Investigation of Eccentric Open Eye Formation in a Slab Caster Tundish

Metallurgical and Materials Transactions B - Inert gas shrouding in tundish can result in the formation of a tundish open eye (TOE) due to the presence of reversed flows on the upper surface of the...     

Studies on spinel cobaltites,MCo2O4 (M = Mn,Zn, Fe,Ni and Co) and their functional properties

Optimization of electrodes for charge storage with appropriate processing conditions places significant challenges in the developments for high performance charge storage devices. In this article, metal cobaltite spinels of formula MCo₂O₄ (where M = Mn, Zn, Fe, Ni and Co) are synthesized by oxalate decomposition method followed by calcination at three typical temperatures, viz. 350, 550, and 750 °C and examined their performance variation when used as anodes in lithium ion batteries. Phase and structure of the materials are studied by powder x-ray diffraction (XRD) technique. Single phase MnCo2O4,ZnCo2O4 and Co3O4 are obtained for all different temperatures 350 °C, 550 °C and 750 °C; whereas FeCo₂O₄ and NiCo₂O₄ contained their constituent binary phases even after repeated calcination. Morphologies of the materials are studied via scanning electron microscopy (SEM): needle-shaped particles of MnCo₂O₄ and ZnCo₂O₄, submicron sized particles of FeCo₂O₄ and agglomerated submicron particle of NiCo₂O₄ are observed. Galvanostatic cycling has been conducted in the voltage range 0.005–3.0 V vs. Li at a current density of 60 mA g^?1 up to 50 cycles to study their Li storage capabilities. Highest observed charge capacities are: MnCo₂O₄ – 365 mA h g^?1 (750 °C); ZnCo₂O₄ – 516 mA h g^?1 (550 °C); FeCo₂O₄ – 480 mA h g^?1 (550 °C); NiCo₂O₄ – 384 mA h g^?1 (750 °C); and Co₃O₄ – 675 mA h g^?1 (350 °C). The Co₃O₄ showed the highest reversible capacity of 675 mA h g^?1; the NiO present in NiCo₂O₄ acts as a buffer layer that results in improved cycling stability; the ZnCo₂O₄ with long needle-like shows good cycling stability.     

Failure analysis of air pre-heater tubes of a petrochemicals plant

Heat resistant alloy tubes used in the higher temperature range of 1150–1273 K depends on the protective scale integrity for prevention of corrosion induced premature failures in a mixed gas environment with potential corrodents for oxidation, carburization and sulphidation attack. Cast HK40+Nb alloy tubes of an air pre-heater unit of a petrochemical industry failed prematurely after 13,000 h in service. The unit used smoke gas containing gaseous corrodents that could cause oxidation/sulphidation/carburization type of attack. Failed parts showed crack/punctures below the corrosion product filled pits. The crack occurred in the fully carburized zone present at the thinned out centre of the pit. Factors like excessive temperature cycling, overheating, presence of impurities either in the pre-heating gas mixture or that got introduced while in operation were found to be the reasons for breach of protective scale integrity leading to unwarranted corrosion attack resulting in thinning of tube material and internal corrosion penetration which finally led to premature failure.     

Efficacy of organophosphorus derivatives containing chalcones/chalcone semicarbazones against fungal pathogens of sugarcane

Ten newly synthesized organophosphorus derivatives containing substituted chalcones and substituted chalcone semicarbazones were tested for their antifungal efficacy against Colletotrichum falcatum, Fusarium oxysporum, Curvularia pallescens (all sugarcane pathogens). The O,O-diethylphosphate derivatives containing 2-chlorochalcone and 2-chlorochalcone semicarbazone exhibited 70-85% mycelial inhibition against all the test fungi at 1000 ppm. The screening results were correlated with structural features of the tested compounds.     

Interaction between borosilicate melt and Inconel

Understanding the mode of interaction between borosilicate melt and Inconel is important for long time usage of melter pot in vitrification plant. The present study shows that significant elemental exchanges take place across the borosilicate melt/Inconel interface resulting in the development of (Fe, Ni)CrO₄ needle and (Fe, Ni)Cr₂O₄ cubic phases. This results in significant depletion of Cr within Inconel near the interface. Beside these, CrB precipitates formed along the Inconel grain boundaries.     

Face posture estimation using eigen analysis on an IBR (image based rendered) database

In this paper, we present a novel representation of the human face for estimating the orientation of the human head in a two dimensional intensity image. The method combines the use of the much familiar eigenvalue based dissimilarity measure with image based rendering. There are two main components of the algorithm described here: the offline hierarchical image database generation and organization, and the online pose estimation stage. The synthetic images of the subject's face are automatically generated offline, for a large set of pose parameter values, using an affine coordinate based image reprojection technique. The resulting database is formally called as the IBR (or image based rendered) database. This is followed by the hierarchical organization of the database, which is driven by the eigenvalue based dissimilarity measure between any two synthetic image pair. This hierarchically organized database is a detailed, yet structured, representation of the subject's face. During the pose estimation of a subject in an image, the eigenvalue based measure is invoked again to search the synthetic (IBR) image closest to the real image. This approach provides a relatively easy first step to narrow down the search space for complex feature detection and tracking algorithms in potential applications like virtual reality and video-teleconferencing applications.     

Studies of protein binding to nonpolar solutes by using zonal elution and high-performance affinity chromatography: interactions of cis- and trans-clomiphene with human serum albumin in the presence of beta-cyclodextrin

High-performance affinity chromatography and zonal elution studies were used to examine the binding that takes place between the drug clomiphene and the protein human serum albumin (HSA). Equations were derived to describe the behavior of zonal elution experiments in which a solubilizing agent is present in the mobile phase to aid in the dissolution of a competing agent or injected analyte. These equations were then used to determine the association equilibrium constants for the clomiphene/HSA system, with beta-cyclodextrin being used as a complexation agent to improve the water solubility of cis- and trans-clomiphene without affecting the nature of their binding to HSA. It was found in these studies that both cis- and trans-clomiphene have 1:1 interactions at a common binding region on HSA (association constants at pH 7.4 and 37 degrees C: cis, 7.5 x 10(6) M-1; trans, 1.3 x 10(6) M-1). Further competition experiments between cis- or trans-clomiphene and various site-selective probes indicated that the clomiphene-binding region is the same as the proposed tamoxifen site of HSA. The approach and equations used within this report are general ones that can be applied to zonal elution studies of other solute-ligand systems in which one or more of the test components have limited solubility in the desired mobile phase.