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排序方式: 共有1473条查询结果,搜索用时 15 毫秒
51.
Oishi S Masuda R Evans B Ueda S Goto Y Ohno H Hirasawa A Tsujimoto G Wang Z Peiper SC Naito T Kodama E Matsuoka M Fujii N 《Chembiochem : a European journal of chemical biology》2008,9(7):1154-1158
The design, synthesis, and bioevaluation of fluorescence- and biotin-labeled CXCR4 antagonists are described. The modification of D-Lys8 at an epsilon-amino group in the peptide antagonist Ac-TZ14011 derived from polyphemusin II had no significant influence on the potent binding of the peptide to the CXCR4 receptor. The application of the labeled peptides in flow cytometry and confocal microscopy studies demonstrated the selectivity of their binding to the CXCR4 receptor, but not to CXCR7, which was recently reported to be another receptor for stromal cell-derived factor 1 (SDF-1)/CXCL12. 相似文献
52.
Hiroaki Ohfuji Takuo Okuchi Shoko Odake Hiroyuki Kagi Hitoshi Sumiya Tetsuo Irifune 《Diamond and Related Materials》2010,19(7-9):1040-1051
Micrometer- to nanometer-scale structures of the cut surfaces of single- and polycrystalline diamonds by a pulsed ultraviolet laser have been thoroughly investigated by scanning and transmission electron microscopy. Within the laser-cut grooves, the processed diamond surfaces are extensively covered with laser-modified debris which consists of complex layered units of graphite with various crystallinities. The units consist of 1) highly oriented graphite, 2) corrugated graphite, and 3) nanocrystalline graphite, which are sequentially located from the surface of the underlying diamond substrate to the center of the grooves. Detailed textural examinations revealed that the highly oriented graphite unit is a product of the initial graphitization of diamond by a solid-state diffusion process, whereas the latter two units are deposition products from the liquid and/or vapor phases of carbon in the later stage. The present study demonstrates that the laser-cutting of diamonds proceeds in a two-step process: 1) extensive graphitization of laser-scanning path and 2) subsequent sublimation of the pre-formed graphite. These processes are basically identical among the three different types of diamonds (single crystal type Ib, single crystal type IIa and nano-polycrystalline aggregate) tested in this study. 相似文献
53.
Sang Jun Yoon Jae Goo Lee Hideo Tajima Akihiro Yamasaki Fumio Kiyono Tetsuya Nakazato Hiroaki Tao 《Journal of Industrial and Engineering Chemistry》2010,16(3):350-354
Extractions of five kinds of lanthanide metal ions by bis(2-ethylhexyl)phosphoric acid (DEHPA) with [1-Cn-3-methylimidazolium][PF6](Cn = C2, C4) or [1-butyl-4-methylpyridinium][PF6] were carried out under various DEHPA and HNO3 concentrations from 0 to 1 M and under different temperature conditions from 298 to 333 K. These results were compared with those using the conventional organic solvent, hexane, in terms of their distribution coefficient values. Under all of the conditions in this study, the ionic liquid system shows more than three times greater extractability for lanthanide compared to when hexane was used. The distribution coefficient of lanthanide ions decreased as the length of the alkyl chain increased from the ethyl to the butyl. In addition, the imidazolium cation generally shows a higher distribution coefficient compared to the pyridinium cation in an ionic liquid. The concentration ratio of lanthanides and DEHPA resulted in an extraction affinity transition for lanthanides. Also evaluated in this study were issues related to the selectivity associated with the lanthanide mixture and the dependency of the ionic radius during lanthanide extraction. 相似文献
54.
Natsuko Goda Kana Shimizu Yohta Kuwahara Takeshi Tenno Tamotsu Noguchi Takahisa Ikegami Motonori Ota Hidekazu Hiroaki 《International journal of molecular sciences》2015,16(7):15743-15760
Intrinsically disordered proteins (IDPs) that lack stable conformations and are highly flexible have attracted the attention of biologists. Therefore, the development of a systematic method to identify polypeptide regions that are unstructured in solution is important. We have designed an “indirect/reflected” detection system for evaluating the physicochemical properties of IDPs using nuclear magnetic resonance (NMR). This approach employs a “chimeric membrane protein”-based method using the thermostable membrane protein PH0471. This protein contains two domains, a transmembrane helical region and a C-terminal OB (oligonucleotide/oligosaccharide binding)-fold domain (named NfeDC domain), connected by a flexible linker. NMR signals of the OB-fold domain of detergent-solubilized PH0471 are observed because of the flexibility of the linker region. In this study, the linker region was substituted with target IDPs. Fifty-three candidates were selected using the prediction tool POODLE and 35 expression vectors were constructed. Subsequently, we obtained 15N-labeled chimeric PH0471 proteins with 25 IDPs as linkers. The NMR spectra allowed us to classify IDPs into three categories: flexible, moderately flexible, and inflexible. The inflexible IDPs contain membrane-associating or aggregation-prone sequences. This is the first attempt to use an indirect/reflected NMR method to evaluate IDPs and can verify the predictions derived from our computational tools. 相似文献
55.
