Copper‐Catalyzed Chloroamination of Alkynes: Highly Regio‐ and Stereoselective Synthesis of (E)‐β‐Chloro‐Enesulfonamides

An efficient copper catalysis system for the chloroamination of alkynes with chlorosulfonamide at room temperature is described, providing a highly regio‐ and stereoselective procedure for the synthesis of (E)‐β‐chloro‐enesulfonamides in moderate to good yields.     

关于汽轮发电机机内冷却气体的湿度问题

近年来通过制造和运行实践，国内对控制发电机机内冷却体湿度的重要性的认识日益加深，汽轮发电机中冷却气体湿度过大对发生定子线圈绝缘故障，转子护环应力腐蚀有很大的影响。本文就冷却气体湿度标准，氢气干燥器的设计使用，湿度测量等有关问题，结合平圩６００ＭＷ发电机的运行经验进行探讨并提出解决措施，以提高发电机运行的可靠性。     

A novel and rapid fabrication for microlens arrays using microinjection molding

This work reports a novel and effective procedure for manufacturing the mold insert of microlens arrays. First, the microlens arrays master is formed using room‐temperature imprint lithography and photoresist reflow process. Next, electroforming is carried out to fabriccate the metal mold insert from the master. Finally, microinjection molding is used to replicate the molded microlens arrays. The 200 × 200 arrays of molded microlens, with a diameter of 150 μm, a pitch of 200 μm, and a sag height of 11.29 μm for polycarbonate (PC) material and 11.24 μm for polymethylmethacrylate (PMMA) material have been successfully fabricated. The moldability for PMMA material is better than PC material on molded microlens arrays. The average surface roughness of the molded microlens arrays is 4.53 nm for PMMA material and 4.81 nm for PC material. The mold temperature is the most important processing factor for the focal length and sag height of molded microlens arrays. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers.     

协调控制系统的专家极点配置自整定方法

本文提出了一种多变量ＰＩＤ控制系统参数在线自整定方法，即多变量专家极点配置（ＭＥＰＰ）法。该方法将单变量ＰＩＤ控制器极点配置自整定方法推广到多变量系统，并成功地运用专家系统原理实现了闭环极点的自动配置，克服了人工试凑的缺陷。该方法用于火电单元机组协调控制系统自整定仿真研究，结果是令人满意的。     

Coating films prepared by photoreactions of the surface‐modified diamond powder and PET film with a binder agent

The surface‐modified diamond and PET film underwent photopolymerization rapidly with a binder agent to afford coating films of interpenetrating network (IPN) structure. The coating films thus formed exhibit higher tensile strength, thermal stability, and adhesion strength to the PET film. The inert surfaces of pristine diamond (PD) and PET film were modified by different chemicals and procedures to introduce epoxide and methacryloyl groups, respectively, on their surfaces. A coating agent consisting of an epoxide group containing modified diamond (called ED), a binder agent, and photoinitiators was prepared. After applying the coating agent to the substrate (a glass plate or a methacryloyl group containing PET film, MMA‐PET) and degassing under reduced pressure, the thin film of the coating agent was exposed to UV light (λ_max; 365 nm) at room temperature to yield a coating film of IPN‐structure. The tensile strength and thermal properties of the ED‐containing free coating film (called free film) increased with the amount of ED embedded, whereas the strength of the PD‐containing free film decreased with the amount of PD embedded. The adhesion strength of the coating film on the MMA‐PET improved significantly by the free radical polymerization of the methacryloyl groups on the MMA‐PET and the acrylate resin in the binder agent. The surface photoreactions of ED and MMA‐PET with the binder agent were confirmed by modeling. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Effect of nanosilica content on properties of polyurethane/silica hybrid emulsion and its films

