Modeling gas absorption accompanied by chemical reaction in bubble column and foam-bed slurry reactors

The published data in the literature and the reported models on foam-bed reactors have been reanalyzed. It is observed that the models have been developed assuming negligible conversion in the storage section although the storage constitutes 65–85% of the total volume of liquid/slurry charged into the reactor. For confirmation of the reported information, in the present work, experiments have been performed in foam-bed and bubble column slurry reactors for carbonation of hydrated lime slurry using carbon-dioxide gas under identical conditions. A comparison of the relative performances of the two reactors has been made. Storage section is found to be the main section governing the performance of the foam-bed slurry reactor. New mathematical models have been developed for both the reactors. The model predictions agree well with the experimental data.     

Bacterial Dehydrogenases Facilitate Oxidative Inactivation and Bioremediation of Chloramphenicol

Antimicrobial resistance represents a major threat to human health and knowledge of the underlying mechanisms is therefore vital. Here, we report the discovery and characterization of oxidoreductases that inactivate the broad-spectrum antibiotic chloramphenicol via dual oxidation of the C3-hydroxyl group. Accordingly, chloramphenicol oxidation either depends on standalone glucose-methanol-choline (GMC)-type flavoenzymes, or on additional aldehyde dehydrogenases that boost overall turnover. These enzymes also enable the inactivation of the chloramphenicol analogues thiamphenicol and azidamfenicol, but not of the C3-fluorinated florfenicol. Notably, distinct isofunctional enzymes can be found in Gram-positive (e. g., Streptomyces sp.) and Gram-negative (e. g., Sphingobium sp.) bacteria, which presumably evolved their selectivity for chloramphenicol independently based on phylogenetic analyses. Mechanistic and structural studies provide further insights into the catalytic mechanisms of these biotechnologically interesting enzymes, which, in sum, are both a curse and a blessing by contributing to the spread of antibiotic resistance as well as to the bioremediation of chloramphenicol.     

Furanocoumarins in vegetables: influence of farming system and other factors on levels of toxicants

Furanocoumarins are toxic chemicals that occur naturally in edible food plants such as celery, parsnip, carrot, etc. belonging to the Apiaceae family. Lower levels of these phytochemicals are also found in citrus fruits and other crops representing the Rutaceae family. Since their presence in the human diet represents a food safety issue of concern, more knowledge is needed to reduce consumer exposure. This paper provides an overview of various factors influencing the levels of furanocoumarins in vegetables and processed commodities. Special attention is paid to the comparison of crops from organic and conventional farming systems with regard to levels of furanocoumarins and their changes during storage and processing. Copyright © 2007 Society of Chemical Industry     

Titania supported Co-Mn-Al oxide catalysts in total oxidation of ethanol

Catalytic activity of the Co-Mn-Al mixed oxide catalysts (Co:Mn:Al molar ratio of 4:1:1) supported over titania was examined in total oxidation of ethanol. The prepared catalysts were characterized by chemical analysis (AAS), surface area measurements, and temperature programmed techniques (TPR, TPD). In ethanol oxidation, the catalysts activity gradually increased with increasing active phase content. Low concentration of Co-Mn-Al oxides in the catalyst negatively affected formation of reaction byproducts: carbon monoxide production steeply increased when Co + Mn metals concentration were lower than 5 wt.%. On the other hand, formation of the second main reaction intermediate, acetaldehyde was limited, when acidity of the catalyst was not high, i.e. concentration of Co-Mn metals over titania was low.     

Assessment of the technological development and economic potential of photobioreactors

In this paper, we investigate the development and economic potential of the photobioreactor (PBR) technology for energy purposes, i.e. production of hydrogen or biofuels. The approach adopted is to consider the technology, its expected costs and revenues, and related risks from an investor perspective. To this end we develop an investment model that is used to calculate the economic feasibility of PBRs for different scenarios, including a best-case scenario, with plenty of sunlight and water, inexpensive nutrients, high prices for hydrogen and biomass, and low other costs. The best-case scenario is compared to a scenario with less favorable boundary conditions. We find that PBR efficiencies will likely be less than 10%, with typical values between 1.8% and 5.6%. We also find that hydrogen production costs would be lower than those for biodiesel or biogas from solid biomass produced in PBRs. Compared to biofuels from traditional agriculture there is a great advantage for the PBR technology if land is scarce, because land is used more efficiently. Since PBRs can be designed as a closed system they can be applied in very dry regions. In the long term this might enable this promising concept to penetrate the energy supply market.     