Microwave-Hydrothermal Synthesis of Nanophase Ferrites 总被引:4,自引:0,他引:4
Sridhar Komarneni Maria Cristina D'Arrigo Cristina Leonelli Gian Carlo Pellacani Hiroaki Katsuki 《Journal of the American Ceramic Society》1998,81(11):3041-3043
This paper reports the synthesis of technologically important ferrites such as ZnFe2 O4 , NiFe2 O4 , MnFe2 O4 , and CoFe2 O4 by using novel microwave-hydrothermal processing. Nanophase ferrites with high surface areas, in the range of 72-247m2 /g, have been synthesized in a matter of a few minutes at temperatures as low as 164°C. The rapid synthesis of nanophase ferrites via an acceleration of reaction rates under microwave-hydrothermal conditions is expected to lead to energy savings. 相似文献
56.
Kimiaki Tsutsui Hiroaki Yoshimizu Yoshiharu Tsujita Takatoshi Kinoshita 《应用聚合物科学杂志》1999,73(13):2733-2738
The permeability coefficients of O2, N2, and CO2 gases at 25°C were examined for composite membranes that were prepared by filling poly(ethylene oxide)(PEO) with different molecular weights into a porous membrane. The permeability coefficients of O2, N2, and CO2 were 2 × 10−10 – 4 × 10−10, 5 × 10−11 – 9.5 × 10−11, and 6 × 10−10 – 1 × 10−9 (cm3 STPcm/cm2 s cmHg), respectively. The higher permeability coefficients of CO2 are explained in terms of high solubility of CO2 in filled PEO. The permeability coefficient of CO2 was affected by the degree of crystallinity of PEO in the composite. On the other hand, there was little effect of crystallinity on O2 and N2 permeability coefficients. Some probable relationships between selectivities of O2 to N2 and CO2 to N2 and the degree of crystallinity of PEO were observed. The CO2 gas permeability coefficients of the composite membrane for PEO50000 (Mw = 5 × 104) showed a marked change due to melting or crystallization of PEO. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2733–2738, 1999 相似文献
57.
Yomi Watanabe Shinichi Sato Saiko Sera Chiemi Sato Kazuaki Yoshinaga Toshiharu Nagai Ryota Sato Hiroaki Iwasaka Tsunehiro Aki 《Journal of the American Oil Chemists' Society》2014,91(8):1323-1330
A protocol for the analysis of the positional distribution of fatty acids (FA) in solid triacylglycerols (TAG) was developed using sn-1(3) selective alcoholysis catalyzed by immobilized Candida antarctica lipase B (CALB). One part by weight of solid fat and ten parts by weight of ethanol (99.5 %) were warmed to liquefy the fat. After adding 0.44 parts by weight of CALB, the mixture was shaken at 50 °C for 10 min then at 30 °C for 2.8 h. The recovery of 2-MAG after the 3-h transesterification reaction was ca. 85 % of the maximum theoretical yield (33 mol%), with the loss of 15 % attributable to the acyl migration from sn-2 to sn-1(3). The recovery was similar to that of the solvent-free alcoholysis of structured lipids, 1,3-dipalmitoyl, 2-oleoyl glycerol and 1,3-dioleoyl, 2-palmitoyl glycerol, conducted at 30 °C for 3 h. In contrast, the acyl migration from sn-1(3) to sn-2 was hardly observed. Because the detected acyl migration was only in the direction of sn-2 to sn-1(3), and not vice versa, it is proposed to determine the FA composition of the sn-2 position of TAG by the gas chromatographic analysis of 2-MAG fraction recovered from the enzymatic reaction mixture, and the FA composition of sn-1(3) position by a mass balance using the FA composition of TAG and of the sn-2 position as inputs. The procedure was successfully applied to palm oil and shea butter, and docosahexaenoic acid (DHA)-rich single cell oil from Aurantiochytrium sp. KH105 for the first time. 相似文献
58.