Polyurethane/silica hybrid emulsion (PUSi) was synthesized by the reaction of isophorone isocyanate, polyether polyol, hydrophilic nanosilica (A200), dimethylol propionic acid, trimethylol propane, and 3‐aminopropyltriethoxysilane (KH550). The films of the waterborne polyurethane (WPU) were prepared. The structure of the polyurethane was characterized by Fourier transform infrared spectrometer (FTIR), thermogravimetry (TG), and differential scanning calorimetry (DSC). The particle size distribution and morphology of emulsion were examined. Influence of nanosilica content on the mechanical properties and solvent absorption of the cast films were also measured quantificationally. FTIR indicates that  NH₂ of KH550 reacted with  NCO of polyurethane. TG analysis indicates that nanosilica can improve thermal stability of polyurethane. There is no clear effect of nanosilica on the glass transition of soft segments. It was found that greater mechanical properties of WPU were obtained when chemical networks were formed by sol‐gel process. As the nanosilica content increases, water absorption and ethanol absorption decreased. The particle size increases with increase of A200 content. PUSi hybrid emulsions are endowed with pseudoplasticity. The apparent viscosity of emulsions increased and then decreased with addition of A200. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

信道间隔为12.5kHz的集群系统在电力系统中的应用

本介绍了上海市南供电局将国标４５０ＭＨｚＥ３８频段无线电８０系列改制成９０系列，并组成集群移动通信网，利用车载台及手持机实现了上海市南地区的调度、操作的直通通信及在市南和市区范围内的生产指挥的拨号通信。调度、操作通信具有双向优先及录音功能。本还介绍了该系统的组网及系统配置。     

BP神经网络算法在页岩气饱和度评价的应用

页岩气储层中高含量的有机质和黏土矿物会对饱和度的计算会产生影响,常规油气储层建立的饱和度计算模型在页岩气储层饱和度评价中存在较大误差,亟需寻求新的途径与思路.本文分析总结了页岩气储层性质及其与含水饱和度的关系机理.利用井中地层密度和铀含量与岩心分析含水饱和度有较好的相关性,通过BP神经网络训练建立新的非电性测井饱和度评...     

基于韧性提升的医疗卫生设施布局优化研究 ——以上海为例

"韧性"具有全过程、多尺度、多领域的属性,基于这一理念来优化医疗卫生设施布局,能更好地应对常态化疫情防控以及未来新的公共卫生事件.以上海这一超特大城市近年来的实践为例,围绕当前医疗卫生设施防养环节相对滞后、基层与郊区相对薄弱、总量冗余度有所不足等问题,提出"夯实两端,优化'防、治、养'一体的服务体系""重心下移,完善多...     

基于特征选择和时间卷积网络的工业控制系统入侵检测

针对工业控制系统流量数据存在特征冗余及深度学习模型对较小规模数据集检测能力较差的问题,提出了一种基于特征选择和时间卷积网络的工业控制系统入侵检测模型。首先,对源域数据集的异常特征和样本不平衡数据进行处理,提高源域数据集质量。其次,针对流量数据的特征冗余,利用信息增益率和主成分分析法构建IGR-PCA特征选择算法,筛选出最优特征子集实现数据降维。然后,根据工业控制系统流量数据的时间序列特性,在较大规模的源域数据集上,利用时间卷积网络（temporal convolution network,TCN）对时间序列数据优异的处理能力,构建源域时间卷积网络预训练模型。最后,在较小规模的目标域数据集上,结合迁移学习（transfer learning,TL）微调策略,获取源域样本数据的流量特征,构建目标域TCN-TL模型。利用公开的工业控制系统数据集进行实验测试,实验结果表明：流量数据经本文特征算法处理后,相较于其他方法,在降低数据维度减少计算量的同时仍具有良好的检测效果;在较大规模的源域数据集和较小规模的目标域数据集上,本文模型均取得了良好的检测效果,在目标域中利用迁移学习微调策略能够学习到源域中的知识,模型检测准确率为99.06%,在训练时间对比中,本文模型训练时间消耗更少,具有更好的泛化能力,能够更好地保护工业控制系统安全。