'EUROPART'. Airborne particles in the indoor environment. A European interdisciplinary review of scientific evidence on associations between exposure to particles in buildings and health effects

The relevance of particle mass, surface area or number concentration as risk indicators for health effects in non-industrial buildings has been assessed by a European interdisciplinary group of researchers (called EUROPART) by reviewing papers identified in Medline, Toxline, and OSH. Studies dealing with dermal effects or cancer or specifically addressing environmental tobacco smoke, house dust-mite, cockroach or animal allergens, microorganisms and pesticides were excluded. A total of 70 papers were reviewed, and eight were identified for the final review: Five experimental studies involving mainly healthy subjects, two cross-sectional office studies and one longitudinal study among elderly on cardiovascular effects. From most studies, no definite conclusions could be drawn. Overall, the group concluded that there is inadequate scientific evidence that airborne, indoor particulate mass or number concentrations can be used as generally applicable risk indicators of health effects in non-industrial buildings and consequently that there is inadequate scientific evidence for establishing limit values or guidelines for particulate mass or number concentrations.     

Characterization of particulate emissions from occupant activities in offices

This paper characterizes the relationship between occupant activities and indoor air particulate levels in a non-smoking office building. Occupant activities were recorded on video. Particulate concentrations were monitored by three optical particle counters (OPCs) in five size ranges at three heights. Particulate mass concentrations were measured gravimetrically and bioaerosol concentrations were determined by impaction methods. Occupant activities and number concentrations were determined with 1-min resolution over a 1-week period. Occupant activities such as walking past or visiting the monitoring site explained 24-55% of the variation of 1- to 25-micron diameter particle number concentrations. Statistical models associating particulate concentrations with occupant activities depended on the size fraction and included an autocorrelative term. Occupant activities are estimated to contribute up to 10 micrograms m-3 in particulate concentrations per person. Number concentrations of particles smaller than 1 micron had little correlation with indoor activities other than cigarette smoking and were highly correlated with outdoor levels. The method can be used to characterize emissions from activities if rapid measurements can be made and if activities can be coded from the video record.     

Treatment of gas-phase methanol in conventional biofilters packed with lava rock

The performance of laboratory scale methanol-degrading biofilters packed with lava rock was checked during almost 1 yr under different conditions. The biomass concentration and biomass adaptation of the inoculum dramatically affected the start-up and the performance of the systems during the first stages of operation. A fast start-up was obtained when using concentrated and adapted inocula, while diluted or non-adapted inocula proved to be much less efficient. The performance of the reactor during long-term operation was significantly affected by the toxic load and moisture content of the gas. Critical loads between 120 and 280 g/m(3)h were reached during different phases of the study. The reactor had a high stability to EBRT changes when working at values between 48.0 and 91.1s, showing little or no negative effect when decreasing the EBRT. Hardly any difference was observed regarding performance when using either a downflow or upflow feed, although slightly better results were obtained when working in a downflow mode.     

An extension of ASM2d including pH calculation

This paper presents an extension of the Activated Sludge Model No. 2d (ASM2d) including a chemical model able to calculate the pH value in biological processes. The developed chemical model incorporates the complete set of chemical species affecting the pH value to ASM2d describing non-equilibrium biochemical processes. It considers the system formed by one aqueous phase, in which biochemical processes take place, and one gaseous phase, and is based on the assumptions of instantaneous chemical equilibrium under liquid phase and kinetically governed mass transport between the liquid and gas phase. The ASM2d enlargement comprises the addition of every component affecting the pH value and an ion-balance for the calculation of the pH value and the dissociation species. The significant pH variations observed in a sequencing batch reactor operated for enhanced biological phosphorus removal were used to verify the capability of the extended model for predicting the dynamics of pH jointly with concentrations of acetic acid and phosphate. A pH inhibition function for polyphosphate accumulating bacteria has also been included in the model to simulate the behaviour observed. Experimental data obtained in four different experiments (with different sludge retention time and influent phosphorus concentrations) were accurately reproduced.     

A study of a water-reducing agent from cashew nutshell liquid

The water-reducing agent better known as superplasticizer is a recent development. A number of base materials have been used for the development of such water-reducing agents which can act better than ordinary plasticizers in concrete. The sulphonated salts of melamine, napthalene, lignin, hydroxycarboxylic acids and hydroxylated polymers are some typical compounds. Recently cashew nutshell liquid obtained from a natural product waste as a thick black phenolic compound has been converted into a water-reducing agent. This paper describes the results obtained on its effectiveness in influencing the rheological properties of flow, viscosity, particle size distribution, etc, of cement particles in hydrating cements and the water-reducing capabilities in cement mortars and concretes.     

