The impact of thermal conductivity and diffusion rates on water vapor transport through gas diffusion layers

Proper water management in a hydrogen-fueled polymer electrolyte membrane (PEM) fuel cell is critical for performance and durability. A mathematical model has been developed to elucidate the effect of thermal conductivity and water vapor diffusion coefficient in the gas diffusion layers (GDLs). The fraction of product water removed in the vapor phase through the GDL as a function of GDL properties/set of material and component parameters and operating conditions has been calculated. The current model enables identification of conditions wherein condensation occurs in each GDL component. The model predicts the temperature gradient across various components of a PEM fuel cell, providing insight into the overall mechanism of water transport in a given cell design. The water condensation conditions and transport mode in the GDL components depend on the combination of water vapor diffusion coefficients and thermal conductivities of the GDL components. Different types of GDLs and water transport scenarios are defined in this work, based on water condensation in the GDL and fraction of water that the GDL removes through the vapor phase, respectively.     

The use of the portable ergonomic observation method (PEO) to monitor the sitting posture of schoolchildren in the classroom

Contrary to common belief, back pain amongst young people is a frequent phenomenon. Epidemiological studies have found high prevalence rates of back pain amongst schoolchildren. The investigation reported here aims to validate children's self-reporting and the observation of sitting postures to establish the intensity, duration and frequency of exposure in the classroom. The sitting postures of 18 children were recorded using three methods, the portable ergonomic observation method (PEO), video analysis and self-report. The three methods were compared. PEO was significantly correlated with video analysis of the sitting postures after development of the method. Self-report was not significantly correlated with video analysis of the sitting postures. Therefore PEO was selected as the main observation tool in further analysis of children's sitting posture in schools in South-East England as part of a large research programme investigating back pain amongst schoolchildren.     

Customization of a Commercially Available Prep Scale SFC System to Provide Enhanced Capabilities

Preparative Scale Supercritical Fluid Chromatography is emerging as a powerful alternative to HPLC for the purification and separation of complex chemical reaction mixtures. Advantages include greatly reduced solvent usage (and thus lower cost and environmental impact), higher throughput, and in some cases higher resolution. While there are commercially available prep SFC instruments, none currently offer all the features desired by many medicinal chemists engaged in the drug discovery process. These include: the ability to collect an unlimited number of fractions per sample with high recovery and negligible carryover, fully automated capacity to collect several hundred fractions, and the ability to collect fractions into the same disposable test tubes and racks which are already employed in HPLC. This article describes the customization of a preparatory scale SFC system purchased from Berger Instruments, Inc., Newark, DE. (a subsidiary Mettler-Toledo International, Inc., of Greifensee, Switzerland) in order to provide these capabilities.     

Packet video transport in ATM networks with single-bit feedback

The promise of a broadband integrated service digital network has led to the design of mechanisms for efficient transport of real-time compressed video in packet switching networks. We examine feedback control for video transport in ATM networks where the available feedback is a single bit of information carried in the cell header. We investigate the performance of three single-bit schemes for source rate adaptation. Two were originally for congestion control of bursty data traffic and are modified to control video traffic. The third scheme conveys more information about the state of queue(s) at the bottleneck. The simulation results show that all three schemes for feedback control of VBR video streams work remarkably well. During severe network congestion, the signal quality degrades gracefully, but not uniformly across all connections. Based on insights from the initial simulations, we propose a scheme to improve the fairness of service and demonstrate its effectiveness.     

Update on methodology topics

The following column on methodology topic was prepared by AOCS Technical Director Dave Berner. Questions on these or other topics concerning analytical methodology of fats and oils or related products may be directed to Dave Berner, AOCS, PO Box 3489, Champaign, IL 61821-0489, USA     

Efficient testing of segmented aspherical mirrors by use of a reference plate and computer-generated holograms. II. Case study, error analysis, and experimental validation

Segmented mirrors present unique challenges to fabrication and testing that are absent for monolithic optics. Since traditional asphere tests do not address segmented optics adequately, we validate a previously developed method to test large quantities of segments accurately, quickly, and economically. In this test, the aspheric shape of each segment is controlled to high accuracy by use of computer-generated holograms, and the radius of curvature is tightly controlled by use of the reference plate. In an adjoining paper [Appl Opt 43, 5303 (2004)] we developed the theory for this test, and now we present a complete system design and optimization for measuring the 1.4-m segments from a 30-m F/1 primary. A complete tolerance analysis predicts a test accuracy of 4.8-nm rms surface and excellent accuracy for controlling the geometry of the segment. In addition, a laboratory demonstration using 30-cm optics is presented that demonstrated 3.9-nm rms surface accuracy.     

A central cholinergic inhibitory system as a basis for tonic immobility (animal hypnosis) in chickens.

4 experiments provided support for the hypothesis that tonic immobility (TI) in chickens, which may be analogous to response suppression in the rat, is a result of fear and is mediated by central cholinergic systems. A total of 124 experimental and 54 control, White Leghorn cockerel chicks were the Ss. Exp I established that scopolamine, a central and peripheral acting anticholinergic, will reduce the duration of TI, whereas methylscopolamine, which acts only peripherally, will not. Exp II established a dose-response curve for scopolamine and TI. Exp III demonstrated that scopolamine increased activity and that this increase may be a factor in reducing the duration of TI. Exp IV showed that physostigmine, which blocks acetylcholinesterase and allows longer action of acetylcholine at the synapse, increased the duration of TI. (18 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Progress in Web-based decision support technologies

World Wide Web technologies have transformed the design, development, implementation and deployment of decision support systems. This article reviews and summarizes recent technology developments, current usage of Web-based DSS, and trends in the deployment of such systems. Many firms use the Web as a medium to convey information about DSS products or to distribute DSS software. The use of Web-based computation to provide product demonstrations or to deploy DSS applications for remote access remains less common. The academic literature on Web-based DSS is largely focused on applications and implementations, and only a few articles examine architectural issues or provide design guidelines based on empirical evidence.     

电炉JetBOxTM技术的发展

美国PTI公司发明的专利技术JetBOxTM超音速氧枪喷射系统被证明是一种能有效提高电弧炉产量同时又能减少电炉改造成本的技术.通过在各个炼钢电炉上使用这种独特而有效的化学能输入方式从而获得了良好的效果.由于每个电炉的JetBOxTM系统都是专门设计,能满足每个炼钢车间的不同要求,因此已经被成功地应用在用料篮加料的普通电炉、Consteel电炉、使用DRI/HBI的电炉以及热装铁水的电炉上,同样都获得了良好的运行效果.自2001年以来JetBOxTM系统已经在全世界超过60台不同的电炉上安全而有效地运行着,满足了不同钢厂的要求.