Morphological Stabilization by Supramolecular Perfluorophenyl‐C60 Interactions Leading to Efficient and Thermally Stable Organic Photovoltaics

A new PC₆₁BM‐based fullerene, [6,6]‐phenyl‐C₆₁ butyric acid pentafluorophenyl ester (PC₆₁BP^F) is designed and synthesized. This new n‐type material can replace PC₆₁BM to form a P3HT:PC₆₁BP^F binary blend or serve as an additive to form a P3HT:PC₆₁BM:PC₆₁BP^F ternary blend. Supramolecular attraction between the pentafluorophenyl group of PC₆₁BP^F and the C₆₀ cores of PC₆₁BP^F/PC₆₁BM can effectively suppress the PC₆₁BP^F/PC₆₁BM materials from severe aggregation. By doping only 8.3 wt% PC₆₁BP^F, device PC₆₁BP^F651 exhibits a PCE of 3.88% and decreases slightly to 3.68% after heating for 25 h, preserving 95% of its original value. When PC₆₁BP with non‐fluorinated phenyl group is used to substitute PC₆₁BP^F, the stabilizing ability disappears completely. The efficiencies of PC₆₁BP651 and PC₆₁BP321 devices significantly decay to 0.44% and 0.11%, respectively, after 25 h isothermal heating. Most significantly, this strategy is demonstrated to be effective for a blend system incorporating a low band‐gap polymer. By adding only 10 wt% PC₆₁BP^F, the PDTBCDTB: PC₇₁BM‐based device exhibits thermally stable morphology and device characteristics. These findings demonstrate that smart utilization of supramolecular interactions is an effective and practical strategy to control morphological evolution.     

Facile Generation of L10‐FePt Nanodot Arrays from a Nanopatterned Metallopolymer Blend of Iron and Platinum Homopolymers

Hard ferromagnetic (L1₀ phase) FePt alloy nanoparticles (NPs) with extremely high magnetocrystalline anisotropy are considered to be one of the most promising candidates for the next generation of ultrahigh‐density data storage system. The question of how to generate ordered patterns of L1₀‐FePt NPs and how to transform the technology for practical applications represents a key current challenge. Here the direct synthesis of L1₀ phase FePt NPs by pyrolysis of Fe‐containing and Pt‐containing metallopolymer blend without post‐annealing treatment is reported. Rapid single‐step fabrication of large‐area nanodot arrays (periodicity of 500 nm) of L1₀‐ordered FePt NPs can also be achieved by employing the metallopolymer blend, which possesses excellent solubility in most organic solvents and good solution processability, as the precursor through nanoimprint lithography (NIL). Magnetic force microscopy (MFM) imaging of the nanodot pattern indicates that the patterned L1₀ phase FePt NPs are capable of exhibiting decent magnetic response, which suggests a great potential to be utilized directly in the fabrication of bit patterned media (BPM) for the next generation of magnetic recording technology.     

Enzymatic Writing to Soft Films: Potential to Filter,Store, and Analyze Biologically Relevant Chemical Information

Sensor‐based chemical analyses commonly enlist either the molecular recognition capabilities of biology (e.g., enzyme biosensors) or advanced information processing algorithms (e.g., the electronic nose). Here, a hybrid approach is proposed in which an enzyme is used to “filter” chemical information and write this information to a film which then serves as a permanent storage medium that can be ‘read’ repeatedly, interactively, and by multiple sensor modalities. This approach is demonstrated by analyzing common dietary phenols that are reported to offer health benefits. Specifically, the enzyme tyrosinase is used to convert these phenols into reactive quinones that graft (i.e., write) to a chitosan film. Grafting can be detected by optical, mechanical, and electrochemical sensors. Importantly, grafting confers redox activity to the films and this redox activity can be probed interactively by advanced electrochemical methods that allow the intrinsic redox reactivities to be compared, redox interactions to be identified, and biologically relevant redox activities to be examined. The transfer of chemical and biological information to a film is envisioned to provide broader access to the extensive capabilities offered by sensor technologies and signal processing methodologies.     

Closed-form 2-D angle estimation with rectangular arrays in elementspace or beamspace via unitary ESPRIT

The UCA-ESPRIT is a closed-form algorithm developed for use in conjunction with a uniform circular array (UCA) that provides automatically paired source azimuth and elevation angle estimates. The 2-D unitary ESPRIT is presented as an algorithm providing the same capabilities for a uniform rectangular array (URA). In the final stage of the algorithm, the real and imaginary parts of the ith eigenvalue of a matrix are one-to-one related to the respective direction cosines of the ith source relative to the two major array axes. The 2-D unitary ESPRIT offers a number of advantages over other proposed ESPRIT based closed-form 2-D angle estimation techniques. First, except for the final eigenvalue decomposition of a dimension equal to the number of sources, it is efficiently formulated in terms of real-valued computation throughout. Second, it is amenable to efficient beamspace implementations that are presented. Third, it is applicable to array configurations that do not exhibit identical subarrays, e.g., two orthogonal linear arrays. Finally, the 2-D unitary ESPRIT easily handles sources having one member of the spatial frequency coordinate pair in common. Simulation results are presented verifying the efficacy of the method     

Aggregate industrial energy consumer response to wholesale prices in the restructured Texas electricity market

The aggregate response of consumers to wholesale price signals is very limited in the restructured Electric Reliability Council of Texas (ERCOT) market. An overall average own-price elasticity of demand of − 0.000008 for industrial energy consumers served at transmission voltage is estimated using a Symmetric Generalized McFadden cost function model. To date, ERCOT has sought to promote demand response to price signals without reliance on “stand alone” demand response programs, but with a market structure that is designed to facilitate economic demand response. This very limited responsiveness to wholesale price signals may prove problematic in light of policy decisions to pursue an “energy only” resource adequacy mechanism for ERCOT.     

