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Kinetic‐Oriented Construction of MoS2 Synergistic Interface to Boost pH‐Universal Hydrogen Evolution
Jue Hu Chengxu Zhang Peng Yang Jingyi Xiao Tao Deng Zhiyong Liu Bolong Huang Michael K. H. Leung Shihe Yang 《Advanced functional materials》2020,30(6)
As a prerequisite for a sustainable energy economy in the future, designing earth‐abundant MoS2 catalysts with a comparable hydrogen evolution catalytic performance in both acidic and alkaline environments is still an urgent challenge. Decreasing the energy barriers could enhance the catalysts' activity but is not often a strategy for doing so. Here, the first kinetic‐oriented design of the MoS2‐based heterostructure is presented for pH‐universal hydrogen evolution catalysis by optimizing the electronic structure based on the simultaneous modulation of the 3d‐band‐offsets of Ni, Co, and Mo near the interface. Benefiting from this desirable electronic structure, the obtained MoS2/CoNi2S4 catalyst achieves an ultralow overpotential of 78 and 81 mV at 10 mA cm?2, and turnover frequency as high as 2.7 and 1.7 s?1 at the overpotential of 200 mV in alkaline and acidic media, respectively. The MoS2/CoNi2S4 catalyst represents one of the best hydrogen evolution reaction performing ones among MoS2‐based catalysts reported to date in both alkaline and acidic environments, and equally important is the remarkable long‐term stability with negligible activity loss after maintaining at 10 mA cm?2 for 48 h in both acid and base. This work highlights the potential to deeply understand and rationally design highly efficient pH‐universal electrocatalysts for future energy storage and delivery. 相似文献
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In this paper, we describe an improved cooperative two-way quantum communication scheme that works in a forward-and-backward fashion. In this scheme, partial entanglement analysis based on five-qubit entangled Brown state allows for the simultaneous exchange of arbitrary unknown states between Alice and Bob (with the help of trusted Charlie). Security is guaranteed because opposing unknown states are transmitted by performing the suitable recovery operations in a deterministic way or, in the case of irregularities, no results are generated. The current two-way quantum communication scheme can also be extended to transmit arbitrary unknown states. This is done in a probabilistic way by using two-way quantum teleportation based on the generalized Brown-like state. 相似文献
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本文在解码的基础上,结合协议统计功能,完成了TD-SCDMA系统业务分析功能的设计.此功能针对TD-SCDMA系统中接口协议栈的特点,从接口的信令中提取无线网络层中分别与无线资源管理有关的、与移动管理有关的和与呼叫管理有关的参数.对这些网络参数进行统计处理后,得到基站子系统的完备的统计数据.这些数据对制定无线网络资源优化措施提供数据支持,有利于解决网络优化工作中网络覆盖,信道拥塞,无线参数设置不合理等问题. 相似文献
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Jing Liang Xiao Hongling Wang Xiaoliang Wang Cuimei Deng Qingwen Li Zhidong Ding Jieqin Wang Zhanguo Hou Xun 《半导体学报》2013,34(11):113002-5
GaN films are grown on cone-shaped patterned sapphire substrates(CPSSs)by metal-organic chemical vapor deposition,and the influence of the temperature during the middle stage of GaN growth on the threading dislocation(TD)density of GaN is investigated.High-resolution X-ray diffraction(XRD)and cathodeluminescence(CL)wereusedtocharacterizetheGaNfilms.TheXRDresultsshowedthattheedge-typedislocation density of GaN grown on CPSS is remarkably reduced compared to that of GaN grown on conventional sapphire substrates(CSSs).Furthermore,whenthegrowthtemperatureinthemiddlestageofGaNgrownonCPSSdecreases,the full width at half maximum of the asymmetry(102)plane of GaN is reduced.This reduction is attributed to the enhancement of vertical growth in the middle stage with a more triangular-like shape and the bending of TDs.The CL intensity spatial mapping results also showed the superior optical properties of GaN grown on CPSS to those of GaN on CSS,and that the density of dark spots of GaN grown on CPSS induced by nonradiative recombination is reduced when the growth temperature in the middle stage decreases. 相似文献
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