玻纤增强复合材料及其复合绝缘横担覆冰特性研究

为了指导复合材料横担在重冰区的应用,本文开展了玻纤增强复合材料及复合材料绝缘横担的覆冰特性研究.结果表明:空白样品在垂直悬挂方式下的覆冰量和冰闪络电压均优于水平悬挂样品,且覆冰量均少于对应的亲水性的纯铝棒和Q345钢棒;涂覆PRTV涂料的复合材料样品覆冰量比空白样品少,对应的闪络电压大幅提升,且对应样品的冰面粘附力值最小,为纯铝棒冰面粘附力值的19％,而空白样品的冰面粘附力值为纯铝棒的78％.硅橡胶复合绝缘横担的覆冰特性正好和复合材料试样相反,水平悬挂方式下复合绝缘横担覆冰量相比垂直悬挂的同规格复合绝缘子减少了30％,闪络电压提高了51％.     

模具敏捷制造系统研究

针对模具设计制造过程复杂、条件苛刻和单件或小批量生产的特点 ,论述了模具产业发展敏捷制造技术的必要性。提出了模具敏捷制造系统框架和基于STEP与特征技术实现信息集成与过程集成的运行机制。阐述了基于Internet/Intranet的开放式可视化协同工作平台的模具敏捷制造实施方案。     

Effect of supports on the redox performance of pyrite cinder in chemical looping combustion

Chemical looping combustion (CLC) is a clean and efficient flame-free combustion technology,which combust the fuels by lattice oxygen from a solid oxygen carrier with inherent CO2 capture.The develop-ment of oxygen carriers with low cost and high redox performance is crucial to the whole efficiency of CLC process.As the solid by-product from the sulfuric acid production,pyrite cinder presented excellent redox performance as an oxygen carrier in CLC process.The main components in pyrite cinder are Fe2O3,CaSO4,Al2O3 and SiO2 in which Fe2O3 is the active component to provide lattice oxygen.In order to sys-tematic investigate the functions of supports (CaSO4,Al2O3 and SiO2) in pyrite cinder,three oxygen car-riers (Fe2O3-CaSO4,Fe2O3-Al2O3 and Fe2O3-SiO2) were prepared and evaluated in this study.The results showed that Fe2O3-CaSO4 displayed high redox activity and cycling stability in the multiple redox cycles.However,both Fe2O3-Al2O3 and Fe2O3-SiO2 experienced serious deactivation during redox reactions.It indicated that the inert Fe-Si solid solution (Fe2SiO4) was formed in the spent Fe2O3-SiO2 sample,which decreased the oxygen carrying capacity of this sample.The XPS results showed that the oxygen species on the surface of Fe2O3-CaSO4 could be fully recovered after the 20 redox cycles.It can be concluded that CaSO4 is the key to the high redox activity and cycling stability of pyrite cinder.     

PAN/FPU Composite Nanofiber Membrane with Superhydrophobic and Superoleophobic Surface as a Filter Element for High-Efficiency Protective Masks

Recently, because of the outbreak of COVID-19, the demand for various types of filter elements in protective materials has increased globally. Furthermore, new requirements for the filtration performance of PM2.5 liquid (oil) particles have been put forward. In this work, Superhydrophobic and superoleophobic composite nanofibers with excellent filtration capacity for oil and salt particles are developed through the modification of polyacrylonitrile (PAN) by fluoro-polyurethane (FPU) doping. The results show that the PAN/FPU composite nanofibers doped with 9 wt% FPU has a uniform fiber morphology with a diameter of 240 ± 30 nm. Compared to the pure PAN nanofibers, the water-based contact angle of PAN/FPU increases from 90 ± 5° to 151 ± 5°, and the oil-based contact angle increases from 58 ± 2° to 152 ± 3°. Importantly, at a high flow rate of 95 L min⁻¹, the filtration efficiency of the PAN/FPU nanofiber membrane for 0.3 µm oil particles increases from 92 ± 1% to 99.2 ± 0.1%. After cyclic loading, the filtration efficiency of 0.3 µm oil particles remains above 98%. Meanwhile, the filtration efficiency for 0.3 µm salt particles remains at 98.23 ± 0.1%. The PAN/FPU nanofiber membrane developed in this work is effective in applications and has good market prospects as a protective filtration material.     

