Morphology Transformation Pathway of Block Copolymer-Directed Cooperative Self-Assembly of ZnO Hybrid Films Monitored In Situ during Slot-Die Coating

Cooperative self-assembly (co-assembly) of diblock copolymers (DBCs) and inorganic precursors that takes inspiration from the rich phase separation behavior of DBCs can enable the realization of a broad spectrum of functional nanostructures with the desired sizes. In a DBC assisted sol–gel chemistry approach with polystyrene-block-poly(ethylene oxide) and ZnO, hybrid films are formed with slot-die coating. Pure DBC films are printed as control. In situ grazing-incidence small-angle X-ray scattering measurements are performed to investigate the self-assembly and co-assembly process during the film formation. Combining complementary ex situ characterizations, several distinct regimes are differentiated to describe the morphological transformations from the initially solvent-dispersed to the ultimately solidified films. The comparison of the assembly pathway evidences that the key step in the establishment of the pure DBC film is the coalescence of spherical micelles toward cylindrical domains. Due to the presence of the phase-selective precursor, the formation of cylindrical aggregates in the solution is crucial for the structural development of the hybrid film. The pre-existing cylinders in the ink impede the domain growth of the hybrid film during the subsequent drying process. The precursor reduces the degree of order, prevents crystallization of the PEO block, and introduces additional length scales in the hybrid films.     

基于自相关函数的前向频率估计方法综述

突发通信模式是数字通信的重要方式。在突发通信模式的载波同步问题中．前向频率估计算法因为具有估计速度快,而且不存在挂起现象的优点而得到广泛使用。该文介绍了基于自相关函数的前向频率估计算法的信号模型,分析TFitz算法、L＆R算法、MM算法和分段累加算法四种经典的估计算法的攮本思想并对其进行了数值仿真和性能比较,提出现有算法存在的不足以及在实际应用中的局限性,以期进一步了解并提出计算更加简单、精度更高、估计范围更广的高效频率估计算法。     

Self-Standing Covalent Organic Framework Membranes for H2/CO2 Separation

Covalent organic frameworks (COFs) are proposed as promising candidates for engineering advanced molecular sieving membranes due to their precise pore sizes, modifiable pore environment, and superior stability. However, COFs are insoluble in common solvents and do not melt at high temperatures, which presents a great challenge for the fabrication of COF-based membranes (COFMs). Herein, for the first time, a new synthetic strategy is reported to prepare continuous and intact self-standing COFMs, including 2D N-COF membrane and 3D COF-300 membrane. Both COFMs show excellent selectivity of H₂/CO₂ mixed gas (13.8 for N-COF membrane and 11 for COF-300 membrane), and especially ultrahigh H₂ permeance (4319 GPU for N-COF membrane and 5160 GPU for COF-300 membrane), which is superior to those of COFMs reported so far. It should be noted that the overall separation performance of self-standing COFMs exceeds the Robeson upper bound. Furthermore, a theoretical study based on Grand Canonical Monte Carlo (GCMC) simulation is performed to explain the excellent separation of H₂/CO₂ through COFMs. Thus, this facile preparation method will provide a broad prospect for the development of self-standing COFMs with highly efficient H₂ purification.     

带落角约束的均值聚类神经网络滑模制导律研究

为提高电视末制导炮弹对地面目标的命中精度,减小炮弹的落角误差,同时实现以期望落角命中目标,在分析带落角约束滑模制导律特点的基础上,针对RBF(Radial Basis Function)神经网络滑模制导律难以以期望落角命中目标的不足,提出了一种结合均值聚类与RBF神经网络的滑模制导律,使得神经网络在学习过程中能根据炮弹...     

