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991.
Joo-Youl?HuhEmail author Sang-Uk?Han Chang-Yong?Park 《Metals and Materials International》2004,10(2):123-131
The effect on the growth kinetics of the intermetallic compounds (IMCs) in solder/Cu joints, caused by adding Bi to eutectic
Sn-3.5Ag solder alloy, was examined at the aging temperatures of 150°C and 180°C. The Cu6Sn5 layer growth was significantly enhanced, but the Cu3Sn layer growth was slightly retarded by the addition of Bi, resulting in significant growth enhancement of the total (Cu6Sn5+Cu3Sn) IMC layer with increasing Bi addition. The IMC layer growth in the Bi-containing solder joints was accompanied by the
accumulation of Bi ahead of the Cu6Sn5 layer that resulted in the formation of a liquid layer at the Cu6Sn5/solder interface. A kinetic model was developed for the planar growth of the Cu6Sn5 and Cu3Sn layers in the solder joints, accounting for the existence of interfacial reaction barriers. Predictions from the kinetic
model showed that the experimental results could be well explained by the hypothesis that the formation of a Bi-rich liquid
layer at the Cu6Sn5/solder interface reduces the interfacial reaction barrier at the interface. 相似文献
992.
采用国产3Y-TZP亚微米粉体,通过双向模压结合等静压成形有效克服了条形试样的烧结弯曲,探讨了24h排胶工艺对预烧试样力学性能的影响,通过对预烧试样热膨胀曲线的测定、不同烧结温度试样力学性能和密度的比较及XRD定量分析确定了适宜的烧结工艺。结果表明,牙科支架用陶瓷,将预烧试样升至1550℃保温0.5h,排胶工艺对预烧试样的抗弯强度和断裂韧性并无显著影响,对于即可获得足够的抗弯强度,提高其断裂韧性。 相似文献
993.
对Cu2O与Al进行热力学分析后将其粉末压制成块,测试了不同温度下反应的热分析曲线,并对反应后的试样进行X射线衍射分析.结果表明Cu2O-Al体系化学反应包括3个阶段,即第1阶段体系温度T<910 K,有少量Al2O3和Cu生成;第2阶段体系温度为910 K≤T<1103 K,Cu2O-Al体系未发生化学反应;第3阶段体系温度为1103 K≤T≤1373 K,Cu2O-Al体系发生化学反应,其产物为Cu、Al2O3及CuAlO2. 相似文献
994.
成都焊研威达自动焊接设备有限公司,是集科研、生产、销售为一体的高科技民营股份制企业,传承成都电焊机研究所40年的科技沉淀和人才积蓄,运用现代企业管理机制,使其科研实力、产业规模在国内焊接设备制造领域均位居前列,成为中国焊接设备制造行业的龙头企业之一。 相似文献
995.
In the present study, the densification of Ti/TiB composites, the growth behavior ofin-situ formed TiB reinforcement, the effects of processing variables — such as reactant powder (TiB2, B4C), sintering temperature and time — on the microstructures and the mechanical properties ofin-situ processed Ti/TiB composites have been investigated. Mixtures of TiB2 or B4C powder with pure titanium powder were compacted and presintered at 700°C for 1 hr followed by sintering at 900, 1000, 1100,
1200, and 1300°C, respectively, for 3hrs. Some specimens were sintered at 1000°C for various times in order to study the formation
behavior of TiB reinforcementin-situ formed within the pure Ti matrix. TiB reinforcements were formed through different mechanisms, such as the formation of fine
TiB and the formation of coarse TiB by Ostwald ripening or the coalescence of fine TiB. There was no crystallographic relationship
between TiB reinforcement and the matrix. There were voids at the interface between the TiB reinforcement and the Ti matrix
due to the preferential growth of coarse TiB without a particular crystallographic relationship with pure Ti matrix and the
surface energy between the Ti matrix and TiB reinforcements. Therefore, the densification of Ti/TiB2 compacts was hindered by the preferential growth of coarse TiB reinforcements. The mechanical properties ofin-situ processed composites were evaluated by measuring the compressive yield strength at ambient and high temperatures. The compressive
yield strength of thein situ processed composites was higher than that of the Ti-6A1-4V alloy. It was also found that the compressive yield strength of
the composite made from TiB2 reactant powder was higher than that of the composite made from B4C at the same volume fraction of reinforcement. A crack path examination suggested that the bonding nature of interface between
matrix and reinforcement made from TiB2 reactant powder was better than that made from B4C. 相似文献
996.
Sung-Ik Shim Yong-Soo Park Soon-Tae Kim Chi-Bok Song 《Metals and Materials International》2002,8(3):301-307
Austenitic stainless steels such as AISI 316L have been used in equipment in which fluid flows at high speeds which can induce cavitation erosion on metallic surfaces due to the collapse of cavities, where the collapse is caused by the sudden change of local pressure within the liquid. Usually AISI 316L is susceptible to cavitation erosion. This research focuses on developing a better material to replace the AISI 316L used in equipment with high speed fluid flow, such as impellers. The effects of Rare Earth Metal (REM) additions on the cavitation erosion-corrosion resistance of duplex stainless steels were studied using metallographic examination, the potentiodynamic anodic polarization test, the tensile test, the X-ray diffraction test and the ultrasonic cavitation erosion test. The experimental alloys were found to have superior mechanical properties due to interstitial solid solution strengthening, by adding high nitrogen (0.4%), as well as by the refinement of phases and grains induced by fine REM oxides and oxy-sulfides. Corrosion resistance decreases in a gentle gradient as the REM content increases. However, REM containing alloys show superior corrosion resistance compared with that of other commercial alloys (SAF 2507, AISI 316L). Owing to their excellent mechanical properties and corrosion resistance, the alloys containing REM have high cavitation erosion-corrosion resistance. 相似文献
997.
998.
999.
应用三元扩散偶技术测定了Ni-Cr-Mo三元系1358 K的等温截面,借助电子探针微区成分分析方法分析了Ni-Cr-Mo三元扩散偶的相区成分,并对其相关系进行了研究.测得Ni-Cr-Mo三元扩散偶在1358 K下存在一个中间化合物NiMo,Cr和Mo在扩散偶中形成连续固溶体,Ni和(Cr,Mo)有限固溶,扩散偶中未发现三元中间化合物.实验发现Ni-Cr-Mo三元系1358 K的等温截面存在一个三相区:Ni+NiMo+(Cr,Mo). 相似文献
1000.
采用外加恒电位下腐蚀电流-温度扫描方法研究了在0.5%Cl^-溶液中,SO4^2-浓度对316不锈钢点腐蚀行为的影响.结果表明,随着SO4^2-浓度的增加,钝化电流增加,开路电位降低.当SO4^2-浓度低于0.42%时,316不锈钢的临界点蚀温度比不存在SO4^2-时的临界点蚀温度低;当SO4^2-浓度大于0.42%时,临界点蚀温度比不存在SO4^2-时的临界点蚀温度高.从离子竞争吸附的角度进行分析,对SO4^2-加速与抑制点蚀两种作用规律的形成原因进行了解释. 相似文献