Crystallographic Data of a New Phase of Dicalcium Silicate

Unit-cell parameters and the space group of a new phase of dicalcium silicate (Ca₂SiO₄) were determined by using powder X-ray diffractometry and selected-area electron diffraction techniques. This phase could be synthesized via the dissociation of hydrothermally synthesized alpha-Ca₂(SiO₄H)OH at temperatures of ∼500°-920°C. Crystallographic data for the sample synthesized at 600°C were as follows: Ca₂SiO₄, monoclinic; P 2₁/ c space group; lattice parameters of a = 0.82147(9) nm, b = 0.9808(1) nm, c = 0.9741(1) nm, and β= 94.642(7)°; cell volume ( V ) of 0.7857(1) nm³; Z = 8 (where Z is the number of chemical formula units in a unit cell); and a density of 2.91 g/cm³. The crystallographic data for samples synthesized at 800°C had slightly different unit-cell parameters of a = 0.82124(6) nm, b = 0.97348(7) nm, c = 0.97935(7) nm, β= 94.831(5)°, and V = 0.7849(1) nm³. Structural relationships of the new phase with the other dicalcium silicates are discussed.     

Plate insertion as a means to improve the damping capacity of a cutting tool system

Effective chatter prevention during cutting operations is achieved by increasing the damping capacity of a cutting tool system. It is well known that damping capacity is generated through (i) micro-slip at the interface between the tool shank and tool post, (ii) slip at the grain boundary within a vibrating body (that is, internal friction), and (iii) friction between the surface of the vibrating body and the surrounding air. Among these three causes of damping capacity, micro-slip at the interface between the tool shank and tool post is the greatest factor affecting the damping capacity of the cutting tool system. In the research investigation, it is shown that the damping capacity of a cutting tool system is improved by friction acting between the inner wall of a rectangular hole made at the overhanging shank of the cutting tool system and the surface of a plate inserted into this rectangular hole. The damping capacity improvement proposed in this paper is realized by a mechanism similar to the inner friction mechanism.     

Temperature‐dependent permeability of polyelectrolyte complex capsule membranes having N‐isopropylacrylamide domains

As a microcapsule with temperature sensitivity, poly(methacrylic acid)–polyethylenimine complex capsules containing N‐isopropylacrylamide units were designed. Two kinds of copolymers of methacrylic acid and N‐isopropylacrylamide were synthesized by free‐radical copolymerization. Partly crosslinked poly(methacrylic acid)–polyethylenimine complex capsules containing the methacrylic acid–N‐isopropylacrylamide copolymers were prepared at 40 or 25°C. The permeation of phenylethylene glycol through the capsule membranes was investigated. Permeability of the capsules prepared at 25°C increased monotonously with increasing temperature from 10 to 50°C. Permeability of the capsules prepared at 40°C also increased with increasing temperature up to 25°C but decreased above 30°C. Also, the degree of swelling of the membranes prepared at 40°C decreased above 30°C. Differential scanning calorimetry measurement showed that N‐isopropylacrylamide units underwent more efficient transition in the capsule membranes prepared at 40°C than in the membranes prepared at 25°C. The capsule membranes prepared at 40°C might have domains in which N‐isopropylacrylamide units are concentrated, whereas these units should distribute uniformly in the capsule membranes made at 25°C. Such a difference in distribution of N‐isopropylacrylamide units might result in the different permeation property of the capsule membranes. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 2703–2710, 2000     

Time-domain magnetic field waveform measurement near printed circuit boards

This paper describes a time domain magnetic field measurement process for measuring magnetic fields near printed circuit boards (PCBs) with a loop probe. In carrying out these measurements, the loop probe needs to be calibrated in the frequency domain. In this process, a microstrip line with a teflon substrate serving as the standard magnetic field source is employed as a means of calibrating the probe. The standard magnetic field intensities of the line are calculated by using an approximate equation obtained from Ampère's law to simplify the calibration. The sensor-factor of the probe obtained from this method agrees with that obtained through the use of a standard G-TEM cell in 2 dB at frequencies below 1 GHz. The waveforms of magnetic fields near a PCB having a four-layer construction are measured using a 10 mm diameter loop probe as the calibrated magnetic field sensor. The generation of magnetic field waveforms causing the radiated emission from the PCB is found to depend on the circuit operating conditions. Our results clarify the fact that the time domain magnetic field measurement process is an effective tool for analyzing the sources of emission radiated from PCBs and for investigating the radiation mechanism. © 1998 Scripta Technica, Electr Eng Jpn, 125(4): 9–18, 1998     

