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91.
Mohammad Kariznovi Hossein NouroziehJalal Abedi Zhangxin Chen 《Chemical Engineering Research and Design》2013
A new method is developed for the estimation of chemical reaction kinetics at high-pressure underground coal gasification from the field produced gas composition. This method combines a developed numerical forward model and field data to investigate uncertain parameters. The forward model is developed on the basis of a unique porous media approach that combines the effects of heat, mass transport, and chemical reactions to simulate the underground coal gasification in three-dimensional basis. The chemical reaction kinetics, that is limited to low pressure, is upscaled based on the available experimental data. A comprehensive sensitivity analysis is carried out to estimate the reaction kinetics and investigate the effect of various parameters, such as pressure, temperature, and reaction environment, on the produced gas composition. The novelty of the developed method is in its applicability as well as its ability to generate the chemical reaction kinetics that corresponds to the field under study. The advantage of the proposed technique is that the sensitivity of the model to different kinetic parameters can be investigated by a graphical method. 相似文献
92.
Nader Taheri Qazvini Seyed Hassan Jafari Hossein Ali Khonakdar Christina Scheffler 《应用聚合物科学杂志》2013,129(4):1868-1874
In this research, influence of incorporating LiClO4 salt on the crystallization, conformation, and ionic conductivity of poly(ethylene oxide) (PEO) in its miscible blend with poly(methyl methacrylate) (PMMA) is studied. Differential scanning calorimetry showed that the incorporation of salt ions into the blend suppresses the crystallinity of PEO. The X‐ray diffraction revealed that the unit‐cell parameters of the crystals are independent of the LiClO4 concentration despite of the existence of ionic interactions between PEO and Li cations. In addition, the complexation of the Li+ ions by oxygen atoms of PEO is investigated via Fourier transform infrared spectroscopy. The conformational changes of PEO segments in the presence of salt ions are studied via Raman spectroscopy. It is found that PEO chains in the blend possess a crown‐ether like conformation because of their particular complexation with the Li+ ions. This coordination of PEO with lithium cations amorphize the PEO and is accounted for suppressed crystallinity of PEO in the presence of salt ions. Finally, electrochemical impedance spectroscopy is used to characterize the ionic conductivity of PEO in the PEO/PMMA/LiClO4 ternary mixture at various temperatures. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
93.
94.
Mohammad Reza Saeb Hadi Ramezani‐Dakhel Hossein Ali Khonakdar Gert Heinrich Udo Wagenknecht 《应用聚合物科学杂志》2013,127(6):4241-4250
After‐hatching eggshell (AHES) nanobiofiller and nanocalcium carbonate (nano‐CA) were separately added to various elastomers, such as acrylonitrile butadiene rubber (NBR), styrene butadiene rubber (SBR), and natural rubber (NR), in various amounts of 5, 10, and 15 phr. The effect of particle size and dispersion of such nanofillers on thermomechanical properties and curing characteristics were then investigated. The ultimate tensile properties of SBR and NR nanocomposites were improved to some extent when 5 phr of AHES nanofiller was added to the rubber compound compared to CA. In the case of NBR nanocompounds, however, the mechanical properties were seemingly comparable, irrespective of the type of nanofiller. This contradictive behavior could be attributed to the alteration of crosslink density due to particular filler–matrix interaction while using mineral and natural fillers. The results of the rheometric study revealed that using AHES rather than CA slightly increases the scorch time of all types of prepared nanocomposites, whereas a significant drop in the optimum curing time was seen for NBR nanocomposites containing AHES biofiller. Moreover, thermogravimetric analysis showed similar thermal stability for SBR nanocomposites containing AHES and CA fillers. Finer particle size of CA and higher porosity of AHES at high and low loading levels were respectively the main reasons for improvement of ultimate properties. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
95.
Mohammad Reza Saeb Mehdi Moghri Hossein Ali Khonakdar Udo Wagenknecht Gert Heinrich 《乙烯基与添加剂工艺杂志》2013,19(3):168-176
The influence of the type and content of organically modified nanoclay (NC) and the amount of calcium stearate (Ca.St) on the fusion characteristics of a poly(vinyl chloride) (PVC) nanocomposite was studied by using response surface methodology. To interpret the fusion behavior, different PVC/NC compounds were prepared in a Plasticorder with a constant rotor speed of 60 rpm while keeping the processing time and temperature constant. The results revealed that introducing NC particles into the PVC compound resulted in an increase in the maximum torque (MAT), while the minimum torque (MIT) declined. On the contrary, both the MAT and MIT values slightly increased with increasing Ca.St content. It was also found that with increasing NC content, the fusion time increased and the fusion factor decreased, whereas increasing the Ca.St lowered the fusion time. Furthermore, the difference between the MIT and MAT values demonstrated multifarious behaviors depending on the material type. Ultimately, a correlation was established between the material characteristics and the fusion factor of the PVC nanocompounds. J. VINYL ADDIT. TECHNOL., 19:168‐176, 2013. © 2013 Society of Plastics Engineers 相似文献
96.