Nanofabrication of gallium nitride photonic crystal light-emitting diodes

We describe a comparison of nanofabrication technologies for the fabrication of 2D photonic crystal structures on GaN/InGaN blue LEDs. Such devices exhibit enhanced brightness and the possibility of controlling the angular emission profile of emitted light. This paper describes three nano lithography techniques for patterning photonic crystal structures on the emitting faces of LEDs: direct-write electron beam lithography, hard stamp nanoimprint lithography and soft-stamp nanoimprint lithography with disposable embossing masters. In each case we describe variations on the technique as well as its advantages and disadvantages. Complete process details have been given for all three techniques. In addition, we show how high performance GaN dry etch techniques, coupled with optical process monitoring can transfer resist patterns into underlying GaN material with high fidelity.     

Review of high level fault modeling approaches for mixed-signal systems

In the modern analogue design, Transistor Level Fault Simulation (TLFS) plays the important part since every fault in the whole circuit has to be simulated at that level. Unfortunately, it is a very CPU intensive task even though it maintains the high accuracy. Therefore, High Level Fault Modeling (HLFM) and High Level Fault Simulation (HLFS) are required in order to alleviate the efforts of simulation. In this paper, different HLFM approaches are reviewed at the device level during last two decades. We clarify their domains of application and evaluate their strengths and current limitations. We also analyze causes of faults and introduce various test approaches.     

Room‐Temperature Phase Demixing in Bulk Heterojunction Layers of Solution‐Processed Organic Photodetectors: the Effect of Active Layer Ageing on the Device Electro‐optical Properties

Herein, we address the reduction in the external quantum efficiency (EQE) of solution‐processed organic photodetectors caused by the room temperature phase demixing of components in the composite material of the photoactive layer. The reduction takes place under ambient conditions and after the completion of device fabrication. As a model system, we study photoactive blend films that consist of the electron acceptor N,N’‐bis(alkyl)‐3,4,9,10‐perylene tetracarboxylic diimide) (PDI) and the electron donor polymer poly(9,9’‐dioctylfluorene‐co‐benzothiadiazole) (F8BT). The ambient ageing of these photo­active layers is a consequence of the PDI component segregation; however, the final PDI domain size remains smaller than the resolution limit of optical microscopy. We find that the photophysical properties of the aged F8BT:PDI layer and the EQE of the aged device are significantly altered. The fabrication of F8BT:PDI layers from solvents of increasing boiling point allows for the spectroscopic monitoring of the ageing‐induced phase segregation (a‐PSG) process. For each solvent used, the extent of a‐PSG is correlated with the PDI dispersion in the F8BT matrix as received immediately after layer deposition. The tendency for room temperature phase demixing becomes stronger as PDI is more finely dispersed in the freshly spun F8BT:PDI layer. The evolution of the room temperature phase segregation of PDI has a negative impact on the photophysical processes that are essential for charge photogeneration in the F8BT:PDI photoactive layer.     

Perceptive admission control for wireless network quality of service

As wireless networks become more widely used, there is a growing need to support advanced services, such as multimedia streaming and voice over IP. Traditional approaches to guarantee quality of service (QoS) work well only with predictable channel and network access. In wireless mobile networks, where conditions dynamically change as nodes move about the network, a stateless, high level approach is required. Since shared wireless resources are easily over-utilized, the load in the network must be controlled so that an acceptable QoS for real-time applications can be maintained. If minimum real-time requirements are not met, these unusable packets waste scarce bandwidth and hinder other traffic, compounding the problem. To enable high QoS for all admitted traffic, we propose the Perceptive Admission Control (PAC) protocol. PAC monitors the wireless channel and dynamically adapts admission control decisions to enable high network utilization while preventing congestion. Through discussion, simulations and testbed experiments, we demonstrate that PAC ensures low packet loss and delay for all admitted flows.     

Tailoring the Molecular Properties with Isomerism Effect of AIEgens

It is challenging to achieve precise control on the properties of organic π‐functional materials to widen their practical applications. On the other hand, the study of aggregation‐induced emission luminogens (AIEgens) helps achieve such goals because of inherent relationships between their luminescence behaviors and conformational variations that allow for the visual monitoring of the changes in the material properties. Inspired by this, in this work, three AIE isomers are fabricated in structures consisting of tetraphenylpyrazine and triphenylethene units with para‐, meta‐, and ortho‐position linkages, respectively. The isomerism effect brings about significantly decreased luminescence efficiency, subtly blueshifted emission, basically reduced AIE effect but boosted porosity in the aggregate state as the conformation of AIEgens evolves from an extended to a folded one. Based on the distinct properties, their respective use in blue organic light‐emitting diodes, nanofluorescent probes, and molecule‐capturing porous crystals are investigated. This work not only achieves precise property control by using the isomerism effect of AIEgens but also provides useful information on the future design of π‐conjugated materials with advanced functionalities.