An optical fiber flow speed sensor of increased sensitivity

A simple-structured speed sensor in which a polarization-maintaining optical fiber is used as a Karman vortex generator and also as a vortex frequency sensor had earlier been proposed. For measuring ocean current velocity, a double-fin-type sensor mount was designed and investigated in detail experimentally. Although the experimental results showed its essential effectiveness, several problems were found. A conduit-type sensor mount has newly been proposed for solving these problems. A sensor for this mount has been constructed by using a circular pipe 16 mm in diameter. Experimental studies of the sensor show a wide range of agreement between detected frequencies versus measured flow speeds and the frequencies expected from the Roshko equation. The minimum detectable flow speed is 0.27 m/s. © 1998 Scripta Technica, Electr Eng Jpn, 125(1): 1–8, 1998     

Critical heat flux in subcooled flow boiling with water in a tube with axially nonuniform heating

Critical heat flux (CHF) in subcooled flow boiling under axially nonuniform heating conditions was experimentally investigated using a tube heated with a dc power source. The thickness of the tube wall in the axial direction was varied to attain axially nonuniform heating. The different thicknesses, therefore, separated the tube into regions of high heat flux and regions of low heat flux. The lengths of these regions of the tube were also varied to study the effect on the CHF. The objective of this system is to initiate boiling in the high-heat-flux region, thus increasing heat transfer, and to interrupt the bubble boundary layer in the low-heat-flux region. Because it is the initiation of boiling that increases heat transfer, the performance of such a system is linked to its effectiveness in repeatedly interrupting and re-establishing the bubble boundary layer. Our experiments, involving tubes that had sections of different thicknesses and different lengths, showed that when the heat flux in the low-heat-flux region was below the net vapor generation (NVG) heat flux, this system enhanced the CHF, but not when it was above the NVG. Also, for relatively short low-heat-flux regions, the CHF was not enhanced, presumably because there was insufficient time to interrupt the bubble boundary layer. © 1998 Scripta Technica, Heat Trans Jpn Res, 27(2): 169–178, 1998     

Investigation of the factors affecting the limit of detection of laser-induced breakdown spectroscopy for surface inspection

Laser-induced breakdown spectroscopy(LIBS) was examined to detect a trace substance adhered onto Al alloys for the surface inspection of materials to be adhesively bonded. As an example of Si contamination, silicone oil was employed and sprayed onto substrates with a controlled surface concentration. LIBS measurements employing nanosecond UV pulses(λ?=?266 nm) and an off-axis emission collection system with different detecting heights were performed. Because surface contaminants are involved in the plasma formed by laser ablation of the substrates, the relative contribution of the surface contaminants and the substrates to the plasma emission could be changed depending on the conditions for plasma formation. The limit of detection(LOD) was evaluated under several detecting conditions for investigating the factors that affected the LOD. A significant factor was the standard deviation values of signal intensities obtained for the clean substrates. This value varied depending on the measurement conditions.For the Al alloy(A6061), the smallest LOD obtained was 0.529 μg?·?cm~(-2). Furthermore, an improved LOD(0.299 μg?·?cm~(-2)) was obtained for the Al alloy with a lower Si content.     

Shape memory behavior of poly(methyl methacrylate)-graft-poly(ethylene glycol) copolymers

This paper describes a shape memory behavior of graft copolymers poly(methyl methacrylate)-graft-poly(ethylene glycol) (PMMA-g-PEG). In shape memory test, the sample was deformed from its original shape to a temporary shape above glass transition temperature (T_g), cooled below T_g to fix the temporary shape, and subsequently heated above T_g for spontaneous recovery to the original shape. By grafting PEG onto PMMA backbone, shape memory ability was drastically enhanced than PMMA homopolymer. The shape recovery ratio was decreased with the increase in the shape deformation temperature. With considering a good miscibility of backbone and side chain in PMMA-g-PEG, this shape memory ability may be related to a physically cross-linked network structure by chain entanglement of the comb-like graft copolymer. Stress relaxation measurements were investigated in order to confirm the effect of the graft chains on the shape memory behavior.