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21.
Two deacetyl-thymosin β4 analogues containing Phe(4Br) or D-Phe(4Br) as position 12 were synthesized by the manual solid-phase method, and their immunological effects on the impaired blastogenic response of phytohemagglutinin-stimulated T lymphocytes of uremic patients with infectious diseases were studied. Bromination of the p-position of Phe12 resulted in a marked restorative effect on the impaired blastogenic response of T lympocytes compared with that of our synthetic deacetyl-thymosin β4 The synthetic [Phe(4Br)12]deacetyl-thymsin β4 was approximately equal in potency to our synthetic [Phe(4F)12]deacetyl-thymosin β4 in uremic patients, but the other analogue, [D-Phe(4Br)12]deacetyl-thymosin β4, had no effect. 相似文献
22.
The oxidation of Fe(II) with dissolved molecular oxygen was studied in sulfuric acid solutions containing 0.2 mol . dm-3 FeSO4 at temperatures ranging from 343 to 363 K. In solutions of sulfuric acid above 0.4 mol . dm-3, the oxidation of Fe (II) was found to proceed through two parallel paths. In one path the reaction rate was proportional
to both [Fe2+]2 and po2, exhibiting an activation energy of 51.6 . kJ mol-1. In another path the reaction rate was proportional to [Fe2+]2, [SO4-], and po2 with an activation energy of 144.6 kJ . mol-1. A reaction mechanism in which the SO4- ions play an important role was proposed for the oxidation of Fe(II). In dilute solutions of sulfuric acid below 0.4 mol
. dm-3, the rate of the oxidation reaction was found to be proportional to both [Fe(II)]2 and Po2, and was also affected by [H+] and [SO2-
4]. The decrease in [H+] resulted in the increase of reaction rate. The discussion was further extended to the effect of Fe (III) on the oxidation
reaction of Fe (II). 相似文献
23.
Manipulation of Micro Solid Particles and Induced Flows in Water by Laser Irradiation 总被引:1,自引:0,他引:1
Q-switch for pulsing laser beam and Galvano scanner for rapid scanning laser beam were adapted to manipulatemicro solid particles in a water droplet.The trapping of fine particles at micron-sized diameters by a YAG lasersystem,induced flows,and the induced motion of the particles by laser beam irradiations are discussed.Particlerotations are observed by using anisotropic micro objects,and moreover the rotational rate with clockwise direc-tion is 22 r/min.The fragments of a cover glass were mixed in a water droplet,and their size and shape are un-even.The rotation of that non-spheres without scanning by the Galvano scanner is also observed in water. 相似文献
24.
Tomoko Akai Hiroshi Yamanaka Hajimu Wakabayashi 《Journal of the American Ceramic Society》1996,79(4):859-864
Copper-ruby glasses were prepared by the sputtering method and the effect of reducing treatment was examined. The reducing was carried out either during sputtering or heat treatment. Optical absorption was related to the growth of copper particles. The results are summarized as follows: (i) the volume fraction of copper particles in the glasses which are heat-treated in air increases with the addition of hydrogen in the sputtering gas. (ii) The copper particles do not grow larger than 8 nm by heat treatment in reducing atmosphere, whereas they grow as large as 12 nm in air. (iii) Reducing during heat treatment gives a pronounced effect only when sputtering was not carried out under reducing conditions. The origin of these phenomena was also discussed, considering the mechanism of nucleation and growth of copper particles. 相似文献
25.
A molecular orbital approach to materials design has recently made great progress. This approach is based on the electronic structure calculations by the DV-Xα cluster method. In this paper recent progress in this approachis reviewed. In particular 相似文献
26.
Highly transparent cellulose hydrogels with physical crosslinkage were prepared from nonaqueous organic cellulose solutions and viscose by coagulating and regenerating cellulose in an aqueous solution containing a water‐miscible organic solvent. Nonaqueous organic cellulose solutions used were LiCl/dimethylacetamide, paraformaldehyde/dimethyl sulfoxide, and triethylammonium chloride/dimethyl sulfoxide. Preparation conditions and physical properties of the transparent cellulose hydrogels were studied. The transparency of the cellulose hydrogels depended on the composition of the aqueous solution containing the organic solvent. Furthermore, transparent cellulose hydrogels from viscose showed high tensile strength. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3020–3025, 2003 相似文献
27.
Kyoko Kawagishi Hiroshi Harada Akihiro Sato Atsushi Sato Toshiharu Kobayashi 《JOM Journal of the Minerals, Metals and Materials Society》2006,58(1):43-46
The fourth-generation nickel-based single-crystal superalloys, which contain large amounts of refractory metals for strengthening
and platinum group metals for topologically close-packed phase prevention, show excellent high-temperature strength. However,
these alloying elements seem to decrease high-temperature oxidation resistance. In this study, nickel-based superalloys with
various amounts of tantalum, rhenium, and ruthenium were examined in isothermal and cyclic exposures at 1,100°C to investigate
the effect on the oxide growth rate and resistance to scale spallation. Ruthenium and rhenium were found to degrade the oxidation
resistance by the vaporization of their oxide. Tantalum-rich oxide in the spinel layer acts to stabilize ruthenium and rhenium
oxide in the scale. The addition of hafnium and yttrium is effective in improving the oxidation resistance of ruthenium-containing
nickel-based superalloys. 相似文献
28.
Yoshio Yamashita Hideyuki Jinbo Ryuji Kawazu Takateru Asano Hiroshi Umehara 《Polymer Engineering and Science》1991,31(12):855-859
LMR-UV (“low molecular weight resist for uv lithography”), a naphthoquinone-diazide sulfonic acid ester of a novolak resin, is a negative working resist. The mechanism of insolubilization of LMR-UV is based on the facts that the naphthoquinone-diazide moiety is decomposed to indenecarboxylic acid (polar compound) by photolysis upon UV irradiation and that the irradiated resist film insolubilizes in a non-polar developer. LMR-UV reliably forms 0.6 μm lines and spaces over a reflective substrate with steps by using a g-line stepper having a 0.35 NA lens. 0.6 μm-wide aluminum patterns over topography are obtained by use of g-line exposure and reactive ion etching. By use of an i-line aligner (NA = 0.42), LMR-UV resolves 0.25 μm space patterns with overhang profiles. The profiles are due to the large absorption coefficient of 3.8 μm?1. 0.3 μm wide aluminum patterns are formed by i-line exposure and lift-off metallization. 相似文献
29.
30.
This paper investigates induced voltage characteristics from an overhead transmission line by applying a method of modeling of induced voltages proposed by the authors. EMTP simulation results obtained by the modeling method agree with analytical results obtained from a well‐known formula. The induced voltages are significantly dependent on the configuration of the overhead line. A horizontal line induces the largest voltage in a gas pipeline, and the voltage induced by a vertical twin‐circuit line is about 20% smaller than that induced by a vertical single‐circuit line. The method is applied to a real pipeline system and the simulation results show reasonable agreement with field test results. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 164(1): 43–51, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20465 相似文献