Yoshinori Nishiki Koichi Aoki Koichi Tokuda Hiroaki Matsuda 《Journal of Applied Electrochemistry》1987,17(1):67-76
On the basis of the observation of gas bubbles evolved by electrolysis, a two-dimensional vertical model cell composed of electrodes with open parts for releasing gas bubbles to the back side is proposed. The model cell consists of two layers. One layer forms a bubble curtain with a maximum volume fraction of gas bubbles in the vicinity of the working electrode with open parts. The other. being located out of the bubble layer, is a convection layer with a small volume fraction distributed in the vertical direction under forced convection conditions. The cell resistance and the current distribution were computed by the finite element method when resistivity in the back side varied in the vertical direction along the cell. The following three cases for overpotential were considered: no overpotential, overpotential of the linear type and overpotential of the Butler-Volmer type. It was found that the cell resistance was determined not only by the interelectrode gap but also by the percentage of open area and in some cases by the superficial surface area. The cell resistance varied only slightly with the distribution of the bubble layer in the back side.Nomenclature
b
linear overpotential coefficient given byb=/i
-
C
proportionality constant given by Equation 15
-
d
1
distance between front side of working electrode and separator
-
d
2
thickness of separator
-
F
Faraday constant
-
I
total current per half pitch
-
i
current density at working electrode
-
i
0
exchange current density
-
L
length of a real electrolysis cell
-
n
number of electrons transferred in electrode reaction
-
O
p
percentage of open area given by Equation 1
-
p
pitch, i.e. twice the length of the unit cell, defined by 2(BC) in Fig. 4
-
q
thickness of bubble curtain, defined by (AM) in Fig. 4
-
R
gas constant
-
r
t
total cell resistance
-
r
unit-cell resistance defined by (V – V
eq)/I
-
r
rs
residue ofr from sum ofr
0 andr
-
r
0
ohmic resistance of solution when0
p=0
-
r
resistance due to overpotential when0
p=0
-
s
electrode surface ratio or superficial surface area given by Equation 2 for the present model
-
T
absolute temperature
-
t
thickness of working electrode defined by EF in Fig. 4
-
V
cell voltage
-
V
eq
open circuit potential difference between working and counter electrodes
-
solution velocity in cell
- 0
solution velocity at bottom of cell
-
w
width of working electrode, defined by 2(DE) in Fig. 4
-
x
abscissa located on cell model
-
y
ordinate located on cell model
-
anodic transfer coefficient
-
linear overpotential kinetic parameter defined byb/[bc(p/2)]
- d
infinitesimally small length on the boundary
-
volume fraction of gas bubbles in cell
-
dimensionless cell voltage defined bynF(V – V
eq)/RT
-
overpotential at working electrode
-
Butler-Volmer overpotential kinetic parameter defined by [nFi
0bc(p/2)]/RT
-
coordinate perpendicular to boundary of model cell
- 1
resistivity of bubble-free solution
- 2
resistivity of separator
- bc
resistivity of bubble curtain
-
potential in cell 相似文献
59.
Hiroaki NAKANO 《中国有色金属学会会刊》2009,19(4):835-841
Because the lightness, the gloss and the press-formability of electrogalvanized steel sheets change depending on the morphology of deposited Zn, control of this factor is essential to improving these properties. The effects of plating factors on the morphology of deposited Zn were systematically discussed both from the crystallographic viewpoint of epitaxy between Zn and steel and from the electrochemical viewpoint of the overpotential for Zn deposition. Plating factors include crystal orientation of steel substrate, current density, flow rate, temperature, addition of inorganic compounds to the solution and pre-adsorption of organic compounds. These plating factors affect the overpotential for Zn deposition and epitaxy between Zn and steel. The crystal orientation index of the Zn basal plane and the platelet crystal size of Zn are decreased with increasing the overpotential for Zn deposition. They are also decreased with decreasing the epitaxy between Zn and steel, even when the overpotential is kept constant. When the overpotential for Zn deposition is increased, the surface roughness of deposited Zn increases because of an increase in the inclination of the Zn basal plane to the steel substrate. When the epitaxy between Zn and steel is decreased without changing the overpotential, the surface roughness is reduced due to the decrease in platelet crystal size of Zn, although the inclination of the Zn basal plane is somewhat increased. The lightness of deposited Zn is enhanced with decreasing the surface roughness of Zn. 相似文献
60.
Hiroaki Takeda Takeshi Shimada Yoshiaki Katsuyama Tadashi Shiosaki 《Journal of Electroceramics》2009,22(1-3):263-269
The electric properties of BaTiO3–(Bi1/2Na1/2)TiO3 (BT–BNT) solid solution ceramics were studied as a lead-free PTCR (positive temperature coefficient of resistivity) thermistor material usable over 130°C. For determining the maximum switching temperature T s, the phase diagram of BT–BNT binary system was clarified. Two semiconductorization processes and their electric properties are described. The lanthanum(La)-doped BBNT ceramics sintered in air still showed dielectric behaviors, but the niobium(Nb)-doped ones had a low resistivity at room temperature, ρ RT, on the order of 103 Ωcm and showed a PTC behavior. Sintering under a low O2 atmosphere produces BT–BNT ceramics with less than 102 Ωcm compared to those prepared in air. Our current research produced the BBNT ceramics with T s values around 210°C by increasing the (Bi1/2Na1/2) content in the ceramics. 相似文献