Enhanced photoconductivity and trapping rate through control of bulk state in organic triphenylamine-based photorefractive materials

In organic optical semiconductors, it is rather challenging to achieve precise control of photoconductivity and charge trapping, which determines the device performance. This paper reports on enhanced photorefractive response rate through control of the photoconductivity and trapping rate in organic triphenylamine-based photorefractive materials by means of bulk state tuning. The bulk state in organic triphenylamine-based photorefractive composites was controlled through a rapid cooling process from various melting temperatures during sample fabrication. The photoconductivity and trapping rate were determined from photocurrent measurements. Fabrication at lower melting temperatures enhanced the trapping rate for deep traps, whereas it reduced the trapping rate for shallow traps. As a result, a faster photorefractive response was obtained.     

Calculations of positron states in BEDT-TTF based organic superconductors

We have calculated positron distributions on a series of BEDT-TTF based organic conductors, whose anion species are I₃, Cu(NCS)₂, Cu(CN)[N(CN)₂], Cu[N(CN)₂]Br and KHg(SCN)₄. The results are discussed in connection with Fermiological studies by the positron annihilation method. Lifetimes and band masses of positrons have been calculated also.     

Magnetic and FTIR studies of BixY3−xFe5O12 (x = 0, 1, 2) powders prepared by the metal organic decomposition method

The crystallization process of bismuth substituted yttrium iron garnet (Bi_xY_3−xFe₅O₁₂; x = 0, 1, 2) powder prepared by the metal-organic decomposition method has been studied with various sintering temperatures. The pure garnet phase was observed for the x = 1 powder at 900 °C sintering temperature, whereas the x = 0, 2 powder showed secondary phases. The x = 0 powder showed a similar crystallization process to that of the solid state reaction method. For the x =1, 2 powders, it is proposed that the lowering of the crystallization temperature is due to the lowered stability of the intermediate phase. The infrared spectroscopy and magnetic properties were also investigated. The pure garnet phase showed three absorption bands located at 563, 598, 655 cm⁻¹ that shifted to 555, 588, 639 cm⁻¹ along with an increase of bismuth concentration. The maximum values of saturation and remanence magnetization and the minimum value of coercivity were observed for the x = 1 powder sintered at 900 °C, which were 20.8 emu/g, 2.67 emu/g, and 31.9 Oe, respectively.     

Advanced TFT SRAM cell technology using a phase-shift lithography

An advanced TFT memory cell technology has been developed for making high-density and high-speed SRAM cells. The cell is fabricated using a phase-shift lithography that enables patterns with spaces of less than 0.25 μm to be made using the conventional stepper. Cell area is also reduced by using a small cell-ratio and a parallel layout for the transistor. Despite the small cell-ratio, stable operation is assured by using advanced polysilicon PMOS TFT's for load devices. The effect of the Si₃N₄ multilayer gate insulator on the on-current and the influence of the channel implantation are also investigated. To obtain stable operation and extremely low stand-by power dissipation, a self-aligned offset structure for the polysilicon PMOS TFT is proposed and demonstrated. A leakage current of only 2 fA/cell and an on-/off-current ratio of 4.6×10⁶ are achieved with this polysilicon PMOS TFT in a memory cell, which is demonstrated in a experimental 1-Mbit CMOS SRAM chip that has an access time of only 7 ns     

Impurity‐Induced First‐Order Phase Transitions in Highly Crystalline V2O3 Nanocrystals

A first‐order phase transition in a bulk material is generally considered to arise at extended defects such as grain boundaries or dislocations, where the energetic barrier between the two phases is reduced. Downsizing a crystal to the nanoscale can exclude the number of defects, leading to enhanced kinetic stabilization of the metastable phase. Here, the disappearance of the first‐order metal–insulator transition in defect‐free V₂O₃ nanocrystals and the revival of the transition by introducing a certain Cr or Ti impurity content are investigated. The hysteresis width of the transition corresponding to the barrier height decreases with the impurity content. It is proposed that homogeneous impurity doping is a universal method that can control the occurrence of a first‐order phase transition in nanoscale materials.     

