Aroused problems in the deposition of diamond-like carbon films by using the liquid phase electrodeposition technique

Hydrogenated diamond-like carbon (DLC) films were prepared by using liquid phase electrodeposition technique. The effects of the applied potential and the carbon sources on the deposition process and film structures were studied. It has been found that the organic liquids with high dielectric constants, small viscosities and the methyl group bonding to the polar group are appropriate carbon sources. The increasing of potential improves the formation of sp³ carbon during the deposition process. In a high electric field, organic molecules are polarized and reacted on the surface of the electrode, turning out DLC and other products. It is believed that the reaction follows a polarization-reaction mechanism.     

LaNiO3薄膜热稳定性的研究

LaNiO3导电金属氧化物薄膜在现代应用科学研究中作为电极和过渡阻挡层倍受青睐，它具有很好的导电特性和稳定性。该文采用射频溅射法制备了具有(100)择优取向的赝立方结构LaNiO3-x薄膜，并进行了原位热处理。实验结果表明，在265℃的处理条件下，LaNiO3薄膜表现出不稳定性，晶格中的氧在2h内失去了2.7％。氧的损失对品格结构没有明显影响，但薄膜的导电性能明显下降，折射率和消光系数也具有相同幅度的下降。对薄膜的应用具有一定的影响。该文从LaNiO3薄膜的导电机理方面对实验现象给出了分析和解释。     

B－ISDN中的拥塞控制技术

Ｂ－ＩＳＤＮ是现代电信网的发展方向，拥塞控制技术则是其中的一个重要问题。由于Ｂ－ＩＳＤＮ采用新的信息传递方式──ＡＴＭ，使传统的拥塞控制方法不再适用。本文依据ＩＴＵ－Ｔ有关建议的最新内容对Ｂ－ＩＳＤＮ拥塞控制的基本思想、工作机制以及其中的主要功能作了较为详细的分析讨论，并提出了一些Ｂ－ＩＳＤＮ拥塞控制技术中尚需进一步研究的问题。     

川东地区长兴组缝洞型储层的识别

本文针对四川东部地区上二叠统长兴组(P_2~2)缝洞型储层的低孔、低渗及非均质性等特点,分析了影响这类储层识别的主要因素,提出了利用现有的地球物理测井手段定性识别储层的指标和定量综合识别储层的方法,这可望提高测试成功率。     

激光微焊接质量的模糊识别技术研究

讨论了激光微焊点焊接质量的模糊识别的概念，数学模型及其应用方法，并介绍了系统的硬件组成。     

Hydrogen Reduction and Microstructural Changes of ISF Sinter

The reduction rate and microstructural changes of imperial smelting furnace (ISF) sinter have been investigated by means of thermogravimetric analysis, X-ray difFraction (XRD), scanning electron microscope (SEM ), energy dispersive analysis of X-ray (EDAX) and optical microscope.It is demonstrated that the overall reaction rate of the reduction is influenced by temperature and hydrogen partial pressure in H2 /N2 gas mixtures. There are two distinct zones observed in the partially reduced sinter. The reduction of zincite proceeds predominantly in a narrow range between the two zones, while the reduction of tead oxide and silicate takes place throughout the sinter. The differences between zincite and lead oxide or silicate in reducibility are analysed by thermodynamlcs. The phase transformations and microstructural changes occurring during the reduction process are discussed     

二烷基硫代磷酸铵的捕收性能

本文研究了二烷基硫代磷酸铵（ＲＯ）２ＰＳＯＮＨ４（Ｒ＝乙基、丁基、己基、烯丙烯）系列捕收剂对非硫化矿孔雀石、锡石、赤铁矿、白铅矿、方解石和菱锌矿的浮选性能，并就药剂结构与性能关系进行了分析讨论．     

Quantum-mechanical reaction rate constants from centroid molecular dynamics simulations: Barrier crossing in an asymmetrical double-well

Quantum-mechanical reaction rate constants were calculated from centroid molecular dynamics (CMD) simulations, for the case of barrier crossing in an asymmetrical double-well potential bilinearly coupled to a harmonic bath. The calculation is based on a recently proposed formulation of the reaction rate constant in terms of the position—flux correlation function, which can be approximated via CMD in a well-defined manner. The predictions of CMD and various simplified versions of it are compared to exact results, which were obtained via the quasi-adiabatic propagator path integral (QUAPI) method, and/or path integral quantum transition state theory (PI-QTST). The predictions based on CMD are found to be in good agreement with both.     

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.