Softening and melting mechanisms of polyamides interfering with sliding stability under adhesive conditions

The thermal stability of polymers is a main issue when used as friction elements under dry sliding. Cast polyamide grades processed with either natrium or magnesium catalysors are slid on a small-scale and a large-scale test configuration to reveal the effect of softening or degradation on the sliding stability and to investigate possibilities for extrapolation of friction and wear rates between both testing scales. The combination of softening and afterwards transition into the glassy state is detrimental for the sliding stability of natrium catalysed polyamides, characterised by heavy noise during sliding. A transfer film formed under continuous softening also provides high friction. Melting during initial sliding is necessary for stabilisation in both friction and wear, and eventual softening of a molten film near the end of the test then not deteriorates the sliding stability. Softening of magnesium catalysed polyamides is favourable for the formation of a coherent transfer film resulting in more stable sliding than natrium catalysed polyamides. The differences in softening mechanisms of both polyamide grades is correlated to structural changes investigated by thermal analysis and Raman spectroscopy: the γ crystalline structure prevails in magnesium catalysed samples and the α crystalline structure is predominant in natrium catalysed samples. For internal oil lubricated polyamides, a time dependent degradation of the polyamide bulk deteriorates the supply of internal oil lubricant to the sliding interface, resulting in high friction and wear under overload conditions. As the degradation mechanisms during sliding are strongly correlated to the test set-up, extrapolation is only possible for friction in a limited application range, while wear rates cannot be extrapolated.     

Relationship of peroxide value and thiobarbituric acid value to development of undesirable flavor characteristics in fats

The peroxide value and thiobarbituric acid value were compared with the flavor score for a series of different types of fats, with and without added monoglyceride and with and without different stabilizers. The data indicated that the flavor score cannot be estimated for any given fat from either the peroxide value or the thiobarbituric acid value. Either can be used to follow the development of off flavors in a given product or formulation but the relative level may vary from product to product. Presented at the AOCS Meeting in Minneapolis, 1963.     

Inhomogeneous Density in Die Compaction: Experiments and Finite-Element Calculations

X-ray density measurements and two-color powder displacement observations were used to determine the reliability of the cylindrical test cell as a source of data for a plasticity model of granular materials. Calculations with such a model agree well with the experimental density distribution, for the cylindrical test cell itself and for a cylindrical die, compacted from one side by means of a profiled plunger .     

Satellite-Based Water Quality Mapping from Sequential Simulation with Parameter Outlier Removal

The satellite-based regression model provides the data model that identifies water quality for inland and coastal waters. However, the satellite regression usually depends on the selection of observation, satellite data, and model type. A resampling simulation technique, such as sequential simulation using geographically weighted regression (GWR simulation), can be applied in generating multiple realizations for water quality estimation to reduce the sampling effect and consider spatial heterogeneity. Traditional models often result in considerable underestimation in extreme observations. The GWR simulation provides the best goodness of fit and spatial varying relationship between observed water quality and remote sensing considering parameter outlier and noise removal for parameter stability. This simulation model can increase the sampling diversity from various observations and reduce the neighboring effects of observations using outlier and noise removal. The model that handles spatial uncertainty and heterogeneity is a novel tool for inferring the characteristics of water quality from a series of sample subsets.

     

Thermal efficiency of manifold-heat-pipe heat exchangers

The thermal efficiency of manifold-heat-pipe heat exchangers is considered. A method for predicting the efficiency and an analysis of effects of various factors of the actual process are presented.Academic Scientific Complex A. V. Luikov Heat and Mass Transfer Institute of the Academy of Sciences of Belarus, Minsk. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 66, No. 2, pp. 173–178, February, 1994.     

Composites of hydroxyapatite and bisphosphonate: properties and alveolar bone response

A composite was made by adsorption of the bisphosphonate [(3-dimethylamino-1-hydroxypropylidene)-1,1-bisphosphonate; dimethyl-APD] into an hydroxyapatite (HA) tube. Adsorbed dimethyl-APD did not change the bulk properties of the HA tube but the surface properties were altered. The amount of 0.1 mmol/L dimethyl-APD adsorbed into the HA tube was 0.78 ( ± 0.20) g after 4 weeks. The composite tube of HA and dimethyl-APD placed after extraction of teeth in the premolar regions of dogs were biocompatible, stable and bonded strongly and intimately to the alveolar bone. Although there was no bone resorption around the composite tubes, no conclusion can be drawn yet from this study as far as local inhibition of alveolar bone resorption is concerned.     

The so-called congenital trigger digit: further experience

The authors reviewed 53 patients with 70 congenital trigger digits. Three of these were seen at an early age. Most "congenital" trigger digits present later than the neonatal period. A clear difference exists between trigger thumbs and trigger fingers. In our series, thumbs were more frequently affected, 30% were bilateral and none resolved spontaneously. The long fingers were less frequently affected, and two of them (28%) recovered without operation. All other children had an operative release of the A1 pulley of the flexor tendon sheath, with excellent results.     

Report from the Wellcome Trust/EBA “Perspectives in Clinical Proteomics” retreat--a strategy to implement next-generation proteomic analyses to the clinic for patient benefit: pathway to translation

Proteomics has long been thought to hold the promise of producing results of clinical utility which will influence patient treatment and outcomes. A recent Wellcome Trust/EBI meeting and retreat--“Perspectives in Clinical Proteomics”--brought together experts from a broad range of stakeholder groups with an interest in ensuring proteomics achieves this aim. This viewpoint presents views derived from these forums, proposing a pathway for the development of next-generation proteomic analyses in the clinical setting from selection of candidates through to their validation and ultimate demonstration of utility through health technology assessments. Although not meant to be all encompassing, important elements for proteomics researchers to consider are presented.