Autonomic Self‐Healing of PEDOT:PSS Achieved Via Polyethylene Glycol Addition

Self‐healing electronic materials are of primary interest for bioelectronics and sustainable electronics. In this work, autonomic self‐healing of films obtained from mixtures of the conducting polymer poly(3,4‐ethylenedioxythiophene) doped with polystyrene sulfonate (PEDOT:PSS) and polyethylene glycol (PEG) is reported. The presence of PEG in PEDOT:PSS films decreases the elastic modulus and increases the elongation at break, thus leading to a softer material with enhanced self‐healing characteristics. In situ imaging of the cutting/healing process shows that the healing mechanism is likely due to flowing back of the material to the damaged area right after the cutting.     

Radio frequency response of flexible microstrip patch antennas under compressive and bending loads using multiphysics modeling approach

This research article studies the effect of compression and bending loads on resonant frequency of microstrip patch antennas using COMSOL Multiphysics software (will be called COMSOL hereafter). In this study, copper microstrip patch antenna of dimension 30 mm × 25 mm on polydimethylsiloxane (PDMS) substrate of dimension 50 mm × 50 mm is considered. The interface bonding is assumed to be ideal between the patch and substrate. Both Ansoft HFSS and COMSOL are used to model and analyze the original geometry of the microstrip patch antenna without applying physical load to make sure that the design and the impedance match is satisfactory. Then, COMSOL is used to find deformed shape of the microstrip patch antenna under different values of compression and bending loads. The deformed geometries are reanalyzed using COMSOL radio frequency (RF) simulation. The resonant frequencies at different load levels are obtained and the effect of loading and boundary conditions on the resonant frequency shift is discussed.     

Structure–process–yield interrelations in nanocrystalline cellulose extraction

In order to improve the extraction of nanocrystalline cellulose (NCC) from sulfuric acid hydrolysis of chemical pulps, we have studied the effect of hydrolysis conditions on the degree of polymerization (DP), the extent of sulfation, morphological, and solid‐state characteristics of the extracted materials vis‐à‐vis yield. Our results demonstrate that sulfation plays a significant role in (i) determining the yield of, and (ii) imparting the unique solid‐state characteristics to, the extracted, H₂O‐insoluble cellulose nanomaterial from sulfuric acid hydrolysis. The hydrolysis process is itself proven to be highly reproducible, and NCC with high crystallinity (>80%) and a yield between 21% and 38% could be extracted from a fully bleached, commercial softwood kraft pulp using 64 wt.% sulfuric acid at 45–65°C after freeze drying. The NCC aggregates, with iridescent patterns typical of chiral nematic materials, are parallelepiped rod‐like structures which possess cross‐sections in the nanometer range and lengths orders of magnitude larger, resulting in high aspect ratios. The Ruland–Rietveld analysis was employed to precisely resolve X‐ray diffraction patterns and obtain information on crystallite size, crystalline and amorphous areas, and crystallinity of the extracted materials.     

Rheological and mechanical properties of poly(lactic acid)/polystyrene polymer blend

Properties modification by blending polymers has been an area of immense interest. In this work, rheological and mechanical properties of poly(lactic acid)/polystyrene (PLA/PS) blends were investigated. PLA/PS blends in different ratios were prepared using a laboratory scale single screw extruder to obtain (3 mm) granules. Rheological properties were studied using a capillary rheometer and the Bagley’s correction was performed. True shear rate (γ _r ), true shear stress (τ _r ), and true viscosity (η _r ) were determined, the relationship between true viscosity and (1/T) was studied for PLA70 blend and the flow activation energy at a constant shear stress (E _τ ) and a constant shear rate (E _γ ) was determined. The mechanical property measurements were performed at room temperature. Stress at break and strain at break were determined. The results showed that PLA/PS blend exhibited a typical shear-thinning behavior over the range of the studied shear rates, and the viscosity of the blend decreased with increasing PLA content. Also it was found that no equal-viscosity temperature exists between PLA and PS. The mechanical results showed immiscibility between PLA and PS in the blend.     

Synthesis and solution properties of poly(acrylamide-styrene) block copolymers with high hydrophobic content

Hydrophobically associating block copolymers of polyacrylamide/styrene with a high hydrophobe content were synthesized using micellar copolymerization under various conditions of surfactant and initiator concentrations with the objective of determining the conditions that produce optimum solution properties for enhanced oil recovery. Solubilities, aqueous solution viscosities and interfacial properties with air and oil of the copolymers were investigated. The influence of salt on the solution properties was also studied. Nature of hydrophobic sites and onset of hydrophobic association were studied by measuring the fluorescence of pyrene in polymer solutions. Optimum solution properties were obtained for copolymers synthesized under conditions of high surfactant and initiator concentrations. The copolymers displayed substantial thickening properties at low concentrations with enhanced thickening in the presence of salt. The interfacial tensions of the aqueous solutions with n-decane and air were also reduced. Interfacial properties were slightly sensitive to salt concentration. The copolymer solutions showed shear and temperature thinning behaviors typical of polymer solutions.     

Surfaces with Adjustable Features—Effective and Durable Materials for Water Desalination

Materials based on PVDF with desirable and controllable features were successfully developed. The chemistry and roughness were adjusted to produce membranes with improved transport and separation properties. Membranes were activated using the novel piranha approach to generate OH-rich surfaces, and finally furnished with epoxy and long-alkyl moieties via stable covalent attachment. The comprehensive materials characterization provided a broad spectrum of data, including morphology, textural, thermal properties, and wettability features. The defined materials were tested in the air-gap membrane distillation process for desalination, and improvement compared with pristine PVDF was observed. An outstanding behavior was found for the PVDF sample equipped with long-alkyl chains. The generated membrane showed an enhancement in the transport of 58–62% compared to pristine. A relatively high contact angle of 148° was achieved with a 560 nm roughness, producing a highly hydrophobic material. On the other hand, it was possible to tone the hydrophobicity and significantly reduce adhesion work. All materials were highly stable during the long-lasting separation process and were characterized by excellent effectiveness in water desalination.     

