulsed electric field

It is established that bismuth crystals under the simultaneous action of a constant magnetic field and current pulses exhibit a correlation between the microhardness and the mobility of twinning dislocations. It is shown that application of the external fields favors translation of the twinning dislocations along the twin-matrix boundaries.     

TEM study of PLZT ceramics

The microscopic structures of PLZT(7.9/70/30 and x/65/35, x = 7 or 8) ceramics were studied by means of transmission electron microscopy. The presence of micro-regions in PLZTs was first verfied.