陶瓷电容器的制备工艺概述

简介了新型陶瓷电容器的优点、功能、类型和发展现状及表面层陶瓷电容器、表面层型陶瓷电容器和晶界型陶瓷电容器的产生机理和区别，和影响陶瓷电容器性能的诸多因素，如显微结构、掺杂元素和包覆改性等；回顾了国内外陶瓷电容器的烧成工艺发展历史，如高温一次烧成、低温一次烧成、独石法和激光辐射法等；展望了陶瓷电容器在21世纪的研究和应用前景。     

顶空固相微萃取-气相色谱法测定苯胺类化合物

应用自制羟基-二苯并冠醚(OH-DB14C4/OH-TSO)为涂层的固相微萃取探头,采用气相色谱法测定苯胺(A)、间甲苯胺(MT)、N,N-二乙基苯胺(NNDEA)、N-乙基间甲苯胺(NEMT)和3,4-二甲基苯胺(3,4-DMA).并对固相微萃取的最佳条件进行了优化.顶空固相微萃取-气相色谱法的检测限(LOD)为0.17～0.98 ng·ml-1,相对标准偏差(RSD)为3.23%～6.20%,线性范围(LR)为0.11～29 μg·ml-1.对药厂废水的3,4-DMA进行了分析,其回收率为86%～90%.     

有机浆料发泡法制备多孔羟基磷灰石

本文以湿法合成的羟基磷灰石粉体为原料,采用树脂、异氰酸与水发泡工艺制备多孔生物陶瓷材料。采用浆料发泡法制得的生物陶瓷材料具有三维无序孔和二维直通孔复合结构,其总气孔率可达70%～85%;宏观孔径主要分布在0.3～0.6mm之间,微观孔径主要分布在1～3μm之间,抗压强度可达0.85MPa。通过控制烧结温度,可以调节生物陶瓷材料中羟基磷灰石(HAP)和β-磷酸三钙(β-TCP)的成分配比,从而使之满足多孔生物陶瓷材料生物相容性和生物降解性的要求。     

Moisture sorption of a three‐dimensional braided carbon fiber–epoxy composite under different media

A three‐dimensional braided carbon fiber–epoxy (C_3D/EP) composite was prepared by the vacuum‐assisted resin transfer molding (VARTM) technique. Its moisture absorption behavior under different media was characterized and compared with a unidirectional composite. Similar to the unidirectional composite, diffusion in the 3D composite obeys Fick's second law of diffusion when immersed in distilled water and phosphate‐buffered saline. In HCl and NaOH solutions, no Fickian behavior was observed. The similarity between the unidirectional and 3D composites suggests that fiber structure does not change diffusion pattern. However, the two composites showed different diffusion parameters (k, D, and M_e) in each medium studied. The 3D composite showed lower k, D, and M_e values because of its stronger hindrance effect to transport of moisture molecules. Diffusion in PBS is slower than that in distilled water because of the presence of heavy ions, but the diffusion pattern remains unchanged. In HCl, the diffusion behavior of the two composites cannot be described by Fick's law. In addition, the k value calculated from the initial linear part of the moisture sorption curve is much lower than that in distilled water. Diffusion in NaOH is unusual; the uptake initially increases rather rapidly but quickly drops, which is likely caused by the extensive solubility of the polymer matrix. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 507–512, 2005     

从稀珍残片研究结果论国宝油滴建盏的特质

根据90年代以来仅有的三块出土稀珍油滴残片的科学研究结果,间接论证了国宝油滴天目的特质。这类稀珍油滴建盏釉的化学组成与其他建盏显著不同,其特点为低Fe_2O_3、低Al_2O_3和高SiO_2。油滴斑的形成与建盏釉的沸腾效应密切相关。在仿制时,除了适当的釉配方之外,关键在于适当工艺条件下改善油滴斑发育所形成的显微结构与选择若干加入物以提高其镜而反射率。     

