Thermal runaway prevention in catalytic packed bed reactor by solid temperature measurement and Control

Magnetic crystallite thermometry has been used to measure the average nickel crystallite temperature in packed bed reactors during ethane hydrogenolysis, an exothermic reaction. The technique is based on the temperature dependence of the magnetic moment of dispersed nickel catalysts. Measurement of the average catalyst temperature is very useful for reactor control because of its shorter time constant compared with exit fluid temperature. Bed temperature control based on the exit fluid temperature, which has often been used as a control variable, is too slow to protect thermal runaway of the bed. The advantage of short time constant by measuring the average catalyst temperature has been incorporated with enhanced feedback control system to control the bed temperature and prevent the thermal runaway of the catalyst bed. An enhanced feedback control structure with supervisory action performed better than the classical proportional-integral control in runaway prevention when the two control schemes were compared with each other on the basis of the trippoint (incipient thermal runaway).     

A power-aware code-compression design for RISC/VLIW architecture

We studied the architecture of embedded computing systems from the viewpoint of power consumption in memory systems and used a selective-code-compression (SCC) approach to realize our design.Based on t...     

A model for studying LCAT reaction: In vitro cholesterol esterification in pig ovarian follicular fluid

Phosphatidylcholine acyltransferase (lecithin:cholesterol acyltransferase or LCAT; EC 2.3.1.43) activity was found to be present in pig ovarian follicular fluid (POFF), in addition to pig serum (PS). The cholesterol esterification rate in both POFF and PS is linear with incubation time up to 2 hr. The mean absolute rate of POFF-cholesterol esterification was 8.1±0.4 nmoles per ml per hr approximately one-fourth of that in PS. However, the fractional rate (percent of labeled cholesterol esterified per hr) of POFF-cholesterol esterification was similar to that observed in PS. There was little variation of absolute rate of cholesterol esterification in the fluid obtained from different sizes of follicles. Fatty acid or triacylglycerol did not participate in the reaction of cholesterol esterification in POFF. No appreciable change in enzymatic activity was found from storing POFF at 4 C for periods of time up to 24 hr or at −70 C up to 2 months, but activity was lost thereafter. On the other hand, PS showed a much longer period of stability (5 days at 4 C and 9 months at −70 C). A discrepancy between the fatty acid composition of cholesteryl esters formed by the LCAT reaction and the fatty acid composition at the C-2 position of phosphatidylcholine led us to propose a two-step mechanism for the LCAT reaction. It is concluded that the LCAT of POFF, as well as that of plasma, is specific for individual fatty acids rather than for the fatty acid composition of phosphatidylcholine. The fatty acid concentration of lysophosphatidylcholine decreased during prolonged incubation times (6 to 21 hr) suggesting that the increased lysophosphatidylcholine formed as a product of the LCAT reaction may be reused as substrate for the LCAT reaction or for hydrolysis by lysophosphatidylcholine hydrolase. Presented at the AOCS Meeting, New York, May 1977.     

A new possibility of photostabilization of polymers by keto-enol tautomerizm of some β-dicarbonyls with fluoro (-CF3) group

Summary It has been found that -dicarbonyl compounds such as 1-phenyl-butane-1,3-dione(benzoyl-acetone)and 4,4,4-trifluoro-phenylbutane-1,3-dione (benzoyl-trifluoroacetone) can effectively photostabilize photodegradation of polyisoprene in solutions containing protonic solvents (alcohols). The photostabilization mechanism is due to the photo-enolization reaction, during which absorbed UV radiation is consumed for the proceeding of this reaction. The photostabilization of formulations containing alcohol by -dicarbonyl compounds, has potential application in the protection of cosmetics against photoageing reaction.     

The optical properties of hot-pressed magnesium fluoride and single-crystal magnesium fluoride in the 0.1 to 9.0 μm range

A polycrystalline high-density magnesium fluoride, fabricated into plates or shapes by hot-pressing, exhibits high in-line transmittance from 2.5 to 6.0 m, and single-crystal magnesium fluoride extends from 0.1 to 6.0 m. The ultimate and practical transmittance of hot-pressed magnesium fluoride using intrinsic and extrinsic reflectance, absorptance and scattering mechanisms, are investigated. The intrinsic scattering mechanism due to the polycrystalline structure is basically responsible for the tremendous difference in transmittance in the short wavelength region of the spectrum. The in-line transmittance of polycrystalline and singlecrystal MgF₂ is discussed in terms of sample thickness.     

Modeling and Control of Hybrid-driven Gliding Motion for an Underwater Gliding Snake-like Robot

International Journal of Control, Automation and Systems - An underwater gliding snake-like robot (UGSR) combines the advantages of an underwater glider (UG) and an underwater snake-like robot...     

Reaction mechanism and microstructure evolution of reaction sintered <Emphasis Type="Italic">h</Emphasis>-BN

Hexagonal boron nitride ceramic (h-BN) based on the nitridation of B powders was obtained by reaction sintering method. The effects of sintering temperature on the mechanical properties and microstructure of the resultant products were investigated and the reaction mechanism was discussed. Results showed that the reaction between B and N₂ occurred vigorously at temperatures ranging from 1 000 °C to 1 300 °C, which resulted in the generation of t-BN. When the temperature exceeded 1 450 °C, transformation from t-BN to h-BN began to occur. As the sintering temperature increased, the spherical particles of t-BN gradually transformed into fine sheet particles of h-BN. These particles subsequently displayed a compact arrangement to achieve a more uniform microstructure, thereby increasing the strength.     

Modal Identification of Linear Time-varying Systems Using Continuous Wavelet Transform

A wavelet based identification method for linear time-varying systems is presented,and the ridge and skeleton of the continuous wavelet transform of free response is used to extract time-varying parameters. The stiffness and damping coefficients of single-degree-of—freedom systems,frequencies and damping ratios of multi-degree-of-freedom systems are estimated without any prior information of systems. The proposed method is applied to linear time-varying systems with both abrupt and smooth variation parameters. Gaussian white noise is added to the response to test the anti-noise performance of the algorithm. The simulation results show that the proposed method is capable of accurately tracking the variation of the systems.