油脂己烷浸出工程进展

油脂己烷浸出工程经过几十年的发展，在工艺、设备、自控、节能、环保等方面都已趋于完善。装置的规模日趋大型化。车间内的工段组合更加科学、合理与多样化，浅料层浸出器，形式多样化的湿粕脱溶系统，湿粕挤压机，废水零排放系统，不同理念的负压蒸发及余热回收系统，蒸汽冷凝水的再利用，简洁实用的全电脑操作系统，分步萃取，混合油过滤，浸出车间内的混合油碱炼、水化脱胶、磷脂干燥等使得当今的油脂浸出向大型化、集约化、自动化、节能环保的方向发展，为客户提供了越来越多的选择。     

Material removal and surface damage in EDM of Ti3SiC2 ceramic

Material removal and surface damage of Ti₃SiC₂ ceramic during electrical discharge machining (EDM) were investigated. Melting and decomposition were found to be the main material removal mechanisms during the machining process. Material removal rate was enhanced acceleratively with increasing discharge current, i_e, working voltage, u_i, but increased deceleratively with pulse duration, t_e. Microcracks in the surface and loose grains in the subsurface resulted from thermal shock were confirmed, and the surface damage in Ti₃SiC₂ ceramic led to a degradation of both strength and reliability.     

Synthesis of nonsharp distillation sequences via genetic programming

This paper addresses the application of Genetic Programming (GP) to the synthesis of multicomponent product nonsharp distillation sequences. Combined with the domain knowledge of chemical engineering, some evolutionary factors are improved, and a set of special encoding method and solving strategy is proposed to deal with this kind of problem. The system structural variable is optimized by GP and the continuous variable is optimized by the simulated annealing algorithm simultaneously. Because GP has an automatic searching function, the optimal solution can be found including distillation, splitting, blending and bypassing operations automatically without any superstructures of nonsharp distillation sequences. Three illustrative examples are presented to demonstrate the effective computational strategies.     

钢纤维聚合物混凝土抗压本构关系

钢纤维聚合物混凝土是由聚合物混凝土基体和钢纤维共同组成的纤维增强复合材料，它的力学行为不仅依赖于聚合物混凝土基体的行为，而且与钢纤维的掺量、分散特征以及钢纤维的几何尺寸有关，本文将基于损伤力学原理研究在不同纤维掺量下的钢纤维聚合物混凝土的全程压力-应变曲线及其本构模型。     

Electrochemical determination of estradiol using a poly(l-serine) film-modified electrode

A thin film of poly(l-serine) was prepared via electropolymerization for the determination of trace levels of estradiol. In pH 5.0 phosphate buffer, l-serine was oxidized during the cyclic potential sweeps between −0.60 and 2.0 V, forming a thin film at the electrode surface. The electrochemical behavior of estradiol was investigated. The oxidation peak potential of estradiol shifts negatively at the poly(l-serine) film-coated glassy carbon electrode (GCE) compared with that at the bare GCE. Otherwise, the oxidation peak current greatly increases at the poly(l-serine) film-modified GCE. These phenomena suggest that the poly(l-serine) film exhibits catalytic activity towards the electrochemical oxidation of estradiol. Based on this, a sensitive, rapid and simple electrochemical method was proposed for the determination of estradiol. The limit of detection is evaluated to be 2.0 × 10⁻⁸ mol L⁻¹. Finally, this method was successfully used to determine estradiol in blood serum.     

Application of ultrasonic waves in activation of microcrystalline cellulose

In this work, microcrystalline cellulose (MCC) was activated with ultrasonic waves. The influences of ultrasonic treatment on the changes of supramolecular structures and morphology structure were studied by WAXS and SEM. The accessibility of the MCC was characterized by water retention value (WRV) and specific surficial area. The influence of ultrasonic treatment on the reactivity of MCC was investigated through the reaction of MCC being oxidized into 2,3‐diadehyde cellulose (DAC) by periodate sodium. The mechanism of the reactivity change of ultrasonically treated MCC was examined. The results showed that the degree of crystallinity of MCC decreased and the degree of polymerization showed little change after treatment with ultrasonic waves. The morphologial variation of the treated MCC was significant when compared with the untreated MCC, which contribute to the improvement of accessibility. The aldehyde content of DAC prepared from ultrasonically treated MCC was improved from 64.19 to 85.00%, indicating that the regioselective oxidation reactivity of MCC was significantly improved. The aldehyde content was found to first increase with time of ultrasonic treatment to a point, and then decrease as time progressed. In addition, the aldehyde content was found to increase with an increase in ultrasonic power. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Influence of post‐treatments on the properties of porous poly(vinyl alcohol) membranes

Porous poly(vinyl alcohol) (PVA) membranes were prepared by a phase‐inversion method. The influence of chemical crosslinking and heat treatments on the swelling degree, resistance to compaction, mechanical strength, and morphology of porous PVA membranes was extensively studied. The crosslinking degree and crystallinity of the membranes, calculated from IR spectra, increased with the treatment time. The porosity, calculated on the basis of swelling experiments, showed a decreasing trend for heat‐treated membranes but remained almost at a constant value for crosslinked membranes. Such a change was further proved with scanning electron microscopy pictures. The behavior was explained by the rearrangement of PVA chains during the heat‐treatment process, which led to morphological changes in the membranes. The mechanical properties of the porous membranes in dry and wet states were measured, and a great difference was observed between crosslinked and heat‐treated membranes in the dry and wet states. The crosslinked membranes showed good mechanical properties in the dry state but became fragile in the wet state. On the contrary, the heat‐treated membranes were more flexible in the wet state than in the dry state. This change was explained by the turnaround of inner stress in the systems during the swelling process. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Study of the effect of ultrasonic treatment on the surface composition and the flotation performance of high-sulfur coal

This paper highlighted the use of X-ray diffraction, scanning electron microscopy and X-ray fluorescence spectroscopy to investigate the changes on the surface composition of high-sulfur coal and pyrite before and after ultrasonic conditioning. The results showed that ultrasonic conditioning resulted in a decrease in the contents of iron and sulfur in coal, an increase in the content of element carbon, and an increase in the purity of the coal. Conversely, ultrasonic conditioning led to an increase in the content of iron and sulfur in pyrite, a decrease in the impure content of calcium, and a relative increase in the purity of the pyrite after ultrasonic conditioning. This study verified that on the one hand, ultrasonic conditioning can promote the pyrite separation from the high-sulfur coal, with the separated pyrite taking the form of FeS; on the other hand, it can produce a cleaning effect on the surface of coal and pyrite with the consequent increase both in hydrophobicity of coal and hydrophilicity of pyrite. The paper introduced ultrasonic pre-treatment of the slurry and stepped froth removal tests of high-sulfur coal and the study on the yield, ash and sulfur content of clean coal in different phases. The results gave further evidence of the increases both in the rate and the selectivity of flotation. This study shows that ultrasonic conditioning can enhance the performance of de-sulphurization of high-sulfur coal flotation.