粉煤灰高附加值利用研究进展

粉煤灰是火电厂燃煤过程中产生的固体残渣, 其成分复杂, 具有毒性, 若处理不当会对环境造成危害。因此, 粉煤灰的高附加值利用迫在眉睫。然而, 粉煤灰的品质是制约其高附加值利用的主要因素。目前, 中国粉煤灰品质参差不齐, 缺少完善的品质评价体系, 由此造成粉煤灰利用领域的局限性。针对上述问题, 首先分析了中国粉煤灰的资源化特性, 总结了粉煤灰的品质评价方法, 并重点阐述了适用于粉煤灰高附加值利用的品质评价方法;其次, 详细介绍了粉煤灰高附加值利用技术（高附加值提取技术、高附加值材料制备技术）;最后, 对粉煤灰高附加值利用的发展趋势做出了展望。     

CHARAC TERIZATION OF TiAl POWDER PRODUCED BY MECHANICAL ALLOYING

The microstructure,alloying reaction and sintering behavior of the powder produced by Mechanical Al-loying(MA)for 8 h from 64 wt.-% Ti powder and 36 wt.-% Al powder were studied by scanning electronmicroscopy,optical microscopy,X-ray diffractometry,differential scanning calorimetry(DSC)and dilatometry.The mechanically alloyed powder partictes are Ti-Al composite particles.Thus,titanium aluminides can formeasily in the powder through diffusion during heat treatment.It is shown that the sintering behavior of this pow-der,different from the behaviors of TiAl alloy powder and mixed powder of 64 wt.-% Ti powder and 36 wt.-%Al powder,changes from expansion at temperatures below 1000℃ to shrinkage at temperatures above 1000℃.Homogeneously alloyed TiAl material with a density over 96% of the theoretical density can be produced fromthe mechanically alloyed powder by compaction-sintering.     

高功率锂离子电池研究进展

高功率快放型锂离子电池是目前锂离子电池领域研究的重点方向之一。为了获得具有高功率密度的锂离子电池,正极材料须具有较高的电压和较高的电子与离子导电率,正极材料主要包括高电压钴酸锂、镍锰酸锂和高电压三元材料,负极材料包括碳系材料、钛基材料和金属氧化物材料,以及为提高首效和降低负极电位而采用的预嵌锂方法,并对锂离子电池电解液用锂盐、溶剂和添加剂进行了综述。最终总结了功率密度测试方法,并对高功率锂离子电池的研究进行展望。      

青海某微细粒浸染型难处理金矿石工艺矿物学研究

采用显微镜、X射线衍射仪、化学分析等多种手段,对青海某金矿石进行了工艺矿物学研究,查明矿石中矿物组成、主要矿物嵌布状态、嵌布粒度等。结果表明：矿石中主要有价元素为金,伴生低品位银,金品位4.20 g/t、银品位<2.0 g/t、碳品位1.17%、硫品位1.92%,属微细粒—超微细粒浸染型高碳低硫极难处理金矿石;金主要以微细粒、超微细粒包裹于毒砂和黄铁矿中,部分以单体金形式嵌布于脉石矿物中;毒砂、黄铁矿嵌布粒度较粗,硫化矿物包裹金可通过初步磨矿达到回收效果,脉石矿物中金则需要进一步磨矿进行回收。     

基于地质勘查技术的矿山环境地质灾害预防探析

中国矿产资源总量庞大,很多矿产资源开采难度较高,勘查和解决好矿山环境地质灾害,是从业人员面临的难题之一。简述了利用地质勘查技术勘查矿山环境地质灾害的重要性,分析了典型矿山环境地质灾害类型,介绍了先进地质勘查技术,并给出了相关技术支撑下的矿山环境地质灾害预防对策,以提升矿山资源开采安全性。     

低压铸造三维温度场的冷却边界条件处理

低压铸造模具结构比较复杂，存在多处冷却系统对模具进行强制冷却。对低压铸造的多种类型的界面根据其换热的特点作了大致分类。针对每种情况，考虑了冷却介质和冷却管道的个性参数，建立了相应的计算模型，并编制计算程序对实际铸件进行了模拟计算。