The stability of several poly(
N-propargylamides) was investigated in solution and in solid state on the basis of molecular weight change with time, and further their thermal stability was investigated by TGA. When the stability of poly(
N-propargylamides) with varying pendent groups was compared, polymers with pendent groups of moderate size showed the highest stability in solution. Too short and too bulky pendent groups were not favorable for the stability of polymers. When poly(
N-propargylheptanamide) (poly(
6)) was stored in THF as solution at −20 °C in the absence of oxygen in dark, its degradation rate was the lowest. The degradation rate of poly(
6) depended on the solvents used, which may be related to different solubility of oxygen in these solvents. Polymers with high
cis contents degraded faster than polymers with low
cis contents did. Addition of TEMPO and DPPH into the poly(
6)/THF solution more or less depressed the degradation of poly(
6). The degradation of polymer main chain in solution was always accompanied by the decrease of
cis content, i.e. geometric isomerization from
cis- to
trans-structure. When the polymers were stored in the solid state at −20 °C, the polymers having alkyl pendent groups with moderate length were more stable than those with bulky pendent groups. Geometric isomerization occurred along with degradation in the solid state as well.
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