Mechanism of Mechanical Strength Increase of Soda–Lime Glass by Aging

Two models have been proposed to explain the mechanical strength increase of abraded or indented soda–lime glasses upon aging, namely, crack tip blunting and the release of residual tensile stress near the crack tip. To clarify the mechanism, the time dependence of the strengthening of an abraded soda–lime glass was investigated. Effects of aging media, such as moist air, distilled water, 1 N HCI and 1 N NaOH solutions, as well as the abrasion flaw depth, were determined. The strength increase rate in water of abraded soda–lime glass was compared with those of borosilicate and high-silica glasses. The effect of stressing during aging was also investigated. It was found that the rate of strength increase was faster with decreasing abrasion flaw depth and with decreasing chemical durability. For a given flaw depth, an acidic solution produced the fastest strengthening. The strengthening rate was found to accelerate because of the "coaxing'effect of stressing during aging. From these observations, it was concluded that the strengthening rates relate to the diffusion process and chemical reactions, especially the alkali–hydrogen (or hydronium) ion-exchange reaction, near the crack tip. The role of the residual tensile stress appears to be similar to that of the applied tensile stress, helping the diffusion process near the crack tip. The observed strength increase of soda–lime glass by aging was thus attributed to the effective blunting of the crack tip geometry by the glass–water reaction.     

管理信息系统人机交互优化方法

由于管理信息系统的结构越来越复杂、影响因素越来越多,根据人机交互方法研究管理信息系统具有十分重要的理论意义和应用价值.针对管理信息系统人机交互问题,提出了一种遗传神经网络方法,采用具有高度非线性映射能力的结构化神经网络来拟合管理信息系统人机交互模型的输入输出关系,利用具有全局寻优能力的遗传算法来训练结构化神经网络的参数,应用遗传算法对神经网络模型进行优化设计.上述方法从遗传算法的优化过程中抽取一些知识,采用知识来指导遗传算法的后续优化过程.     

离散零空间算法在机织物仿真中的应用

针对机织物卡尔丹角多体模型维数较高,计算效率不理想的问题,提出采用离散零空间算法降低多体动力学方程维数,减少计算复杂度和约束违约所导致的数值漂移.首先结合离散零空间等效变换消去拉格朗日乘子项,然后进行结点参数化,实现两次系统降维,提高机织物仿真速度.通过KES剪切试验与仿真,验证了上述算法应用的可行性.通过仿真计算复杂度及效率特征指标对比,反映出优化方程的降维优势和计算高效,尤其适用于大型织物仿真.     

改进复杂网络模型的形状特征提取

目的 传统的基于欧氏距离的复杂网络表示方法容易受形状的非刚性变形影响。鉴于此,提出一种基于复杂网络模型与相对一致性距离相结合的形状特征提取方法。方法 首先,提取形状的边界轮廓点作为网络的节点,利用节点间的相对一致性距离作为边的权值构建初始的复杂网络模型;然后,利用阈值演化方法对初始网络模型进行动态演化,得到一系列子网络;最后,提取不同演化阶段下子网络的拓扑特征,实现对形状特征的提取。结果 分类和检索实验结果表明,相比于传统的复杂网络描述方法,本文方法对形状图像具有更强的描述和识别能力。结论 相比于传统的距离度量,相对一致性距离对形状的非刚性变形具有更强的稳定性。     

基于虚拟现实技术的无人机转角控制仿真

无人机飞行状态具有较强的非线性特征,机体绕X轴的转动惯量较小,副翼的舵效相对较高,受到扰动后滚转角速率变化很快,使得无人机的横侧向控制成为转角控制的难点问题.传统采用转角跟踪器的无人机转角控制方法中,反馈线性化过程较为繁琐,对于模型精度要求较高,无法适应不断变化的无人机飞行状态.提出一种应用虚拟现实技术的无人机转角控制方法,用三维实景仿真塑造虚拟的无人机飞行区域实景,在无人机运动过程中,辅助操纵手在目视距离内,由增稳控制或人工遥控方式对飞机转角进行操作,并通过三维建模来对无人机机体模型和舵面模型进行构建,并导人到相应的环境中,再通过相应程序对无人机的运动和舵面的转角进行有效的控制,从而实现无人机转角的准确控制.仿真结果表明,相比传统控制方法,所提方法控制下的无人机转角的响应速度更快,具有高的控制效率,在各种扰动的情况下,均可以实现无差的控制跟踪.