MHD flow over an inclined radiating plate with the temperature‐dependent thermal conductivity,variable reactive index,and heat generation

We study the effects of higher‐order chemical reaction and heat generation on coupled heat and mass transfer by MHD mixed convection from a permeable radiating inclined plate with the thermal convective boundary condition. The governing boundary layer equations are formulated and transformed into a set of similarity equations using dimensionless similarity variables developed by Lie group analysis. The resulting equations are then solved numerically using Maple 13 which uses a fourth–fifth order Runge–Kutta–Fehlberg algorithm for solving nonlinear boundary value problems. A representative set of numerical results are displayed graphically and discussed to show some interesting aspects of the parameters: convective heat transfer (γ), the angle of inclination (α), generation order of chemical reaction (n), reaction rate (λ), the Prandtl number (Pr), and the Schmidt number (Sc) on the dimensionless axial velocity, the temperature, and the concentration profiles. Also effects of pertinent parameters on the skin friction factor, the rate of heat, and the rate of mass transfer are obtained and displayed in tabular form. Good agreement is found between the numerical results of the present paper with the earlier published works under some special cases. © 2012 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20409     

Investigation of combined heat and mass transfer by Lie group analysis with variable diffusivity taking into account hydrodynamic slip and thermal convective boundary conditions

The present paper investigates heat and mass transfer over a moving porous plate with hydrodynamic slip and thermal convective boundary conditions and concentration dependent diffusivity. The similarity representation of the system of partial differential equations of the problem is obtained through Lie group analysis. The resulting equations are solved numerically by Maple with Runge–Kutta–Fehlberg fourth–fifth order method. A representative set of results for the physical problem is displayed to illustrate the influence of parameters (velocity slip parameter, convective heat transfer parameter, concentration diffusivity parameter, Prandtl number and Schmidt number) on the dimensionless axial velocity, temperature and concentration field as well as the wall shear stress, the rate of heat transfer and the rate of mass transfer. The analytical solutions for velocity and temperature are obtained. Very good agreements are found between the analytical and numerical results of the present paper with published results.     

Identification and safety evaluation of Bacillus species occurring in high numbers during spontaneous fermentations to produce Gergoush, a traditional Sudanese bread snack

Gergoush is a naturally fermented Sudanese Bread snack produced in three fermentation steps (primary starter, adapted starter and final dough), followed by three baking steps for a half to one hour at above 200 °C. This study examines the microbiota of two sets of fermentations performed at a traditional production site in Khartoum, Sudan in 2006 and 2009, respectively. In 2006 four different milk/legume based primary starters (faba bean, chick pea, lentil and white bean) were sampled in order to enumerate and identify the Bacillus at species or group level. In 2009 specific focus was on the enumeration and safety evaluation of the dominant Bacillus cereus group species occurring during various Gergoush productions (including the three fermentations steps and after baking). In 2006, the primary starters contained Bacillus spp. in the order of between 7.7 and 8.1 log₁₀ CFU/g. Species identifications were performed by M13-PCR typing using the Escherichia coli phage M13 derived primer PM13 combined with internally transcribed 16-23S rRNA PCR, 16S rRNA gene and gyrA or gyrB gene sequencing, and selected phenotypic tests. Depending on the legume used, 40-68% of the isolates were identified as B. cereus sensu lato, 16-27% as Bacillus licheniformis, 8-32% as Bacillus subtilis and 4-20% as Bacillus sonorensis. During the second set of fermentation trials performed in 2009, the Bacillus spp. and B. cereus occurred in numbers of between 7.7-9.9 and 6.1-7.8 log₁₀ CFU/g, respectively, while no bacteria were detected after baking. A total of 180 B. cereus sensu lato isolates from four different primary starters, adapted starters and final doughs were further identified as B. cereus sensu stricto (118 isolates) and Bacillus thuringiensis (62 isolates). The safety of Gergoush was evaluated based on the counts and toxin gene profiles of the dominant B. cereus species. Considering that no bacteria survived the baking process, and that the cereulide synthetase gene cesB involved in the production of the heat stable emetic toxin cereulide was not detected in any of the investigated B. cereus isolates, the results indicate, that Gergoush produced at the traditional production site is safe for human consumption. This study is the first to identify the Bacillus of Gergoush to species level, and it is the first to perform a safety evaluation of the product, based on the dominant B. cereus species.     

Unsteady MHD natural convection flow past an infinite vertical porous plate with radiation absorption effects

In this paper, we have explored the unsteady hydromagnetic free convective flow over an infinite perpendicular porous plate with temperature resource and/or radiation absorption. The prevailing equations are subsequently resolved systematically by utilizing perturbation methodology. The velocity, temperatures as well as concentrations sketches are shown in graphics. The impacts in the flow area for dissimilar leading parameters have been explored. Also, the skin friction, Nusselt quantity along with Sherwood quantity are computed with different parameters and mentioned in the tables. The velocity diminishes with escalating in the chemically reacting parameter as well as improves with an increment in temperature resource parameters. The temperature field reduces with an augment in the Prandtl number, whereas it enlarges with an augment in temperature absorption parameters. The concentrations field is enhanced by an amplifying in chemically reacting variable, whereas it lessens with an amplifying Schmidt number.