A 9-ns 1-Mbit CMOS SRAM

A 1-Mbit CMOS static RAM (SRAM) with a typical address access time of 9 ns has been developed. A high-speed sense amplifier circuit, consisting of a three-stage PMOS cross-coupled sense amplifier with a CMOS preamplifier, is the key to the fast access time. A parallel-word-access redundancy architecture, which causes no access time penalty, was also incorporated. A polysilicon PMOS load memory cell, which had a large on-current-to-off-current ratio, gave a much lower soft-error rate than a conventional high-resistance polysilicon load cell. The 1-Mbit SRAM, fabricated using a half-micrometer, triple-poly, and double-metal CMOS technology, operated at a single supply voltage of 5 V. An on-chip power supply converter was incorporated in the SRAM to supply a partial internal supply voltage of 4 V to the high-performance half-micrometer MOS transistors.<>     

Contamination and effects of perfluorochemicals in Baikal seal (Pusa sibirica). 1. Residue level, tissue distribution, and temporal trend

Concentrations of perfluorochemicals (PFCs) including perfluoroalkylsulfonates (PFSAs) and perfluoroalkylcarboxylates (PFCAs) were determined in liver and serum of Baikal seals (Pusa sibirica) collected from Lake Baikal, Russia in 2005. Among the 10 PFC compounds measured, perfluorononanoic acid (PFNA, 3.3-72 ng/g wet wt) concentrations were the highest in liver, followed by perfluorooctanesulfonate (PFOS, 2.6-38 ng/g). The accumulation profile of long-chain (C7-C12) PFCAs in particular, the predominance of PFNA, indicated that 8:2 fluorotelomer alcohol or commercially manufactured PFNA is a major local source of PFCs in Lake Baikal. No gender-related differences in the concentrations of individual PFCs or total PFCs were found. Tissues from pups and juveniles contained relatively higher concentrations of PFCs than tissues from subadults and adults, suggesting that maternal transfer of PFCs is of critical importance. Comparison of concentrations of PFCs in livers and sera collected from the same individuals of Baikal seals revealed that residue levels of PFOS, PFNA, perfluorodecanoic acid (PFDA), and perfluoroundecanoic acid (PFUnDA) were significantly higher in liver than in serum. The concentration ratios of PFNA and PFDA between liver and serum were calculated to be 14 and 15, respectively, whereas the ratio of PFOS was 2.4. This suggests preferential retention of both PFNA and PFDA in liver. Concentrations of PFOS, PFNA, and PFDA in liver were significantly correlated with those in serum, whereas concentrations of PFUnDA were not correlated in between the two tissues, suggesting differences in pharmacokinetics among these PFCs. Temporal comparisons of hepatic PFC concentrations in seals collected between 1992 and 2005 showed that the concentrations of PFOS (p = 0.0006), PFNA (p = 0.061) and PFDA (p = 0.017) were higher in animals collected in recentyears, indicating ongoing sources of PFC contamination in Lake Baikal.     

Hierarchical Tensor SOM Network for Multilevel–Multigroup Analysis

The aim of this work is to develop a visualization method for multilevel–multigroup analysis based on a multiway nonlinear dimensionality reduction. The task of the method is to visualize what kinds of members each group is composed and to visualize the similarity between the groups in terms of probability distribution of constituent members. To achieve the task, the proposed method consists of hierarchically coupled tensor self-organizing maps, corresponding to the member/group level. This architecture enables more flexible analysis than ordinary parametric multilevel analysis, as it retains a high level of interpretability supported by strong visualization. We applied the proposed method to one benchmark dataset and two practical datasets: one is the survey data on the football players belonging to different teams and the other is the employee survey data belonging to different departments in a company. Our method successfully visualizes the types of the members that constitute each group as well as visualizes the differences or similarities between the groups.     

Possible use of bulk superconductor with tunnel junctions for nuclear radiation spectroscopy

Nuclear radiation detectors with Josephson junctions, as hitherto reported, were composed of thin superconducting strips and had a poor energy resolution. A conceptual study is made on improvement of these detectors, with special consideration of quasiparticle collection. A bulk superconductor is shown to be appropriate as a radiation detector. Superconducting tunnel junctions of two types are proposed for superconducting radiation detectors of excellent energy resolution. These have high barrier penetrability and large area in order to collect all the quasiparticles generated in the superconductor by nuclear radiation.