Reversible polarization control of single photon emission

We present reversible and a-priori control of the polarization of a photon emitted by a single molecule by introducing a nanoscale metal object in its near field. It is experimentally shown that, with the metal close to the emitter, the polarization ratio of the emission can be varied by a factor of 2. The tunability of polarization decays, when the metal is displaced by typically 30 nm. Calculations based on the multiple multipole method agree well with our experiments and predict even further enhancement with a suitable nanoantenna design.     

Age of drinking onset, driving after drinking, and involvement in alcohol related motor-vehicle crashes.

This study assessed whether persons who begin drinking at younger ages are more likely to report drunk driving and alcohol-related crash involvement over the life course, even after controlling analytically for diagnosis of alcohol dependence, years of drinking alcohol, and other personal characteristics associated with the age respondents started drinking. A national survey asked 42,862 respondents the age that they started drinking, whether they drove after drinking too much, and whether they were in motor-vehicle crashes because of their drinking. This analysis focused on 27,081 (65%), who reported ever drinking in their lifetime. The earlier the age respondents started drinking, the more likely they were to report driving after drinking too much and being in a motor-vehicle crash because of their drinking even after adjusting for current/ever diagnosis of alcohol dependence, number of years respondents had been drinking, and other characteristics and behaviors associated with the age respondents started drinking. Particularly, among persons who were never alcohol-dependent, those who began drinking in each age group under 21, relative to those starting at age 21 or older, were more likely to report "ever" and "in the past year" being in a crash after drinking too much. The traffic safety benefits of delaying drinking may extend well beyond the legal drinking age of 21.     

Microstructured Fibers for the Production of Food

Food engineering faces the difficult challenge of combining taste, i.e., tailoring texture and rheology of food matrices with the balanced intake of healthy nutrients. In materials science, fiber suspensions and composites have been developed as a versatile and successful approach to tailor rheology while imparting materials with added functionalities. Structures based on such types of physical (micro)fibers are however rare in food production mainly due to a lack of food‐grade materials and processes allowing for the fabrication of fibers with controlled sizes and microstructures. Here, the controlled fabrication of multi‐material microstructured edible fibers is demonstrated using a food compatible process based on preform‐to‐fiber thermal drawing. It is shown that different material systems based on gelatin or casein, with plasticizers such as glycerol, can be thermally drawn into fibers with various geometries and cross‐sectional structures. It is demonstrated that fibers can exhibit tailored mechanical properties post‐drawing, and can encapsulate nutrients to control their release. The versatility of fiber materials is also exploited to demonstrate the fabrication of food‐grade fabrics and scaffolds for food growth. The end results establish a new field in food production that relies on fiber‐based simple and eco‐friendly processes to realize enjoyable yet healthy and nutritious products.     

Nanoforest Nb2O5 photoanodes for dye-sensitized solar cells by pulsed laser deposition

Vertically aligned bundles of Nb(2)O(5) nanocrystals were fabricated by pulsed laser deposition (PLD) and tested as a photoanode material in dye-sensitized solar cells (DSSC). They were characterized using scanning and transmission electron microscopies, optical absorption spectroscopy (UV-vis), and incident-photon-to-current efficiency (IPCE) experiments. The background gas composition and the thickness of the films were varied to determine the influence of those parameters in the photoanode behavior. An optimal background pressure of oxygen during deposition was found to produce a photoanode structure that both achieves high dye loading and enhanced photoelectrochemical performance. For optimal structures, IPCE values up to 40% and APCE values around 90% were obtained with the N(3) dye and I(3)(-)/I(-) couple in acetonitrile with open circuit voltage of 0.71 V and 2.41% power conversion efficiency.     

Degenerate Quantum Gases in Microgravity

Clouds of ultra-cold atoms and especially Bose–Einstein condensates (BEC) provide a source for coherent matter-waves in numerous earth bound experiments. Analogous to optical interferometry, matter-wave interferometers can be used for precision measurements allowing for a sensitivity orders of magnitude above their optical counterparts. However, in some respects the presence of gravitational forces in the lab limits experimental possibilities. In this article, we report about a compact and robust experiment generating Bose–Einstein condensates in the drop tower facility in Bremen, Germany. We also present the progress of building the succeeding experiment in which a two species atom interferometer will be implemented to test the weak equivalence principle with quantum matter.     

