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91.
Among various coating systems for industrial and engineering applications, glass and glass-ceramic coatings have advantages
of chemical inertness, high temperature stability and superior mechanical properties such as abrasion, impact etc as compared
to other coating materials applied by thermal spraying in its different forms viz. PVD, CVD, plasma, etc. Besides imparting
required functional properties such as heat, abrasion and corrosion resistance to suit particular end use requirements, the
glass and glass-ceramic coatings in general also provide good adherence, defect free surface and refractoriness.
Systematic studies covering the basic science of glass and glass-ceramic coatings, the functional properties required for
a particular end-use along with the various fields of application have been reviewed in this paper. 相似文献
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Zdeněk Sobalík Kamil Jíša Dalibor Kaucký Alena Vondrová Zdeňka Tvarůžková Jana Nováková 《Catalysis Letters》2007,113(3-4):124-129
The decomposition of nitrous oxide was studied over Fe-ferrierite, Me-ferrierites and Fe/Me-ferrierites (Me: Pt, Rh and Ru).
Flow as well as batch experiments were carried out and showed a synergy between Fe and Me ions. Ions of noble metals in Fe-ferrierite
increased the catalytic activity in the sequence Pt < Rh ≅ Ru. Addition of NO substantially decreased the decomposition of
N2O over Rh/ferrierite and Ru/ferrierite, but not over bimetallic ferrierites. NO
x
species created during the decomposition of nitrous oxide alone as well as with addition of NO, and employment of nitrous
oxide labeled with 18O allowed us to assume a changing decomposition mechanism in the presence of Me ions in Fe-ferrierites. 相似文献
94.
Herrington Rachael L.; Mitchell Alexandra E.; Castellani Angela M.; Joseph Jana I.; Snyder Douglas K.; Gleaves David H. 《Canadian Metallurgical Quarterly》2008,20(4):341
Previous research has identified 2 broad components of distress in intimate relationships: overt conflict, or disharmony, and emotional distance, or disaffection. Using confirmatory factor analysis, the authors derived 2 broadband scales of disharmony and disaffection from the Marital Satisfaction Inventory-Revised (D. K. Snyder, 1997), building upon previous measures of these constructs (D. K. Snyder & Regts, 1982) derived from the original instrument. The new scales demonstrated high internal consistency and test-retest reliability, as well as discriminative validity and convergent validity with independent criteria of relationship functioning. Distinct distributions of these scales in community and clinical samples suggested their complementary role in research on intimate relationships and assessment of couples in treatment. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
95.
Qi Zhou Tijana Perovic Ines Fechner Lowell T. Edgar Peter R. Hoskins Holger Gerhardt Timm Krüger Miguel O. Bernabeu 《Journal of the Royal Society Interface》2021,18(179)
Sprouting angiogenesis is an essential vascularization mechanism consisting of sprouting and remodelling. The remodelling phase is driven by rearrangements of endothelial cells (ECs) within the post-sprouting vascular plexus. Prior work has uncovered how ECs polarize and migrate in response to flow-induced wall shear stress (WSS). However, the question of how the presence of erythrocytes (widely known as red blood cells (RBCs)) and their impact on haemodynamics affect vascular remodelling remains unanswered. Here, we devise a computational framework to model cellular blood flow in developmental mouse retina. We demonstrate a previously unreported highly heterogeneous distribution of RBCs in primitive vasculature. Furthermore, we report a strong association between vessel regression and RBC hypoperfusion, and identify plasma skimming as the driving mechanism. Live imaging in a developmental zebrafish model confirms this association. Taken together, our results indicate that RBC dynamics are fundamental to establishing the regional WSS differences driving vascular remodelling via their ability to modulate effective viscosity. 相似文献
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The Tyrosine Gate of the Bacterial Lectin FimH: A Conformational Analysis by NMR Spectroscopy and X‐ray Crystallography
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Dr. Brigitte Fiege Dr. Said Rabbani Dr. Roland C. Preston Dr. Roman P. Jakob Pascal Zihlmann Dr. Oliver Schwardt Dr. Xiaohua Jiang Prof. Timm Maier Prof. Beat Ernst 《Chembiochem : a European journal of chemical biology》2015,16(8):1235-1246
Urinary tract infections caused by uropathogenic E. coli are among the most prevalent infectious diseases. The mannose‐specific lectin FimH mediates the adhesion of the bacteria to the urothelium, thus enabling host cell invasion and recurrent infections. An attractive alternative to antibiotic treatment is the development of FimH antagonists that mimic the physiological ligand. A large variety of candidate drugs have been developed and characterized by means of in vitro studies and animal models. Here we present the X‐ray co‐crystal structures of FimH with members of four antagonist classes. In three of these cases no structural data had previously been available. We used NMR spectroscopy to characterize FimH–antagonist interactions further by chemical shift perturbation. The analysis allowed a clear determination of the conformation of the tyrosine gate motif that is crucial for the interaction with aglycone moieties and was not obvious from X‐ray structural data alone. Finally, ITC experiments provided insight into the thermodynamics of antagonist binding. In conjunction with the structural information from X‐ray and NMR experiments the results provide a mechanism for the often‐observed enthalpy–entropy compensation of FimH antagonists that plays a role in fine‐tuning of the interaction. 相似文献
100.
Lubica Sobotova Jana Jurkovicova Ludmila Sevcikova 《The Science of the total environment》2010,408(6):1264-1270