Paving the Way for High-Performance UVB-LEDs Through Substrate-Dominated Strain-Modulation

AlGaN-based ultraviolet-B light-emitting diodes (UVB-LEDs) exhibit great potential in phototherapy, vitamin D3 synthesis promotion, plant growth regulation, and so on. However, subjected to the excess compressive strain induced by the large lattice mismatch between multiple quantum wells (MQWs) and AlN, UVB-LEDs that simultaneously satisfy the requirements of high light output power (LOP), low working voltage, and excellent stability are rarely reported. Here, a substrate-dominated strain-modulation strategy is proposed. By precisely manipulating the strain in AlN grown on nano-patterned sapphire substrate (NPSS) to a slightly tensile one, the compressive strain in the following Al_0.55Ga_0.45N underlayer and Al_0.28Ga_0.72N/Al_0.45Ga_0.55N MQWs is successfully suppressed. As a result, an outstanding UVB-LED with a peak wavelength at 303.6 nm is achieved. The 20 × 20 mil² UVB-LED chip shows a wall-plug efficiency (WPE) of 3.27% under a forward current of 20 mA and a high LOP of 57.2 mW with an extremely low voltage of 5.87 V under a forward current of 800 mA. It is more exciting that the LOP degradation is as low as 17% after 1000 h operation under a forward current density of 75 A cm⁻², showing excellent stability. The here-developed UVB-LED, with a high LOP and excellent reliability, will definitely promote the applications of AlGaN-based UVB-LEDs.     

接入技术-ADSL技术的现在和未来发展趋势

本文论述了ＡＤＳＬ技术的产生背景,而后介绍了ＡＤＳＬ系统的体系结构和ＡＤ－ＳＬ几种常见的信道分割和调制技术,最后对ＡＤＳＬ技术的前景进行了展望。     

钾原子的能量积聚诱导电离和双光子共振三光子电离

用染料激光激发钾蒸气 ,发现了钾原子的两种电离机制和三个电离通道 :能量积聚诱导的电离 ,4S 6S和4S 4D双光子共振三光子电离。对前两个电离通道 ,分别研究了电离谱与钾蒸气温度和激光强度的关系 ,发现了钾原子的辐射囚禁效应和钾原子电离的非线性现象 ,并给出了定性解释     

以降低HTTP页面时延为目标的参数优化

移动网络结构日趋复杂,网络场景多样化,影响用户体验的因素也越来越难以判断。结合SEQ平台系统,通过调整上行调度算法参数中"上行HARQ最大传输次数"参数,增大UE配置的最大传输次数,提高数据包传输成功率,降低信道编码率,提高解码效果,以降低HTTP页面打开时延。通过试验区优化验证,该措施能有效降低HTTP页面的各项时延。     

双圈圆阵方向特性分析

研究了双圈圆阵在两种不同放置情况下的方向特性, 主要包括阵列方向图的指向、主瓣波束宽度和副瓣峰值电平等.首先, 建立了双圈圆阵的阵列模型, 推导方向图公式并推广到多圈圆阵的情况, 随后对其进行了理论分析.其次, 通过大量仿真实验, 分析了主瓣的半功率点波束宽度和副瓣峰值电平以及扫描角分别与内、外圈阵元数以及内、外圈阵元半径之间的关系.最后, 对理论分析和仿真结果进行综合梳理, 发现在阵元内、外半径之比为0.5左右时副瓣电平最低, 波束宽度会随着内圈阵元数增大而增大, 随外圈阵元数增大而减小等结论.实验结果可为实际工程应用中合理设置阵元数目以及阵元位置提供理论参考.     

硼酸-柠檬酸比色法测银杏枝叶中黄酮苷含量

用硼酸-柠檬酸比色法测定了银杏枝叶不同季节黄酮苷的含量,结果表明:硼酸-柠檬酸比色法测定银杏枝叶中的黄酮苷含量稳定性好,精度高,标准差为0.06,黄酮苷测定回收率为98.3%～101.1%,测定结果不受脂溶性杂质的干扰;银杏枝叶中的黄酮苷含量随季节的变化而变化,8月黄酮苷含量最高。