In this work, the method of moments is used for solution of population balance equations appearing in modeling of emulsion polymerization (EP). The zero-one model without coagulation effect and the pseudo-bulk model including coagulation effect are investigated as two common approaches for modeling EP processes. The fixed quadrature method is used to close the set of moment equations, and the maximum entropy approach is applied to reconstruct the particle size distribution from a finite number of its moments. Comparing the results with those obtained by the high-precision finite volume technique indicates that, despite the low computational load of the moment method, it has an acceptable accuracy. These features support use of the moment technique for other applications such as on-line control or optimization in particulate processes. 相似文献
97.
Reza Ghasemi Reza Shoja-Razavi Reza Mozafarinia Hossein Jamali 《Ceramics International》2013,39(8):8805-8813
The main goal of this paper was to evaluate and compare the microstructure and mechanical properties of plasma-sprayed nanostructured and conventional yttria stabilized zirconia (YSZ) thermal barrier coatings (TBCs). To this end, NiCrAlY bond coat, nanostructured, and conventional YSZ coatings were deposited on Inconel 738LC substrate by atmospheric plasma spraying (APS). The mechanical properties of the coating were evaluated using nanoindentation and bonding strength tests. The microstructure and phase composition of the coating were characterized by field emission scanning electron microscopy (FESEM) and X-ray diffractometry (XRD). The nanostructured YSZ coating contained both nanosized particles retained from the powder and microcolumnar grains formed through the resolidification of the molten part of the powder, whereas the microstructure of the conventional YSZ coating consisted of columnar grain splats only. The phase composition of the as-sprayed nanostructured coating consisted of the non-transformable tetragonal phase, while the conventional coating showed the presence of both the monoclinic and non-transformable tetragonal phases. The results of nanoindentation and bonding strength tests indicated that the mechanical properties of the nanostructured coating were better than those of the conventional coating. 相似文献
98.
Mohammad Hossein Habibi Reza Sheibani 《Journal of Industrial and Engineering Chemistry》2013,19(1):161-165
Silver-doped zinc oxide (SDZO) films have been grown on glass substrate by a novel combination of sol–gel and photochemical deposition processes (SGPD). The effect of sintering on structural, electrical and optical properties was investigated. The films were characterized by UV–vis absorption spectroscopy (UV–vis), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The result of X-ray photoelectron spectroscopy (XPS) revealed that the binding energy of Ag 3d5/2 for SDZO shifts remarkably to the lower binding energy compared to the pure metallic Ag due to the interaction between silver and zinc oxide. The XRD spectra of the SDZO films indicate that silver was incorporated in the hexagonal crystal structure of zinc oxide. SEM micrographs show the uniform distribution of spherical grains of about 73 nm grain size for the pure zinc oxide thin films. The results indicated that silver doping photochemical deposition was a feasible method to tune the optical properties of zinc oxide nanostructures. SDZO films coated on glass were applied for the photodegradation of mercaptan in water. SDZO films were applied for degradation of mercaptobenzoxazole which reduced the mercaptan concentration to more than 98%. 相似文献
99.
Seyed‐Ataollah Mirshafiei‐Langari Vahid Haddadi‐Asl Hossein Roghani‐Mamaqani Masoud Sobani Khezrollah Khezri 《Polymer Composites》2013,34(10):1648-1654
Polystyrene nanocomposite with mixed free and anchored chains was synthesized by atom transfer radical polymerization. Attachment of 3‐(trimethoxysilyl)propyl methacrylate with a double bond on the nanoporous silica aerogel surface results in a double bond grafted silica aerogel which could be incorporated into the polystyrene chains by a grafting‐through process. Conversion and molecular weight evaluation was carried out using gas chromatography and gel permeation chromatography, respectively. Double bond containing silica aerogel has an inconsiderable effect on conversion. There is no considerable discrepancy between the molecular weights of the free and anchored chains. Addition of silica aerogel with pendant CC bonds leads to increase of apparent rate constant of polymerization and also molecular weights. This is mainly because of initiator trapping in silica aerogel pores. Every percent of double bond containing silica aerogel with respect to styrene results in trapping of about 0.08 mol of ethyl alpha‐bromoisobutyrate among the silica pores. POLYM. COMPOS., 34:1648–1654, 2013. © 2013 Society of Plastics Engineers 相似文献
100.
In connection with our research program directed toward the synthesis of anthraquinones by new catalyst, we achieved a new method for preparation of some anthraquinone derivatives from the reaction of aromatic compounds with phthalic anhydride in the presence of silica sulfuric acid (SSA). The advantages of this method are availability of starting materials, simplicity of the reaction, reusability of catalyst and purity of products. In this reaction, the products were obtained via easy work-up in high yields and short reaction times. The structures of products were assigned by physical data and spectroscopic methods. 相似文献