High pressure electrical resistivity studies on Ni-doped TiO2 nanoparticles

Electrical resistivity measurement of Ni-doped TiO₂ nanoparticles were performed under high pressure using a Bridgman opposed anvil setup. It is observed that, anatase phase nanoparticles shows a sudden increase in resistivity below the pressure limit of 4 GPa and is attributed to the transition from anatase to rutile phase. In addition, the transition limit is shifted towards lower pressure region with increase in dopant concentration. But, Ni-doped TiO₂ nanoparticles with rutile phase shows a rapid decrease in resistivity up to 5 GPa and thereafter it becomes constant. Samples with constant resistivity behavior are mainly ascribed to the semiconductor-metallic transformation.     

Particle swarm optimization algorithm to maximize assembly efficiency

The demands on assembly accuracy require accurate operations both in machining and assembly in order to achieve the high performance of products. Although advanced machining technologies can be used to satisfy most of the demands on precision assembly, the corresponding manufacturing cost will also be increased. Selective assembly provides an effective way for producing high-precision assembly from relatively low-precision components. The accuracy of selective assembly is mainly based on the number of groups and the range of the group (allocated equally on the design tolerance). However, there are often surplus parts in some groups due to the imbalance of mating parts, especially in the cases of undesired dimensional distributions, which makes the methods developed and reported in the literature often not suitable for practice. In this work, a particle swarm optimization (PSO) algorithm is proposed by applying batch selective assembly method to a complex assembly with three mating components (as in ball bearing: an inner race, ball and outer race), to minimize the surplus parts and thereby maximizing the assembly efficiency. Due to the continuous nature of particle swarm optimization algorithm, standard PSO equations cannot be used to generate discrete combination of mating parts. An effective encoding scheme is developed to make the combination of mating parts feasible. The evolution performance of the PSO algorithm with different control parameter values is also analysed.     

Solid-state NMR characterization of motion in flexible polyurethane foams

High-resolution solid-state ¹³C-NMR has been used to study the phase separation and molecular motion in two series of polyurethane foams. These two series differ by one possessing the additive of lithium chloride, LiCl. NMR relaxation times can map the motion throughout the polymer molecule and detect changes in that motion arising from either microseparation or phase mixing between the different segments. There are only slight changes in the soft segment T_1p(¹³C) values as well as an increase in the hard segment T_1p(¹H) values with increase in the hard segment content for the foams studied. The T_1p(¹H) and T_1p(¹³C) values do indicate that the phase separation of the hard and soft segments is similar for all foams. A decrease in the T_1p(¹H) and T_1p(¹³C) values with increasing LiCl content indicates that the motion of the soft segments is restricted more by the hard segments. This is explained by more phase mixing in the foams containing the LiCl additive. © 1994 John Wiley & Sons, Inc.     

Selection of machining parameters for constrained machining problem using evolutionary computation

In this paper, the optimization of cutting parameters for constrained machining operations is reported. Modified genetic algorithm (MGA) is an evolutionary computation technique that has been proposed in this paper to solve the machining problem. Additional constraints have been incorporated to the multipass turning model. The optimization of drilling and facing parameters have also been carried out. To demonstrate the procedure and performance of the approach, an illustrative example is discussed. The results of the proposed algorithm are compared with other traditional and non-traditional techniques such as Newton’s method, hill climbing and ants colony technique.     

Cause of flow distributor on flow uniformity in open waterway stream passage velocity comparisons

In an open waterway flow passage, the inclusion of flow distributor paves a way to understand the idea of flow uniformity of the water along the upstream side and prevents non-uniform flow of water besides the passage length as a function of flow rate. The interesting idea in the flow distributor is its length and porosity. The essential conditions that should be satisfied are: there should not be any turbulence and there should be a possibility of achieving uniform circumferential flow in the flow passage. The other critical issue is the accurate measurement of low velocity of water. In this paper, a propeller-turbine-type anemometer is specially designed, fabricated and calibrated to measure the local velocity of water in the range of 0.001–0.01 m/s. This paper signifies how the flow uniformity is achieved by varying the size and porosity of the flow distributor.     

Combined quality loss (CQL) concept in WPCA-based Taguchi philosophy for optimization of multiple surface quality characteristics of UNS C34000 brass in cylindrical grinding

The present study highlights a multi-objective optimization problem by applying Weighted Principal Component Analysis (WPCA) coupled with Taguchi method through a case study in cylindrical grinding of UNS C34000 Medium Leaded Brass. The study aimed at evaluating the best process environment which could simultaneously satisfy multiple requirements of surface quality. In view of the fact that traditional Taguchi method fails to solve a multi-objective optimization problem, to overcome this limitation, WPCA has been coupled with Taguchi method. Furthermore, to follow the basic assumption of Taguchi method, i.e., quality attributes should be uncorrelated or independent; which is not always satisfied in practical situation; the study applied WPCA to eliminate response correlation and to evaluate independent or uncorrelated quality indices called principal components which were aggregated by WPCA to compute overall quality index denoted as Multi-Response Performance Index. A combined quality loss was then estimated which was optimized (minimized) finally. The study combined WPCA and Taguchi method for predicting optimal setting. Optimal result was verified through confirmatory test. This indicates application feasibility of the aforesaid methodology proposed for multi-response optimization and off-line control of correlated multiple surface quality characteristics in cylindrical grinding.     

