The synthesis,swelling behaviour and rheological properties of chemically crosslinked thermosensitive copolymers based on <Emphasis Type="Italic">N</Emphasis>-isopropylacrylamide

In this contribution thermosensitive polymer matrices based on N-isopropylacrylamide have been developed. The hydrogels were prepared by photopolymerisation of N-isopropylacrylamide and 1-vinyl-2-pyrrolidinone in appropriate amounts of distilled water. The monomers were cured using a UV-light sensitive initiator called 1-hydroxycyclohexylphenylketone. These copolymers were crosslinked using ethylene glycol dimethacrylate and poly(ethylene glycol) dimethacrylate with molecular weights 600 and 1,000, at 0.1 wt% of the total monomer content. The chemical structure of the xerogels was characterised by means of Fourier transform infrared spectroscopy (FTIR) and the transition temperature of the hydrogels was determined using modulated differential scanning calorimetry (MDSC). By altering the feed ratio, hydrogels were synthesised to have lower critical solution temperatures (LCST) around 37 °C. This ability to shift the phase transition temperature of the gels provides excellent flexibility in tailoring transitions for specific uses. The samples synthesised with PEG1000DMA crosslinking agents absorbed over 18 times their weight in water, while maintaining good gel integrity thus falling marginally short of being characterised as superabsorbent. Each of the samples showed similar deswelling behaviour at 37 °C. Rheological studies showed that increasing the molecular weight of the crosslinking agent caused an increase in hydrogel strength.     

Biology of tegument associated IgG-Fc and C3 receptors inSchistosoma mansoni

Mechanisms by which schistosomes escape host immune responses are reviewed, with particular emphasis regarding the possible contributions of host or host-like Fc and C3 receptors on adult parasites.     

Stereotypes and prejudice: Their automatic and controlled components.

Three studies tested basic assumptions derived from a theoretical model based on the dissociation of automatic and controlled processes involved in prejudice. Study 1 supported the model's assumption that high- and low-prejudice persons are equally knowledgeable of the cultural stereotype. The model suggests that the stereotype is automatically activated in the presence of a member (or some symbolic equivalent) of the stereotype group and that low-prejudice responses require controlled inhibition of the automatically activated stereotype. Study 2, which examined the efforts of automatic stereotype activation on the evaluation of ambiguous stereotype-relevant behaviors performed by a race-unspecified person, suggested that when subjects' ability to consciously monitor stereotype activation is precluded, both high- and low-prejudice subjects produce stereotype-congruent evaluations of ambiguous behaviors. Study 3 examined high- and low-prejudice subjects' responses in a consciously directed thought-listing task. Consistent with the model, only low-prejudice subjects inhibited the automatically activated stereotype-congruent thoughts and replaced them with thoughts reflecting equality and negations of the stereotype. The relation between stereotypes and prejudice and implications for prejudice reduction are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

International Conference on Peyronie's disease advances in basic and clinical research. March 17-19, 1993. Introduction

The articles in this section of the Journal support the theory that the lesion of Peyronie's disease is a scar that has developed following trauma to the erect penis in a susceptible individual. The scar involves only the tunica albuginea and does not extend into the erectile tissue. Factors related to the formulation of this scar, discussed on a biochemical and cellular level, are elucidated in the following papers.     

The management of metformin overdose

Only two cases of deliberate self-poisoning with metformin have been described in the literature. We report the management of three cases, all of which presented with severe lactic acidosis. Two cases had a fatal outcome. The options for treatment and previous cases reported in the literature are reviewed. Recommendations for the management of metformin overdose include early recognition, intensive support of the cardiovascular system, the correction of metabolic acidosis and the maintenance of body temperature. The use of venovenous haemofiltration against a non-lactate containing fluid may improve outcome when sodium bicarbonate alone fails to reverse severe systemic acidosis.     

Evaluation of uncertainties in settling velocities of particles in urban stormwater runoff

Field experiments were carried out to contribute to the assessment of the VICAS protocol aiming to measure settling velocities of particles. Samples of deposited sediments have been taken in the Django Reinhardt stormwater detention and settling tank in Chassieu, France, using sediment traps located on the tank bottom. The first set of experiments was designed to assess the VICAS protocol in terms of mass balance and repeatability. A bias in the measurement of settling velocities distributions of deposited sediments (i.e. particles with high settling velocities) was suspected and confirmed by specific tests. Uncertainties in the final distribution curves have been evaluated by using Monte Carlo simulations and the law of propagation of uncertainties. All uncertainty calculations were implemented in a MatLab code named UVICAS used for each experiment. This code allows analysing the main sources of uncertainties and their evolution during experiments. Uncertainties in the final distribution curves decrease with increasing values of settling velocities and are lower than 1%.     

Tantalum pentoxide (Ta2O5) thin films for advanced dielectric applications

This paper reviews the present knowledge on tantalum pentoxide (Ta₂O₅) thin films and their applications in the field of microelectronics and integrated microtechnologies. Different methods used to produce tantalum oxide layers are described, emphazing elaboration mechanisms and key parameters for each technique. We also review recent advances in the deposition of Ta₂O₅ in the particular field of microelectronics where high quality layers are required from the structural and electrical points of view. The physical, structural, optical, chemical and electrical properties of tantalum oxide thin films on semiconductors are then presented and essential film parameters, such as optical index, film density or dielectric permittivity, are discussed. After a reminder of the basic mechanisms that control the bulk electrical conduction in insulating films, we carefully examine the origin of leakage currents in Ta₂O₅ and present the state-of-the-art concerning the insulating behaviour of tantalum oxide layers. Finally, applications of tantalum oxide thin films are presented in the last part of this paper. We show how Ta₂O₅ has been employed as an antireflection coating, insulating layer, gate oxide, corrosion resistant material, and sensitive layer in a wide variety of components, circuits and sensors.     

Anger management style and the prediction of treatment outcome among male and female chronic pain patients

Anger is a prominent emotion experienced by chronic pain patients. Anecdotes suggest that anger predicts poor outcome following multidisciplinary pain programs, but no empirical evidence documents this link. We expected that patient anger expression or suppression would predict poor outcome following a pain program and that gender differences would emerge. Pre- to posttreatment measures of lifting capacity, walking endurance, depression, pain severity and activity level were collected from 101 chronic pain patients. An 'anger expression x gender' interaction was found such that anger expression among males was correlated negatively with lifting capacity improvements. 'Anger suppression x gender' interactions emerged such that anger suppression among males was correlated negatively with improvements in depression and general activities. These effects remained significant after controlling for trait anger. Thus, how anger is managed may exert unique influence on outcomes apart from the effects of mere anger proneness, at least among male pain patients.