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61.
Ole Becker Peter Sopade Romain Bourdonnay Peter J. Halley George P. Simon 《Polymer Engineering and Science》2003,43(10):1683-1690
The effect of an organically surface modified layered silicate on the viscosity of various epoxy resins of different structures and different functionalities was investigated. Steady and dynamic shear viscosities of the epoxy resins containing 0–10 Wt% of the organoclay were determined using parallel plate rheology. Viscosity results were compared with those achieved through addition of a commonly used micronsized CaCO3 filler. It was found that changes in viscosities due to the different fillers were of the same order, since the layered silicate was only dispersed on a micron‐sized scale in the monomer (prior to reaction), as indicated by X‐ray diffraction measurements. Flow activation energies at a low frequency were determined and did not show any significant changes due to the addition of organoclay or CaCO3. Comparison between dynamic and steady shear experiments showed good agreement for low layered silicate concentrations below 7.5 wt%, i.e. the Cox‐Merz rule can be applied. Deviations from the Cox‐Merz rule appeared at and above 10 wt%, although such deviations were only slightly above experimental error. Most resin organoclay blends were well predicted by the Power Law model, only concentrations of 10 wt% and above requiring the Herschel‐Buckley (yield stress) model to achieve better fits. Wide‐angle X‐ray measurements have shown that the epoxy resin swells the layered silicate with an increase in the interlayer distance of approximately 15 Å, and that the rheology behavior is due to the lateral, micron‐size of these swollen tactoids. 相似文献
62.
M A Rossi S Zucoloto J E Dutra de Oliveira P F Becker J S Oliveira 《Archivos latinoamericanos de nutrición》1978,28(1):29-40
A study of the effect of long-term alcohol consumption on the liver of well-nourished rats is described. Rats fed for 16 weeks on a semipurified diet supplemented with high levels of vitamins and lipotropic factors and alcohol corresponding to 35% of the total caloric intake developed marked fatty changes of the liver. Mild fatty changes were observed in pair-fed controls receiving as isoenergetic equivalent of sucrose instead of alcohol. Intracellular hyaline bodies, corresponding ultrastructurally to giant mitochondria were abundantly found in the hepatocytes of alcoholic rats, while in the controls they were not seen. Te findings in this investigation are postulated to provide further evidence that the long-term intake of alcohol exerts a direct causative role in the pathogenesis of liver damage. 相似文献
63.
H. R. Spiegel J. Juilfs U. Neubert K. J. Euler J. W. Beck D. Besdo H. Winter H. Becker W. Neuberger R. Jung K. Herfort H. Bühler H. Göppl H. W. Hahnemann W. Siegel 《Forschung im Ingenieurwesen》1970,36(2):64-68
Ohne Zusammenfassung
VDI 相似文献
64.
K. Thangaraj A. Elefsiniots Th. Becker U. Schmid J. Lees C. A. Featherston R. Pullin 《Microsystem Technologies》2014,20(4-5):701-707
This paper describes an approach for efficiently storing the harvested energy from a thermoelectric module for powering autonomous wireless sensor nodes in aircraft health monitoring applications. Thermoelectric devices are the preferred option due to the widespread availability of significant levels of energy from the temperature gradients or variations at the aircraft, such as the cabin, the engine compartment, the fuel tanks or the inner and outer frame of the fuselage. Batteries and supercapacitors are popular choices of storage device, but neither represents the ideal solution, with, supercapacitors possessing low energy densities while batteries have low power density. When using a battery-only solution for storage, the runtime of a typical sensor node is typically reduced by the battery’s relatively high internal impedance and thermal loss. Supercapacitors can overcome some of these problems, but generally do not provide sufficient long-term energy to allow aircraft health monitoring applications to be operated over an extended period. A hybrid energy storage solution can provide both energy and power density to a wireless sensor node simultaneously. Techniques such as acoustic–ultrasonic, acoustic-emission, strain and crack wire sensors require storage approaches that can provide immediate energy on demand, usually in short, high intensity bursts, and that can be sustained over long periods of time, storing up to 40–50 J of energy. This application requirement is considered as a significant constraint when working with battery-only and supercapacitor-only solutions. The hybrid system described here provides an alternate viable solution. 相似文献
65.