Development of superlattice CrN/NbN coatings for joint replacements deposited by high power impulse magnetron sputtering

The demand for reliable coating on medical implants is ever growing. In this research, enhanced performance of medical implants was achieved by a CrN/NbN coating, utilising nanoscale multilayer/superlattice structure. The advantages of the novel high power impulse magnetron sputtering technology, namely, its unique highly ionised plasma, were exploited to deposit dense and strongly adherent coatings on CoCr implants. Transmission electron microscopy analysis revealed coating superlattice structure with bi-layer thickness of 3.5?nm. CrN/NbN deposited on CoCr samples showed exceptionally high adhesion, critical load values of L_C2?=?50?N in scratch adhesion tests. Nanoindentation tests showed high hardness of 34?GPa and Young’s modulus of 447?GPa. Low coefficient of friction (μ) 0.49 and coating wear coefficient (K _C)?=?4.94?×?10^?16?m³?N^?1?m^?1 were recorded in dry sliding tests. Metal ion release studies showed a reduction in Co, Cr and Mo release at physiological and elevated temperatures (70?°C) to almost undetectable levels (<1?ppb). Rotating beam fatigue testing showed a significant increase in fatigue strength from 349?±?59?MPa (uncoated) to 539?±?59?MPa (coated). In vitro biological testing has been performed in order to assess the safety of the coating in biological environment; cytotoxicity, genotoxicity and sensitisation testing have been performed, all showing no adverse effects.     

Critical Incident Stress Management (CISM) in complex systems: Cultural adaptation and safety impacts in healthcare

In complex systems, such as hospitals or air traffic control operations, critical incidents (CIs) are unavoidable. These incidents can not only become critical for victims but also for professionals working at the “sharp end” who may have to deal with critical incident stress (CIS) reactions that may be severe and impede emotional, physical, cognitive and social functioning. These CIS reactions may occur not only under exceptional conditions but also during every-day work and become an important safety issue. In contrast to air traffic management (ATM) operations in Europe, which have readily adopted critical incident stress management (CISM), most hospitals have not yet implemented comprehensive peer support programs. This survey was conducted in 2010 at the only European general hospital setting which implemented CISM program since 2004. The aim of the article is to describe possible contribution of CISM in hospital settings framed from the perspective of organizational safety and individual health for healthcare professionals. Findings affirm that daily work related incidents also can become critical for healthcare professionals. Program efficiency appears to be influenced by the professional culture, as well as organizational structure and policies. Overall, findings demonstrate that the adaptation of the CISM program in general hospitals takes time but, once established, it may serve as a mechanism for changing professional culture, thereby permitting the framing of even small incidents or near misses as an opportunity to provide valuable feedback to the system.     

Neutron powder diffraction and solid-state deuterium NMR studies of Ca2RuD6 and the stability of transition metal hexahydride salts

The crystal structure of Ca₂RuD₆ has been determined by neutron powder diffraction: space group Fm3m, K₂PtCl₆ structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340 K and 50 K. The deuterium nuclear quadrupole coupling constant, 54.7 kHz, leads to an ionic character of the Ru–D bond of 76%. The known trends in the behaviour of A₂MH₆ salts are interpreted in terms of the ionization energies of the cation and the central metal atom.     

Beyond the Normative: Low Income Private Renters' Perspectives of Housing Affordability and Need for Housing Assistance

Housing need in Australia has typically been measured using a normative measure of the percentage of income spent on housing costs. However, this normative measure has tended not to correspond with the level of need as measured by the applications for housing assistance. This article reports on a research project commissioned by the Queensland Department of Housing in 2001, examining how low income private renters view their housing situation, with a particular focus on affordability. The Department wanted to better understand the reasons for why people apply for assistance, and how helpful normative affordability analyses are in describing and finding responses to housing need. The findings challenge the conventional wisdoms, dominant discourses and research standards which are commonly used and applied about affordability and housing need. In particular, the research raises serious questions about relying on quantitative analysis alone to appreciate the complexity of housing needs and the potential demand for assistance.