Secondary population implementation in multi-objective evolutionary algorithm for scheduling of FMS

Any practical implementation of any multi-objective evolutionary algorithm (MOEA) must include a secondary population composed of all Pareto-optimal solutions found during its search process. Such an implementation with an active participation of solutions from the secondary population into the generational population of the genetic cycle is expected to improve the effectiveness of the MOEA. In this work, two kinds of secondary population, one with set of non-dominated solutions and another with a set of inferior solutions, accrued out of the generation cycles are constructed, and with different combinations of feeding of solutions from these two secondary populations, seven different implementation schemes are designed with an aim of intensifying the convergence and diversification capabilities of the genetic process of MOEA. All the schemes were implemented in a genetic algorithm-based MOEA designed to solve the scheduling problem with dual objectives for a flexible manufacturing system and tested with common experimental data. The performances of the schemes are compared, and the most appropriate implementation scheme is proposed.     

2,4-dinitroanisole transformation during advanced oxidation with ultraviolet light emitting diodes and hydrogen peroxide

This study investigated the kinetics and reaction mechanisms associated with advanced oxidation of 2,4-dinitroanisole (DNAN) with light emitting diodes (LEDs) in the UV/H₂O₂ process. The pseudo first-order reaction rate constants for DNAN oxidation depended on the H₂O₂/DNAN molar ratio and were between 0.017 and 0.026 min⁻¹. Hydroxyl radical scavenging was strongly implicated by the experimental results. High mass spectrophotometric chromatograms showed the presence of several by-products, including three with ecotoxicity that is greater than that of DNAN. Transformation pathways were analysed using Density Functional Theory (DFT), which helped to predict the presence of experimentally detected DNAN by-products by considering Mulliken charges. This study is the first to elucidate DNAN transformation mechanisms using both experimental studies and computational chemistry.     

Crack stability in edge-notched clamped beam specimens: modeling and experiments

Stability of a fracture toughness testing geometry is important to determine the crack trajectory and R-curve behavior of the specimen. Few configurations provide for inherent geometric stability, especially when the specimen being tested is brittle. We propose a new geometrical construction called the single edge notched clamped bend specimen (SENCB), a modified form of three point bending, yielding stable cracking under load control. It is shown to be particularly suitable for small-scale structures which cannot be made free-standing, (e.g., thin films, coatings). The SENCB is elastically clamped at the two ends to its parent material. A notch is inserted at the bottom center and loaded in bending, to fracture. Numerical simulations are carried out through extended finite element method to derive the geometrical factor f(a/W) and \(\hbox {K}_{\mathrm{I}}\) for different beam dimensions. Experimental corroborations of the FEM results are carried out on both micro-scale and macro-scale brittle specimens. A plot of \(\hbox {K}_{\mathrm{I}}\) vs a/W, is shown to rise initially and fall off, beyond a critical a/W ratio. The difference between conventional SENB and SENCB is highlighted in terms of \(\hbox {K}_{\mathrm{I}}\) and FEM simulated stress contours across the beam cross-section. The \(\hbox {K}_{\mathrm{IC}}\) ’s of bulk NiAl and Si determined experimentally are shown to match closely with literature values. Crack stability and R-curve effect is demonstrated in a PtNiAl bond coat sample and compared with predicted crack trajectories from the simulations. The stability of SENCB is shown for a critical range of a/W ratios, proving that it can be used to get controlled crack growth even in brittle samples under load control.     

Synthesis,structural and optical properties of Er doped,Li doped and Er + Li co-doped ZnO nanocrystallites by solution-combustion method

Pure zinc oxide (ZnO) and 2 mol% of Er, 1 mol% of Li individually doped and Er + Li co-doped ZnO nanopowders were synthesized by auto-combustion method. Crystal structure and grain size were characterized by X-ray diffractometer and found that all synthesized samples have hexagonal wurtzite crystal structure. Scanning electron microscope (SEM) and Transmission electron microscope (TEM) studies were used to determine the morphology and size of the nanocrystallites. A UV–VIS measurement shows four absorbance peaks in the visible regions and the band gap is slowly blue shifted after annealing at 800 °C. The presence of Er, Li and the hexagonal wurtzite structure was confirmed by FT-IR studies. FT-Raman spectroscopy has been employed to study the crystalline quality and structural disorders.