Fluorescence enhancement and cofluorescence in complexes of terbium(III) with trimellitic acid

1. Introduction Rare earth elements have an important function inlife process. The fluorescence enhancement of lan-thanides in aqueous solutions has therefore becomean area of active study in trace-level estimation oflanthanides using spectrofluorimetry [1]. Its possiblemechanism and application as fluorescence probesin biological systems have also attracted attention inrecent years [2]. Generally, fluorescence enhance-ment can be achieved through ligand sensitization.Various ligands have bee…     

数控机床远程故障诊断技术研究

本文介绍了数控机床远程故障诊断系统的结构与功能,论述了系统的构成、实现方法以及所涉及的主要技术。     

Fluorescence enhancement and cofluorescence in complexes of terbium(Ⅲ) with trimellitic acid

The fluorescence of terbium (Ⅲ) was enhanced by about three orders of magnitude in the presence of trimellitic acid (benzene-l, 2, 4-tricarboxylic acid (TLA)) in aqueous solution at pH 6. The fluorescence intensity could be greatly increased when the system of Tb3+-TLA was treated with La3+ (or Gd3+) and TritonX- 100. The addition of La3+ (or Gd3+) enhances the fluorescence of the system by about two orders of magnitude due to cofluorescence, and the TritonX-100 micellar medium plays an important role for stabilization of the system. Both the intermolecular energy transfer mode and intramolecular energy transfer mode are responsible for the mechanism of fluorescence enhancement. In the optimum conditions, the fluorescence intensity is a linear function of Tb3+ concentration in the range of 7.8 × 10-9-3.6 × 10-6 mol/L for the system Tb3+-La3+-TLA and 1.0 × 10-8-4.7 × 10-6 mol/L for the system Tb3+-Gd3+-TLA, and the limits of detection are 4.6 ×10-10 mol/L and 6.0 × 10-10 mol/L, respectively.     

200kA预焙槽强化电流过程中发生电解质粘度增加的实践探讨

通过分析200kA预焙槽在强化电流条件下电解质粘度增大的原因及对电解生产的影响,提出了规范电解生产作业制度及处理电解质粘度过大的建议,以实现降低工人劳动强度,达到工艺参数优化和提高电流效率的目的。     

加电弧推力的多功能逆变焊机

通过控制电路的巧妙设计改变弧焊电源外特性（即静特性），给出了多功能焊机手工焊接时加电弧推力的一种方法及其电路原理。     

K/Na-RE复合变质对辊环用高速钢组织及力学性能的影响

在辊环用高速钢中添加不同含量的K／Na-RE复合变质剂，对试样分别进行HSVM及力学性能测试。结果表明，随着复合变质剂含量的增加，并进行适当的热处理，高速钢中铸态碳化物趋于断网，奥氏体晶粒急剧变小，由大的枝晶变为小的等轴晶，分布趋于均匀，且高速钢的强度和韧性明显提高。当复合变质剂的加入量为1．0％时，高速钢的组织及力学性能较好。     

液压流体脉动主动控制研究现状与展望

液压流体脉动对液压系统的性能与可靠性影响很大。为了减小甚至消除液压流体脉动,各国学者在这方面做了大量工作,提出了各种主动及被动消振策略,取得了很好的消振效果。本文介绍液压流体脉动产生机理及危害、主动消振策略、目前的研究现状以及主要控制算法,提出了可能的研究方向,并对应用前景进行展望。     

300kA预焙铝电解槽中修的可行性探讨

通过对300kA电解槽停槽后的炉底状况分析,表明大型预焙槽具备中修和二次启动的可行性。同时提出大型预焙电解槽具备中修的要求,为大型电解槽进一步延长槽寿命提供了新思路。     

薄宽带钢平整机支撑辊辊型设计

针对单机架四辊光整机生产薄宽镀锌板过程中的边浪、复合浪问题，进行了现场试验和理论研究。以二维变厚度有限元程序为辊型设计的工作平台，建立了四辊光整机辊系弹性变形有限元模型，提出了变接触支撑辊（VCL辊型）技术，并与不同工作辊辊型配套使用进行仿真计算。结果表明，VCL支撑辊辊型可以增加光整机板形控制能力，消除边浪并改善支撑辊轴向不均匀的磨损状态。     

Thermochemistry on coordination behavior of samaric chloride hydrate with diethylammonium diethyldithiocarbamate

The complex of samaric chloride lower hydrate-with diethylammonium diethyldithiocarbamate (D-DDC) was synthesized conveniently in absolute alcohol and dry N2 atmosphere. The title complex was identified as Et2NH2[Sm(S2CNEt2)4] by chemical and elemental analyses, the bonding characteristics of which was characterized by IR.T he enthalpies of solution of samaric chloride hydrate and D-DDC in absolute alcohol at 298.15 K and the enthalpies change of liquid-phase reaction of formation for Et2NH2[Sm(S2CNEt2)4] at different temperatures were determined by microcalorimetry. On the basis of experimental and calculated results, three thermodynamic parameters (the activation enthalpy, the activation entropy, and the activation free energy), the rate constant, and three kinetic parameters (the apparent activation energy, the pre-exponential constant, and the reaction order) of liquid phase reaction of formation were obtained. The enthalpy change of the solid-phase title reaction at 298.15 K was calculated by a thermochemical cycle.