The effects of oxidation/reduction regeneration treatments, with and without 1,2-dichloropropane present as a chlorinating agent, on the structure of Pt(3%)–Sn(4.5%)/Al2O3 catalysts have been correlated with selectivities for butane/H2 reactions. Particles of Pt0 fin Cl-free catalysts were partly covered by Sn0, but retained exposed ensembles of Pt atoms which were active for isomerisation, hydrogenolysis and dehydrogenation reactions, the latter becoming dominant at high reaction temperatures. Coking reduced Pt ensemble size and, hence, also favoured high selectivities for dehydrogenation as hydrogenolysis and isomerisation sites became poisoned. In contrast, the addition of 1,2-dichloropropane in an oxychlorination step before reduction promoted 1:1 Pt0–Sn0 alloy formation after reduction, the proportion of the total Pt in alloy being enhanced by increasing 1,2-dichloropropane concentration and oxychlorination temperature. The alloy surfaces were inactive for isomerisation and hydrogenolysis reactions, giving dehydrogenation as the sole catalytic reaction. 相似文献
66.
Becker A. V. Polianczyk E. V. Volkova N. N. Manelis G. B. 《Theoretical Foundations of Chemical Engineering》2004,38(5):510-515
The kinetics of the overall reactions of carbon gasification at temperatures up to 1600 K is studied. The kinetic characteristics of the reactions are taken into account in a distributed mathematical model of filtration combustion of carbon. By computational experiment at different values of process control parameters (the gas flow rate, the fraction of the oxidant in the gas, and the mass ratio of carbon to the inert material in the combustible mixture), it is found that, in the wave of filtration combustion of carbon under superadiabatic conditions, carbon gasification can predominately yield either CO2 or CO. 相似文献
67.
Jeannette Aumo Johanna Lilja Päivi Mäki-Arvela Tapio Salmi Mats Sundell Hanna Vainio Dmitry Yu. Murzin 《Catalysis Letters》2002,84(3-4):219-224
A polymer-supported Pd catalyst was investigated in hydrogenation of citral (3,7-dimethyl-2,6-octadienal), which is a stereoisomer with an isolated and a conjugated double bond as well as a carbonyl group. The catalyst was a fibrous polymer-supported catalyst modified with functional groups and immobilized metals. A comparison of the polymer-supported catalyst with conventional catalysts was made. 相似文献
68.
The internal, copper-catalysed, addition of keto-carbenes (generated from a diazoketone group) to a double bond conjugated either to a ketone or carboxylic ester function has been found to be a feasible preparative reaction in selected cases. This, together with the facile and regiospecific hydrogenolysis of the resulting 1,2-dicarbonyl cyclopropane intermediate, appear to constitute a convenient route to multifunctional bridged-ring systems. 相似文献
69.
A good way of achieving compatibility in polymer blends of poly(styrene‐co‐acrylonitrile) (S/AN) and bisphenol A polycarbonate (PC) is the chemical modification of S/AN in the melt. A catalyzed reaction of the nitrile groups with a substituted 2‐amino alcohol or 2‐amino phenol resulted in a conversion of nitrile groups of 55–75% in 60 min. The introduced heterocyclic structures were ethyl hydroxymethyl oxazoline (EHMOXA) and benzoxazole (BenzOXA), respectively. The use of dibutyltin oxide as a catalyst led to the highest efficiency. The modified polymer was characterized by Fourier transform infrared and NMR spectroscopy, elemental analysis, and reactions with organic acids and anhydrides. The modified S/AN showed good technical compatibility (single glass‐transition temperature) with PC in blends made from solution and from the melt. All blends were characterized with oscillating rheometry and differential scanning calorimetry. Rheological measurements showed that EHMOXA–S/AN reacted with PC and had crosslinked structures, whereas BenzOXA–S/AN showed compatibilization without any (crosslinking) reaction. The melt blends of BenzOXA–S/AN and PC showed a downward shift in the complex viscosity due to the influence of the BenzOXA group. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2322–2332, 2003 相似文献
70.
Martin Atzmueller Martin Becker Mark Kibanov Christoph Scholz Stephan Doerfel Andreas Hotho 《New Review of Hypermedia and Multimedia》2014,20(1):53-77
The combination of ubiquitous and social computing is an emerging research area which integrates different but complementary methods, techniques, and tools. In this paper, we focus on the Ubicon platform, its applications, and a large spectrum of analysis results. Ubicon provides an extensible framework for building and hosting applications targeting both ubiquitous and social environments. We summarize the architecture and exemplify its implementation using four real-world applications built on top of Ubicon. In addition, we discuss several scientific experiments in the context of these applications in order to give a better picture of the potential of the framework, and discuss analysis results using several real-world data sets collected utilizing Ubicon. 相似文献