In-line optical fiber sensors based on cladded multimode tapered fibers

The use of uniform-waist cladded multimode tapered optical fibers is demonstrated for evanescent wave spectroscopy and sensors. The tapering is a simple, low-loss process and consists of stretching the fiber while it is being heated with an oscillating flame torch. As examples, a refractive-index sensor and a hydrogen sensor are demonstrated by use of a conventional graded-index multimode optical fiber. Also, absorbance spectra are measured while the tapers are immersed in an absorbing liquid. It is found experimentally that the uniform waist is the part of the taper that contributes most to the sensor sensitivity. The taper waist diameter may also be used to adjust the sensor dynamic range.     

Assessing changes in the meaning of children's behavior: Factorial invariance of teachers' temperament ratings.

Tested the assumption that the same behavioral rating scale may be used over a wide age range, using temperament ratings provided by 24 teachers of 564 kindergarten through 4th-grade children. A LISREL analysis supported the hypothesized 3-factor model and established factorial invariance. The consistency of the factor structure over grade and the similarity of this structure to the findings from other factor analytic studies suggest that teachers may organize information about student behavior along the same dimensions regardless of the grade they teach. Such invariance may result from the demands of the teaching task rather than actual covariation among student behaviors. (40 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Influence of aeration on hydrophobic organic contaminant distribution and diffusive flux in estuarine sediments

Dredging operations, resuspension events during storms, and bioturbation alter the oxic state of estuarine sediments and induce changes in the composition of dissolved and particle-associated natural organic matter. These changes may alter the distribution of hydrophobic organic chemicals (HOCs) in sediments and their diffusive flux across the sediment-water interface. In this study, the impact of aerating anoxic sediments on the distribution and diffusive flux of a model HOC, 2,2',4,4'-tetrachlorobiphenyl (TeCB), was investigated. Anoxic estuarine sediments collected from three sites along a salinity gradient were used to determine site-specific apparent sorption coefficients for porewater dissolved organic carbon (Kpwdoc) and sediment organic carbon (Koc) under anoxic and oxic conditions. A two-compartment sediment flux model was employed to examine the diffusive flux of TeCB under both oxic states. Aeration of anoxic porewaters resulted in significant decreases in porewater dissolved organic matter (DOMpw) aromaticity as indicated by declines in molar absorptivity at 254 nm (p < 0.005). Aeration also resulted in a 9-13% decrease in DOMpw concentration (p < 0.005) at the two sites exhibiting lower ionic strengths; the high ionic strength site did not exhibit a significant change in DOMpw concentration (p > 0.10). The impact of aeration on TeCB distribution and diffusive flux appeared to be site-specific. Aeration of anoxic sediments induced a significant 1.4 log unit reduction in Kpwdoc at the lowest ionic strength site (p < 0.0005), while sediments from the intermediate ionic strength site exhibited a significant 0.6 log unit increase (p < 0.005). No significant change in sorption to DOMpw was observed for the high ionic strength site (p > 0.10). The sediment displaying the drop in Kpwdoc also exhibited a significant 0.4 log unit drop in Koc (p < 0.01), while the other two sites did not exhibit significant aeration-induced changes in sorption to particle-associated organic matter (p > 0.10). No significant change in diffusive flux was observed for two sites (p > 0.10), while a significant 89-110 mg m(-2) yr(-1) increase in diffusive flux was observed at the low ionic strength site (p < 0.10). This latter result represented approximately a doubling in diffusive flux. In the systems studied, facilitation of TeCB transport across the sediment-water interface by organic colloids did not appear important.     

Monitoring the formation and decay of transient photosensitized intermediates using pump-probe UV resonance Raman spectroscopy. I: Self-modeling curve resolution

Resolution of transient excited-state Raman scattering from ground-state and solvent bands is a challenging spectroscopic measurement since excited-state spectral features are often of low intensity, overlapping the dominant ground-state and solvent bands. The Raman spectra of these intermediates can be resolved, however, by acquiring time-resolved data and using multidimensional data analysis methods. In the absence of a physical model describing the kinetic behavior of a reaction, resolution of the pure-component spectra from these data can be accomplished using self-modeling curve resolution, a factor analysis technique that relies on the correlation in the data along a changing composition dimension to resolve the component spectra. A two-laser UV pump-probe resonance-enhanced Raman instrument was utilized to monitor the kinetics of amine quenching of excited-triplet states of benzophenone. The formation and decay of transient intermediates were monitored over time, from 15 ns to 100 micros. Factor analysis of the time-resolved spectral data identified three significant components in the data. The time-resolved intensities at each Raman wavenumber shift were projected onto the three significant eigenvectors, and least-squares criteria were developed to find the common plane in the space of the eigenvectors that includes the observed data. Within that plane, the three pure-component spectra were resolved using geometric criteria of convex hull analysis. The resolved spectra were found to arise from benzophenone excited-triplet states, diphenylketyl radicals, and the solvent and ground-state benzophenone.     

