Ligand‐Free Synthesis of Aluminum‐Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color‐Tuned Highly Efficient Organic Solar Cells

The color of polymer solar cells using an opaque electrode is given by the reflected light, which depends on the composition and thickness of each layer of the device. Metal‐oxide‐based optical spacers are intensively studied in polymer solar cells aiming to optimize the light absorption. However, the low conductivity of materials such as ZnO and TiO₂ limits the thickness of such optical spacers to tenths of nanometers. A novel synthesis route of cluster‐free Al‐doped ZnO (AZO) nanocrystals (NCs) is presented for solution processing of highly conductive layers without the need of temperature annealing, including thick optical spacers on top of polymer blends. The processing of 80 nm thick optical spacers based on AZO nanocrystal solutions on top of 200 nm thick polymer blend layer is demonstrated leading to improved photocurrent density of 17% compared to solar cells using standard active layers of 90 nm in combination with thin ZnO‐based optical spacers. These AZO NCs also open new opportunities for the processing of high‐efficiency color tuned solar cells. For the first time, it is shown that applying solution‐processed thick optical spacer with polymer blends of different thicknesses can process solar cells of similar efficiency over 7% but of different colors.     

Application of the percolation model to gelation of an epoxy resin

The percolation model has been applied to the study of gelation of the TGDDM-DDS system (tetraglycidyldiaminodiphenylmethane–diaminodiphenylsulfone) at a mass concentration of 100–30. For each temperature the experimental viscosity curves are satisfactorily described by a percolation law. Using the degree of chemical reactions, X, as a variable, a very clear change in the reaction mechanism with temperature can be shown. Then a rate of advancement of effective reactions, Y, is defined. This value only takes intermolecular-type reactions into account, and is probably the only variable on which viscosity depends in a percolation law: η = B(1 ? Y/Y_c)^?p. We obtain Y_c= 0.45 and p= 2.0. Comparing X_c and Y_c at the gel point, we obtain information on the proportion of intramolecular reactions with temperature. It is also demonstrated that the critical percolation threshold agrees closely with the gel point determined experimentally on log G″= f(t) curves.     

Système de protection contre les erreurs pour la liaison ionosphérique

This paper presents an error correcting system designed for a 1 200 bit/s self adaptative modem operating on the HF channel. An analysis of error statistics has been made simulating a specific link whose characteristics had been measured beforehand by a HF backscattering probe. The coding system which has been chosen consists of a cascade of two cyclic codes. One corrects long bursts of errors (Kasami code), the other corrects single errors and small bursts (Reed Solomon code). Both codes are interleaved. The overall rate is 50 %. An error correction simulation has shown that in most of the cases studied, with a ber of 10^?4 a coding gain of at least 10^?2 has been achieved.     

Hot Corrosion of Silica

The high-temperature corrosion of bulk silica glass was studied in pure oxygen and in SO₃-containing oxygen atmospheres in the presence of liquid sulfate deposits at temperatures of 700° and 1000°C. No reaction and devitrification were observed without Na₂SO₄ on the surface. The wetting of the silica by the sulfate, the tendency toward basic fluxing, and the crystallization of the silica incrased with the activity of Na₂O. The most extensive degradation of vitreous silica occurred by crystallization, and the resulting spalling under basic conditions and thermal cycling at basic conditions were parabolic. This behavior is explained by a model in which the crystallization is controlled by sodium at the glass-crystal interface and its diffusion into the glass. This sodium diffuses into the glass before crystallization and is swept ahead of the crystallization front.     

