Selective oxidation of alcohols using octahedral molecular sieves: influence of synthesis method and property–activity relations

Manganese oxides having a tunnel structure (OMS-2) have been utilized as selective catalysts for alcohol oxidation. In this study manganese oxide catalysts were synthesized in different media and modified by exchanging the tunnel cation by H⁺, using acid treatment or exchanging with NH₄⁺ followed by thermolysis. Various alcohol oxidations were performed using these catalysts to ascertain the influence of synthesis method on their activity. A correlation is made between lattice oxygen instability and activity of the catalysts, which indicates involvement of the lattice oxygen in the mechanism. The exchange of the tunnel cation with the smaller H⁺ ions leads to weakening of the Mn–O bond, as verified by temperature programmed desorption (TPD) results. Only the chemisorbed oxygen on the surface (O⁻) and the lattice oxygen in the layers close to the surface is involved in the oxygen transfer during the reaction.     

Processing Expertise Systematically

The lack of a systematic approach to the management of expertise represents a major difficulty for knowledge engineers.In this paper,we present a framework for assessing knowledge-based expert systems.We show by examples how this framework may be used to guide the development of these systems.Finally ,we discuss the implications of this work and suggest areas of interest for future research.     

大连电视台分量电视车视频系统设计特点

本文介绍亚州第一台模拟分量电视车视频系统的设计思想,比较详细地阐述了该车的各种功能,总结了不同于复合电视车的新特点。     

胶溶法合成 TiO_2超微粒子

用胶溶法合成了 TiO_2超微粒子。研究了反应物浓度、胶溶剂用量、胶溶温度对胶溶过程的影响,以及表面活性剂 DBS 的量与 Ti 萃取率的关系。探讨了合成超微粒子 TiO_2的最佳条件,分析了产品的特性。200℃热处理得到的产品为非晶型圆球状,粒度均匀,平均6.0nm,在许多有机溶剂中具有良好的分散性和透明性。550℃得到晶态锐钛矿型超微粒子 TiO_2,粒度为8.5nm。700℃热处理得到金红石型TiO_2,粒度为33.2nm。     

乳胶漆的市场现状和发展前景

对乳胶漆的生产现状，产品结构以及研究开发情况作了简单的综述，并展望了乳胶漆的发展前景。     

基于感知器的快速彩色图像无损压缩算法

针对彩色图像像素和颜色分量之间存在的相关性，将神经网络中的感知器技术引入彩色图像的无损压缩算法中，提出了一种新的预测模型。应用感知器的自学习和自适应能力，对预测值进行自适应调整，使算法在运行过程中具有很小的预测残差并具有较小的动态范围。同时应用颜色空间变换来减小颜色分量间的相关性。相对于新的国际标准JPEG—LS，这种预测模型具有较低的计算复杂性。对比实验结果说明，这种算法的性能明显优于传统算法，在压缩比损失很小的前提下，其执行速度高于JPEG—LS。     

多层复合膜的成型技术

阐述了用AutoLisp程序模拟塑料熔体在2层复合膜机头内的流动情况，并介绍了复合膜机头的内部结构。     

Fabrication and Room-Temperature Single-Charging Behavior of Self-Aligned Single-Dot Memory Devices

Self-aligned single-dot memory devices and arrays were fabricated based on arsenic-assisted etching and oxidation effects. The resulting device has a floating gate of about 5-10 nm, presenting single-electron memory operation at room temperature. In order to realize the final single-electron memory circuit, this paper investigates process repeatability, device uniformity in single-dot memory arrays, device scalability, and process transferability to an industrial application     

封闭插接母线施工工艺

从工艺原理、流程、操作要点、质量要求等不同侧面介绍了封闭插接母线的施工方法，提出了应注意的安全事项，通过效益分析表明，此法具有工期短、节省人力、工序先进、效益显著等优点。