Influence of the storage orientation on the aerodynamic particle size of a suspension metered dose inhaler containing propellant HFA-227

Presented in this work are the results of a study designed to investigate the impact of the storage position on the particle size distribution (PSD) of a steroid suspension metered dose inhaler (MDI) containing propellant HFA-227. It was hypothesized that the orientation of MDI samples upon storage could influence the PSD of the emitted dose, since it determines the amount of contact the liquid formulation has with the valve and therefore the quantity of nonvolatile leachable materials from the valve components that may enter the product and potentially impact the aerosol spray dynamics. Samples stored in the valve down orientation (i.e., complete contact of the liquid formulation with the valve) showed a higher level of leachables compared to those samples stored valve up (i.e., minimal contact of the formulation with the valve). The valve down samples were found to produce larger particles in the emitted aerosol spray using both cascade impaction, the preferred method of regulatory submission, as well as laser diffraction. It was postulated that the larger particle size of the inverted samples was attributed to its higher levels of leachables. Based on our findings, it is recommended that in order to set appropriate controls on the product PSD, the storage orientation of the product will need to be considered.     

A practical approach to fire hazard analysis for offshore structures

Offshore quantitative risk assessments (QRA) have historically been complex and costly. For large offshore design projects, the level of detail required for a QRA is often not available until well into the detailed design phase of the project. In these cases, the QRA may be unable to provide timely hazard understanding. As a result, the risk reduction measures identified often come too late to allow for cost effective changes to be implemented. This forces project management to make a number of difficult or costly decisions. This paper demonstrates how a scenario-based approached to fire risk assessment can be effectively applied early in a project's development. The scenario or design basis fire approach calculates the consequence of a select number of credible fire scenarios, determines the potential impact on the platform process equipment, structural members, egress routes, safety systems, and determines the effectiveness of potential options for mitigation. The early provision of hazard data allows the project team to select an optimum design that is safe and will meet corporate or regulatory risk criteria later in the project cycle. The focus of this paper is on the application of the scenario-based approach to gas jet fires. This paper draws on recent experience in the Gulf of Mexico (GOM) and other areas to outline an approach to fire hazard analysis and fire hazard management for deep-water structures. The methods presented will include discussions from the recent June 2002 International Workshop for Fire Loading and Response.     

Measurement: a beginner's guide

This paper provides an introduction to measurement theory for psychometricians. The central concept in measurement theory is that of a continuous quantitative attribute and explaining what measurement is requires showing how this central concept leads on to those of ratio and real number and distinguishing measurements from measures. These distinctions made, the logic of quantification is described with particular emphasis upon the scientific task of quantification, as opposed to the instrumental task. The position presented is that measurement is the estimation of the magnitude of a quantitative attribute relative to a unit and that quantification is always contingent upon first attempting the scientific task of acquiring evidence that the relevant attribute is quantitative in structure. This position means that the definition of measurement usually given in psychology is incorrect and that psychologists' claims about being able to already measure psychological attributes must be seriously questioned. Just how the scientific task of investigating whether psychological attributes are quantitative may be undertaken in psychology is then considered and the corollary that psychological attributes may not actually be quantitative is raised.     

Investigation of mixed convection in a large rectangular enclosure

This experimental research investigates mixed convection and heat transfer augmentation by gaseous forced jets in a large enclosure, at conditions simulating those of passive containment cooling systems for Gen III+ passively safe reactors. The experiment is designed to measure the key parameters governing heat transfer augmentation by forced jets, and to investigate the effects of geometric factors, including the jet diameter, jet injection orientation, interior structures, and enclosure aspect ratio. The tests cover a variety of injection modes leading to flow configurations of interest for mixing and stratification phenomena in containments under accident conditions. Correlations for heat transfer augmentation by forced jets are developed and compared with experimental data. The characteristic recirculation speed inside the enclosure is introduced and analyzed. Steady stratified temperature distributions are compared with model simulations of the BMIX++ code.     

Stability and variability of affective experience and interpersonal behavior in borderline personality disorder.

This study examined both mean levels and intraindividual variability in the mood and interpersonal behavior of individuals with borderline personality disorder (BPD) and nonclinical control participants over a 20-day event-contingent recording period. Individuals in the BPD group experienced more unpleasantly valenced affect and were less dominant, more submissive, more quarrelsome, and more extreme in overall levels of behavior than control participants. In addition to these mean-level differences, individuals with BPD also reported more intraindividual variability in overall affect valence and in pleasantly valenced affect; displayed greater variability in dominant, quarrelsome, and agreeable behaviors; and exhibited an increased tendency to "spin" among interpersonal behaviors relative to nonclinical control participants. The findings document behavioral and affective manifestations of BPD in the context of naturally occurring interpersonal situations. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Age differences in item manipulation span: The case of letter-number sequencing.

The authors report 2 experiments in which they examined age differences in working memory tasks involving complex item manipulation (i.e., letter-number sequencing). In Experiment 1, age differences on tasks involving item manipulation were not greater than age differences on tasks requiring recall of items in the order in which they appeared, suggesting that older adults do not have difficulty with item manipulation per se. In Experiment 2, slower presentation rates increased age differences in item manipulation spans, although age differences at the fastest rate may be attributed to differences in strategy use. In both experiments, age differences were largest when participants were most likely to be remembering familiar sequences, suggesting that older adults may have difficulties dampening the representations of such sequences once they are activated. (PsycINFO Database Record (c) 2010 APA, all rights reserved)