Preparation and sintering of nano Fe coated Si3N4 composite powders

Fe/Si₃N₄ composite powder was synthesized by the heterogeneous precipitation-thermal reduction process, and then pressed into flakes under a pressure of 10 MPa. Flakes were sintered by pressureless and hot-pressing at 1 600 °C under 0.1 MPa N₂. The chemical composition, phases and microstructure of composite powder and sintered flakes were investigated by energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results show that the structure of composite powders is Si₃N₄ coated by nano Fe. The crystal phases of sintered flakes by pressureless are Fe(Si) compound, SiC and Si₃N₄. The crystal phases of the sintered samples by hot-pressing are Fe, Fe(Si) compound and Si₃N₄. It is found that crystal phases flakes obtained by pressureless and hot-pressing are very different. Foundation item: Project(50804016) supported by the National Natural Science Foundation of China     

多壁碳纳米管负载ZnO纳米复合材料的制备及其光催化性能研究

采用溶胶法,以醋酸锌和硝酸处理过的多壁碳纳米管（MWCNTs）为主要原料,制备了MWCNTs-ZnO光催化复合材料。通过X射线衍射（XRD）、透射电子显微镜（TEM）、扫描电子显微镜（SEM）等手段研究了制得样品的形态结构;通过紫外-可见分光光度计（UV-vis）,在紫外光照射下,分析比较了MWCNTs-ZnO复合材料、MWCNTs和ZnO的混合物以及纯ZnO对甲基橙光催化降解的性能。结果表明：在相同条件下MWCNTs-ZnO复合催化剂对甲基橙光降解有着最高的光催化活性。讨论了复合催化剂用量、重复使用等因素对甲基橙光催化降解效果的影响,并就复合催化剂的抗光腐蚀机制进行了初步的探讨。     

基于保局映射的图像纹理聚类

为了解决图像检索中的聚类问题,提出一种改进的图像纹理聚类算法.在纹理特征提取阶段,采用双树复小波对图像进行分解,然后对每个高频段提取直方图签名作为纹理特征;在聚类阶段,根据数据分布的密度来动态地计算数据点的邻接矩阵,再采用保局映射进行降维,对降维后的数据进行k-means聚类.通过采用直方图签名的方式能有效地表示图像纹理在各个方向上特征信息,同时根据数据密度构建的邻接矩阵,能够和保局映射一起更有效地发掘数据之间的局部相关性.实验表明:相对于传统方法,该算法具有更高的聚类正确性.     

新自由主义中的政府与市场理论述评

作为凯恩斯主义的反对者,新自由主义以抵制政府干涉,提倡自由市场竞争的面目出现,在一定程度上被看做是对古典自由主义的复辟,但它绝不仅仅是对古典"放任自由"的一种简单继承。对新自由主义主流学派关于政府与市场理论进行考察,理清新自由主义理论思想,从而对其有一个更客观的认识和评价。     

未来电网中的独立电力系统模式

集中发电、远距离输电和统一配电仍是目前电能生产、输送和分配的主要方式．不断增长的电力需求和消费模式以及新能源的开发利用,使得传统互联电力系统面临更大的挑战,迫切需要有与之相适应的电能生产和消费模式．为此,探讨未来电网的一种新模式——独立电力系统,介绍独立电力系统的概念、特点及其典型应用,阐述不同应用环境下独立电力系统在安全稳定、电能质量、经济节能以及自愈控制等方面面临的新需求,分析独立电力系统发展过程中需要解决的关键问题,指出独立电力系统的发展方向及其关键技术．     

GD2308高速加固缝纫机压脚有限元建模与分析

以工业缝纫机的减振降噪为应用背景,针对其结构特点及工作特性,通过CATIA对GD2308高速加固缝纫机压脚进行有限元建模,应用有限元软件ANSYS对压脚进行网格的划分,生成有限元分析模型,对压脚进行动态特性分析,计算压脚的前10阶固有频率与前6阶振型,给出振型图.分析结果表明,压脚结构振动主要表现为弯曲、扭转和弯扭组合...     

气体作冷却润滑剂的绿色切削试验

为实现绿色切削,研究了无污染、无危害的冷却润滑技术.采用氮气、氧气、二氧化碳气、氩气及过热水蒸气作冷却润滑剂,进行了单因素切削试验.试验结果表明,这些气体冷却润滑剂可以减小切削变形、切削力,降低切削温度,改善加工表面形貌.根据试验结果和冷却润滑作用机理分析可知,气体在切削中具有一定的冷却润滑作用,同时具有来源广泛、无毒害和污染、不用回收处理等绿色特点,故气体具备绿色切削的潜力.     

Experiments and reaction characteristics of liquid phase simultaneous removal of SO<Subscript>2</Subscript> and NO

Experiments of simultaneous removal of SO₂ and NO from simulated flue gas, using NaClO₂ solution as the absorbent, were carried out in a self-designed bubble reactor, and high simultaneous removal efficiencies of SO₂ and NO were obtained under the optimal experimental conditions. The mechanism of simultaneous removal based on NaClO₂ acid solutions was proposed by analyzing the removal products. Possibility and limitation of the desulfurization and denitrification using NaClO₂ acid solutions were calculated by thermodynamic methods. Experimental results of reaction kinetics for simultaneous desulfurization and denitrification indicated that the oxidation-absorption processes of SO₂ and NO were divided into two zones, namely the fast and slow reaction zones. In the slow reaction zones both were zero order reactions, and in the fast reaction zones, the reaction order, rate constant and activation energy of SO₂ reaction with absorbent were 1.4, 1.22 (mol·L⁻¹)^−0.4·s⁻¹ and 66.25 kJ·mol⁻¹, respectively, and 2, 3.15×10³ (mol·L⁻¹) ⁻¹·s⁻¹, and 42.50 kJ·mol⁻¹ for NO reaction, respectively. Supported by the National High-Tech Research and Development Program of China (“863” Project) (Grant No. 2007AA061803)     

胆固醇氧化酶高产菌株的诱变选育及产酶条件优化

在对细脚拟青霉、玫烟色拟青霉、粉拟青霉、香菇、平菇、金针菇等胆固醇氧化酶产生菌初筛的基础上．选择以产酶较高的玫烟色拟青霉作为紫外诱变的出发菌株,筛选出一株相对高产突变菌株MFEC006,其酶活达到了0．5483U／mL,比出发菌株提高了154％,经8次传代培养,突变株性质稳定．对MFEC006菌株产酶条件进行优化,得出其最佳产酶条件为：pH为6．5,温度27℃,接种量10％,摇床转速180r／min．     

涵洞工程软弱地基处理中松木桩的应用

介绍赤天化纸业公司涵洞工程软弱地基的处理,针对软弱地基的不同构成需采取不同的处理方法,结合工程实践,对特殊环境下采用松木桩处理软弱地基的问题作了一些探讨。