Ultradispersity of diamond at the nanoscale

Nanometre-sized diamond has been found in meteorites, protoplanetary nebulae and interstellar dusts, as well as in residues of detonation and in diamond films. Remarkably, the size distribution of diamond nanoparticles seems to be peaked around 2-5 nm, and to be largely independent of preparation conditions. We have carried out ab initio calculations of the stability of nanodiamond as a function of surface hydrogen coverage and of size. We have found that at about 3 nm, and for a broad range of pressures and temperatures, particles with bare, reconstructed surfaces become thermodynamically more stable than those with hydrogenated surfaces, thus preventing the formation of larger grains. Our findings provide an explanation of the size distribution of extraterrestrial and of terrestrial nanodiamond found in ultradispersed and ultracrystalline diamond films. They also provide an atomistic structural model of these films, based on the topology and structure of 2-3-nm dimond clusters consisting of a diamond core surrounded by a fullerene-like carbon network.     

In vitro interactions between DMSA-coated maghemite nanoparticles and human fibroblasts: A physicochemical and cyto-genotoxical study

Although the current production of oxide nanoparticles may be modest, the wide range of proposed applications and forecasted growth in production has raised questions about the potential impact of these nanoparticles on the environment and human health. Iron oxide nanoparticles have been proposed for an increasing number of biomedical applications although in vitro toxicity depending on the particles coating has been evidenced. The aim of this study was to examine the potential in vitro cyto- and genotoxicity on human dermal fibroblasts of DMSA-coated maghemite nanoparticles (NmDMSA) as a function of well-defined physicochemical states. Well-stabilized NmDMSA produced weak cytotoxic and no genotoxic effects. This is attributed in part to the DMSA coating, which serves as a barrier for a direct contact between nano-oxide and fibroblasts, inhibiting a potential toxic effect.     

Low response time context awareness through extensible parameter adaptation with ORCA

Ubiquitous computing applications or widespread robots interactions execute in unforeseen environments and need to adapt to changeful available services, user needs, and variations of the environment. Context-awareness ability addresses such a need, enabling, through adaptation rules, applications to react to the perceived dynamic variations. Responses to adaptation have to be quick enough to maximize the time during which the application is coherent with its environment. Adaptation rules, associating variations of the environment to application reactions, are usually established at design time. However, in unforeseen and partially anticipated environments, we claim that adaptation rules have to be dynamically extensible to match previously unexpected variations. Our approach enables rule composition and ensures a deterministic result. We propose to use parameter adaptation to quickly respond to environmental variations and dynamic compositional adaptation to provide extensibility to the parameter adaptation. To foster even lower response times, we internalize context-awareness processing and decision into the application.     

Coupled effect of time and temperature on variations of yield value of highly flowable mortar

In order to enhance the performance of self-consolidating concrete, it is important to have a better understanding of the rheological behavior of the material. The initial rheological parameters and their variations with time are closely affected by material temperature, type and dosage of high range water-reducing admixture (HRWRA), and elapsed time. This paper presents the results of an investigation aimed at evaluating the coupled influence of time and temperature on the variations of yield value with time of mortars made with two types of HRWRA: polynaphtalene sulfonate and polycarboxylate polymer. Four mortars extracted from self-consolidating concrete mixtures proportioned with various binder types and with water-to-binder ratios of 0.42 and 0.53 were prepared at 10 to 30 °C.Test results show that the yield value varies linearly with the coupled effect of time and temperature during the dormant period for mixtures made with polynaphtalene sulfonate-based HRWRA. However, such changes are found to depend on the mixture temperature for mixtures made with polycarboxylate-based HRWRA, which can influence the dispersion efficiency of the polycarboxylate polymer. The threshold temperature of mixtures made with PCP-HRWRA is shown to vary with mixture composition. Below a given threshold temperature, the mortar exhibits a considerable degree of retention or even reduction in yield value over 30% of the dormant period. A sharp increase in yield value is observed beyond 30% of the dormant period. Above this threshold temperature, the yield value is shown to increase linearly with time.     

A hybrid approach to vehicle routing using neural networks and genetic algorithms

A competitive neural network model and a genetic algorithm are used to improve the initialization and construction phase of a parallel insertion heuristic for the vehicle routing problem with time windows. The neural network identifies seed customers that are distributed over the entire geographic area during the initialization phase, while the genetic algorithm finds good parameter settings in the route construction phase that follows. Computational results on a standard set of problems are also reported.     

Effects of polypyrrole modified electrode functionalization on potentiometric pH responses

Two functionalized polypyrrole films, poly(11-N-pyrrolylundecanoic) acid and poly(N-undecylpyrrole), were used as sensitive layers for pH sensors. The functionalized pyrrole monomers were first synthesized before carrying out their electropolymerization onto non-oxidizable electrodes. The deposits were characterized by SEM imaging, XPS and PM-IRRAS to study surface structure and composition. Poly(11-N-pyrrolylundecanoic) acid coating yielded very promising results as sensitive layer in pH sensors. Indeed, the potentiometric responses from pH 4.0 to 9.0 appeared linear, reversible, stable in time over a period of 1 month and highly selective for H⁺ ions. This behavior was attributed to carboxylic acid groups which are sensitive to proton concentration changes. This was confirmed by the fact that poly(N-undecylpyrrole) film led to potentiometric responses being pH dependent only from pH 6.0 to 9.0 with low sensitivity. Poly(11-N-pyrrolylundecanoic) acid is thus promoted to be used as sensitive layer in pH sensors.     

Adaptation of the near-field acoustic sensor to the measurement of the media properties

In this work, the geometry of the near-field acoustic (NFA) sensor has been modified and adapted to the media properties to be characterized. The NFA method consists in studying the alterations of resonance curve of a horn whose tip, the probe, is immersed in the medium to be characterized. The sensor design has been changed by variation of cylinders lengths and their sections ratio. So sensitivity in the measuring of the liquids properties as well as in the characterization of the cement setting has been increased.     

Study of PEMFC ionomers through model molecules mimicking the ionomer repeat units

The thermal and electrochemical behaviours of PEMFC ionomers based on an aromatic backbone i.e., sulfonated polysulfones, sulfonated polyetheretherketones and sulfonated polybenzimidazoles, were investigated through their model molecules. Thermal degradation was characterized by weight losses and allowed inferring ionomer thermal degradations by chain breakings that cannot be detected by thermogravimetric analysis. In addition, cyclic voltammetry was used to characterize the electroactivity of some ionomers, related to their backbone and their ionic moieties. The use of model molecules is thus a useful tool for assessing both the thermal and electrochemical stability of ionomers. Lastly, due to the high concentrations used in liquid electrolytes as compared with an electrode/membrane interface it may be considered as an electrochemical aging test.