Cinemetrics: Embodying architectural representation in the digital age

How can architecture emerge from the prison of its current forms of representation? Grahame Shane1 1 D.G. Shane, “Balkanization and the Postmodern City,” in Peter Lang (ed.), Mortal City, New York: Princeton Architectural Press, 1995, pp. 55-69. interprets the concluding diagram of Robin Evans' Projective Cast: Architecture and its Three Geometries2 2 Robin Evans, The Projective Cast: Architecture and Its Three Geometries, Cambridge, MA: MIT Press, 1995. as a critique of postmodern architecture's self-reflection and lack of engagement with the world. Shane argues that Evan's diagram depicts architectural representation as a self-reinforcing, closed, conceptual triangle of mirrored reflections between the human observer, the scopic regime of perspective, orthographic architectural drawing conventions, and designed objects. Shane draws his interpretation from Evans's early work on Victorian prison architecture as well as one of Evan's last public lectures. Shane characterized Evans' critical view of postmodern architectural practice and representation as a “self-correcting means of stabilization and pacification of the physical, built environment.”3 3 Shane, “Balkanization and the Postmodern City,” p. 68 This essay develops a theory of Cinemetrics that demonstrates how contemporary architectural production, with the aid of digital tools, has the capacity to break this closed system with open-ended, embodied cybernetic feed-back loops within a wider public culture engaged in the making and imagining of architecture.4 4 Brian McGrath and Jean Gardner, Cinemetrics: Architectural Drawing Today, London: Wiley-Academy, 2007. This essay argues that this break can only be accomplished by embodying architectural representation through a careful engagement with Gilles Deleuze's philosophy of movement and time images derived from cinema,5 5 Gilles Deleuze, Cinema 1: the movement image, Hugh Tomlinson and Habberjam (trans.), Minneapolis, MN: University of Minnesota, 1986; Cinema 2: the time-image, Hugh Tomlinson and Robert Galeta (trans.), Minneapolis, MN: University of Minnesota, 1989. Henri Bergson's theories of memory, attention and duration,6 6 Henri Bergson, Creative Evolution, Arthur Mitchell (trans.), Lanham, MD: University Press of America, 1991; Henri Bergson, Matter and Memory, M.N. Paul and W.S. Palmer (trans.), New York: Zone Books, 1991. and from Charles Sanders Peirce's pragmatic semiosis.7 7 Charles Sanders Peirce, The Essential Peirce: Selected Philosophical Writings, Vol. 2 (1893-1913), Peirce Edition Project, Bloomington, IN: Indiana University Press, 1998.      

Microstructure-Based Estimation of Strength and Ductility Distributions for $$\alpha +\beta $$ Titanium Alloys

Titanium alloys are processed to develop a wide range of microstructure configurations and therefore material properties. While these properties are typically measured experimentally, a framework for property prediction could greatly enhance alloy design and manufacturing. Here a microstructure-sensitive framework is presented for the prediction of strength and ductility as well as estimates of the bounds in variability for these properties. The framework explicitly considers distributions of microstructure via new approaches for instantiation of structure in synthetic samples. The parametric evaluation strategy, including the finite element simulation package FEpX, is used to create and test virtual polycrystalline samples to evaluate the variability bounds of mechanical properties in Ti-6Al-4V. Critical parameters for the property evaluation framework are provided by measurements of single crystal properties and advanced characterization of microstructure and slip system strengths in 2D and 3D. Property distributions for yield strength and ductility are presented, along with the validation and verification steps undertaken. Comparisons between strain localization and slip activity in virtual samples and in experimental grain-scale strain measurements are also discussed.

     

Impact of oxygen concentration during the deposition of window layers on lowering the metastability effects in Cu(In,Ga)Se2/CBD Zn(S,O) based solar cell

The purpose of the present paper is to focus on the impact of oxygen gas partial pressure during the sputtering of i‐ZnO and ZnMgO on the transient behavior of Cu(In,Ga)Se₂ (CIGSe) based solar cells parameters when a CBD‐Zn(S,O) buffer layer is used. Based on electrical characterization of cells, it is observed that the effect of light soaking is different on J–V characteristics depending on whether oxygen is or is not present during the first deposition time of the i‐ZnO or ZnMgO layers. In fact, when cells are prepared with standard i‐ZnO, the efficiencies are very low and a pronounced transient behavior is observed. However, when the first 10 nm of i‐ZnO or ZnMgO is formed by sputtered layer without adding oxygen during the process, depending on the thickness of the buffer layer, the transient effects strongly decreases. It is then possible to get stable cells reaching efficiencies quite similar to the CdS reference cells, especially with ZnMgO, without any post‐treatments. Copyright © 2015 John Wiley & Sons, Ltd.     

Physical aging in polymers: Comparison of two ways of determining narayanaswamy's parameter

In this work, we have investigated by differential scanning calorimetry the enthalpy relaxation of two poly[methyl(α-n-alkyl)acrylates] in which it is possible to change the length of the two alkyl chains. In particular, we have evaluated the Narayanaswamy parameter, which controls relative contribution of temperature and of structure to the relaxation times, by two methods: Grenet's method (GM) and the peak-shift method (PSM). The data obtained show that both methods lead to equivalent results. Nevertheless, PSM requires fewer experiments than GM, and PSM appears to be more practical. The results obtained on the two acrylates show that the parameter x increases with the lateral chain length, that is to say, that the temperature effects increase as the length of the alkyl chain is increased.