Effect of agitation, turbidity, aluminium foil reflectors and container volume on the inactivation efficiency of batch-process solar disinfectors

We report the results of experiments designed to improve the efficacy of the solar disinfection of drinking water, inactivation process. The effects of periodic agitation, covering the rear surface of the container with aluminium foil, container volume and turbidity on the solar inactivation kinetics of Escherichia coli (starting population = 10(6) CFU ml(-1)) were investigated. It was shown that agitation promoted the release of dissolved oxygen from water with subsequent decrease in the inactivation rates of E. coli. In contrast, covering the rear surface of the solar disinfection container with aluminium foil improved the inactivation efficiency of the system. The mean decay constant for bacterial populations in foil-backed bottles was found to be a factor of 1.85 (std. dev. = 0.43) higher than that of non-foil-backed bottles. Inactivation rates decrease as turbidity increases. However, total inactivation was achievable in 300 NTU samples within 8 h exposure to strong sunshine. Inactivation kinetics was not dependent on the volume of the water container for volumes in the range 500-1500 ml.     

Environmental Implications of Treatment of Coastal Sewage Discharges

The environmental implications of implementing the requirement for treatment of coastal sewage prior to discharge, which were put forward in an EC draft Directive on municipal waste-water treatment, are examined. In order to establish the current situation, the results of a national survey of coastal and estuarine sewage discharges are presented. A review of the impact of sewage discharges on the marine environment is presented in conjunction with an assessment of the impact of sewage-treatment processes on the land and in the air. These aspects are integrated into overall conclusions about net environmental impact. Finally, a decision-tree approach to the assignment of priority to additional action required at individual locations is developed.     

A framework for rapid local area modeling for construction automation

Rapid 3D positioning and modeling in construction can be used to more effectively plan, visualize, and communicate operations before execution. It can also help to optimize equipment operations, significantly improve safety, and enhance a remote operator's spatial perception of the workspace. A new framework for rapid local area sensing and 3D modeling for better planning and control of construction equipment operation is described and demonstrated. By combining human-assisted graphical workspace modeling with pre-stored Computer-Aided Design (CAD) models and simple sensors (such as single-axis laser rangefinders and remote video cameras), modeling time can be significantly reduced while potentially increasing modeling accuracy.     

Mobilization of lead from human bone tissue during pregnancy and lactation--a summary of long-term research

The skeleton is potential endogenous source of lead during pregnancy and lactation. We have undertaken a longitudinal investigation into the mobilization of lead from the human maternal skeleton to determine whether lead is mobilized from the maternal skeleton during pregnancy and lactation, and if so, when and how much is released. Subjects in the study were migrants to Australia (n=15) whose skeletal lead isotopic composition (endogenous lead) was different to that prevailing in the Australian environment (exogenous lead). This migrant cohort was compared with 6 multi-generational Australian controls. Biological and environmental samples were taken pre-pregnancy where possible, throughout pregnancy and postpartum for at least 6 months. Newly-born infants of the migrant and Australian mothers were monitored for 6 months. Blood lead concentrations for the migrant mothers ranged from 1.5 to 20 microg/dl (geometric mean 2.8) and for Australian mothers ranged from 1.9 to 4.3 microg/dl (geometric mean 2.9). There was minimal change in lead isotopic composition of the Australian pregnant controls although there were increases of approximately 40% in blood lead concentration in 3 of 6 cases during the postpartum period and from 0 to 12% in the other 3. In the migrant pregnant subjects, the geometric mean skeletal lead contribution to blood lead using the isotopic composition was approximately 33% (range 10-88%) for 14 subjects using a revised estimate for exogenous lead. Skeletal contribution to blood lead during the postpartum period was significantly greater than during pregnancy (P<0.001). The skeletal contributions to blood lead are higher and the changes are more consistent in those subjects who conceived within 100 days of arrival in Australia compared with those who conceived longer than 100 days. In the migrant subjects, changes in blood lead concentration during pregnancy and postpartum varied from subject to subject with an overall 20% increase; the increases during the postpartum period were greater than during pregnancy (P<0.001). It was estimated that the amount of maternal skeletal lead mobilized during pregnancy and transferred to the infant via cord blood averaged approximately 79%. The increased skeletal contribution to blood lead is attributed to a low daily calcium intake of approximately 500 mgCa/day, a condition which was present in both migrant and Australian subjects. An ongoing clinical trial is providing a new cohort with calcium supplements. A summary of other aspects of the study is included and covers: additional flux released from the skeleton during pregnancy and postpartum; XRF bone lead results; urinary excretion of lead during pregnancy and postpartum; dietary contribution to blood lead in female adults and children; comparison of rates of exchange of lead in blood of newly-born infants and mothers; relationships of lead in breast milk to lead in blood, urine and diet of the infant and mother; changes in blood lead after cessation of breastfeeding; urinary lead isotopes during pregnancy and postpartum indicate no preferential partitioning of endogenous lead into plasma; a comparison of some aspects of the nonhuman primate and human pregnancy studies.