Optical and electrical transport properties of polyaniline–silver nanocomposite

Polyaniline–silver nanocomposite has been synthesized successfully by the chemical oxidative polymerization of aniline with ammonium peroxydisulphate as an initiator in presence of negatively charged silver nanoparticles. Silver nanoparticles are prepared by standard citrate reduction method. TEM, SEM, XRD, FTIR, TGA, DSC, optical absorption and photoluminescence studies are done for the morphological, structural, thermal and optical characterization of the polyaniline nanocomposite. From the TEM and SEM image, it is observed that nanoparticles are well dispersed in the polyaniline matrix. XRD pattern shows that polyaniline is amorphous, but peaks present in XRD pattern in polymer nanocomposites are for silver nanoparticles. TGA and DSC results show that polyaniline silver nanocomposite is more crystalline and more thermally stable. A surface plasmon absorption band is obtained from the optical absorption at 380 nm, which indicates that silver nanoparticles are present in the polyaniline matrix. The optical band gap of nanocomposite decreases with increasing content of silver nanoparticles. An enhancement in photoluminescence has been observed in polyaniline–silver nanocomposite than that in pure polyaniline. The electrical conductivity of polyaniline–silver nanocomposite increases with increase in silver nanoparticle content than that of pure polyaniline. This is a simple way by which optical and electrical properties of polyaniline may be enhanced by doping with suitable nanoparticles.     

A comparative evaluation of household preferences for solar photovoltaic standalone and mini-grid system: An empirical study in a costal village of Indian Sundarban

Solar PhotoVoltaic (SPV) based systems have been widely accepted technology for rural electrification in developing countries. The standalone SPV home lighting system has increasingly been popular among rural households, while SPV mini-grid supply system is being promoted for rural electrification schemes. This study uses data from household survey to explore the impact of household characteristics on the preference for electrical energy from SPV systems. Econometric evidence shows heterogeneity in behavioural pattern for these two SPV systems. The flexibility in use and cost of systems might explain this difference. Household characteristics such as monthly household income, household size, occupational status of household head, number of room and type of house significantly influence household’s decision for SPV standalone home lighting systems. For SPV mini-grid supply household’s income and monthly expenditure on kerosene are significant predictors. The result reported in this paper might be a valuable input for policy makers to frame right policy mix with regard to provide subsidy on rural electrification programmes.     

Frequency Stability of an Implantable Pressure Telemetry Capsule

An implantable pressure telemetry capsule was developed to permit monitoring cuff pressure in an artificial urethral sphincter during chronic conditions. Following implantation, the baseline frequency of the capsule was observed to increase by nearly 2 percent. A series of experiments was then conducted to determine whether this increase was caused by the temperature rise after implant, by fluid migration through the Silastic diaphragm, or by permeation of water vapor through the epoxy encapsulating the electronics. Elevated temperatures accounted for 84.5 percent of the frequency increase, migration through the diaphragm 11.85 percent of the total, and water permeation through the epoxy 3.65 percent.     

Cerium-based phosphors: blue luminescent properties for applications in optical displays

In this paper, we describe the blue photoluminescence (PL) observed in the multi-component oxosalt phosphor GdVO₄:Ce³⁺. Different doping concentrations (0.25–1 mol%) and heat treatment (900–1100 °C) were used to evaluate which conditions would lead to the most suitable blue phosphor for optimal display performance. The cerium doping concentration influences the profile of the emission spectrum (broad peak at 412 nm under UV excitation at 330 nm), as reflected on the values of chromaticity coordinates. On the basis of luminescent properties, we can conclude that, among the phosphors prepared in this work the most adequate for a blue display is the one obtained via the combustion method using glycine as fuel, a 0.50 mol% cerium doping concentration, and heat treatment at 1000 °C.