悬浮液进样-火焰原子吸收光谱法测定茶叶中的微量铬

将茶叶悬浮于琼脂胶体中制成悬浮液 ,直接喷入空气 -乙炔火焰 ,用火焰原子吸收光谱法测定茶叶中的微量铬 ,方法简便、快速、灵敏度和精密度高、测定结果与用灰化法处理样品一致 ,检验表明 ,两种样品前处理方法之间无显著性差异。相对标准偏差为 3.4 %～ 6 .1% ,加标回收率为 95 .7%～ 10 3.8 %。     

对叔丁基苄胺的合成研究

摘要选择Delepine反应法的路线合成对叔丁基苄胺，并对反应投料比、反应温度及酸化后的反应时间进行了优化试验，得到了较好的反应条件：反应温度为40℃，对叔丁基苄氯与乌洛托品投料比为1：1；加入酸和醇后的保温时间为2h，从而使反应收率稳定在90％以上，含量达到95％。     

Preparation of micro-patterned surfaces of Si-N-O films and their influence on adhesion behavior of endothelial cells

Microgrooves were prepared on Si(100) surface by photolithography and wet etching.Subsequently,Si-N-O films were deposited on the microgrooves by unbalanced magnetron sputtering(UBMS) and micro-patterned surfaces of Si-N-O films were obtained.The size of the micropatterns was measured by surface profilometer.The chemical composition of Si-N-O films were characterized by X-ray photoelectron spectrometry(XPS) and the wettability of the micropatterned surfaces was evaluated by contact angle measurement.The beh...     

Preparation,characterization and salt-resistance of a coal based super absorbent composite

Potassium humate was extracted from brown coal.A novel super absorbent composite,poly (acrylic acid-co-acrylamide)/potassium humate (PAA-AM/KHA),was prepared by graft polymerization of acrylic acid,acrylamide and coal based potassium humate using N,N'-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator.The effects of reaction temperature,degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker,initiator and potassium humate were investigated.Salt resistance tests were also carried out.The composite prepared under optimal conditions had a potassium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water,and 349,286 and 41 g/g in 0.5 mol/L KC1,MgCl2 and AlCl3 solutions respectively.The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate.The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy.Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments.The salt resisting property of the composite is improved,production costs are reduced and the growth stimulant effect is still present.     

基于Java3D的虚拟雕塑系统的设计与实现

针对雕塑作品构思和设计阶段的需求,开发了一个基于Java3D中索引曲面造型方法的虚拟雕塑系统.可以用简单的交互操作,模仿雕塑的手工过程,修改形体几何信息.通过对变形结果的展现、比较和修改,优化设计效果,给出修改形体拓扑结构的实现方法,丰富了虚拟雕塑操作的种类,提高了模型的变形能力.该系统操作方便,对用户使用的技术水平要求低,与专业雕塑人员习惯操作比较吻合,并可推广到工艺品、玩具、景观的方案设计等多个领域.     

钛纳米改性聚合物防腐涂料的研究

为保护大庆油田三元复合液中油管,以钛纳米改性聚合物为主要原料,研制了钛纳米改性聚合物重防腐涂料.采用透射电子显微镜(TEM)研究了钛纳米改性聚合物平均粒径.采用正交试验法,确定最佳原料配比.采用扫描电子显微镜(SEM)研究了漆膜腐蚀.采用金相显微镜研究了钛纳米改性聚合物在漆膜中的分布.探讨了油管的腐蚀机理和钛纳米涂料的防护机理.实验结果表明:钛纳米含量为6%时,涂料具有最佳的防腐蚀效果,能很好的保护大庆油田三元复合液中的油管,并具有优异的抗化学药品介质的腐蚀性能.     

彩钢岩棉夹芯屋面板、墙面板节点性能研究

为了掌握彩钢岩棉夹芯屋面板、墙面板与檩条的螺钉连接节点抗拉破坏机理,采用理论分析、试验验证及有限元模拟相结合的方法研究了不同钢板厚度及芯材厚度时节点破坏情况.分析结果表明:屋面板节点连接破坏是由于钢板局部屈曲引起的,墙面板则是钢板被冲剪破坏造成的,同时,结合对有限元模拟结果的回归,提出了节点承载力设计公式,可为以后节点设计提供参考.增加岩棉刚度及其与侧向钢板的粘结,或增加钢板厚度对提高屋面板节点极限承载力起着重要作用.     

采用离散元法分析路面结构的疲劳特征

为了在考虑疲劳损伤和恢复性能的基础上,获取路面结构在重复荷载作用下的疲劳特征,采用离散元方法建立了路面结构模型,并分析了在正弦重复荷载作用下路面结构沥青层底部的受力特性.由于路面荷载的随机性,分别以荷载大小、荷载间歇时间、荷载作用次序为考察对象,分析其对路面结构沥青层底受力特征的影响.研究结果表明:随着周期荷载作用次数的增大,沥青层底部拉应力快速增大至某一基础值,并在此基础值附近呈周期性波动,拉应变则在以一定幅值波动的同时,呈现整体水平先急剧增大后缓慢增大的规律;延长荷载作用的间歇时间,虽然一定程度上增大了拉应力和拉应变的波动幅值,但却显著降低了沥青层底拉应力和拉应变的整体水平;不同的荷载作用次序在沥青层底引起的应力应变状态不同,从小至大序列的荷载对沥青层造成的损伤明显小于从大至小序列的荷载.     

Surface performance of workpieces processed by electrical discharge machining in gas

The surface performance of workpieces processed by electrical discharge machining in gas(dry EDM)was studied in this paper.Firstly,the composition,micro hardness and recast layer of electrical discharge machined(EDMed)surface of 45 carbon steels in air were investigated through different test analysis methods.The results show that the workpiece surface EDMed in air contains a certain quantity of oxide,and oxidation occurs on the workpiece surface.Compared with the surface of workpieces processed in kerosene,fewer cracks exist on the dry EDMed workpiece surface,and the surface recast layer is thinner than that obtained by conventional EDM.The micro hardness of workpieces machined by dry EDM method is lower than that machined in kerosene,and higher than that of the matrix.In addition,experiments were conducted on the surface wear resistance of workpieces processed in air and kerosene using copper electrode and titanium alloy electrode.The results indicate that the surface wear resistance of workpieces processed in air can be improved,and it is related with tool material and dielectric.     

Web数据挖掘可视化研究与应用

通过Web数据挖掘算法研究Web服务器日志,阐述Web数据挖掘基本流程,利用(.NET)开发组件可视化展示Web数据挖掘信息,以提供决策支持.