Glow discharge techniques in the chemical analysis of photovoltaic materials

The presented study gives an integrated overview on the prospects of glow discharge (GD) methods in the chemical analysis of photovoltaic materials. With a focus on recent research and important photovoltaic (PV) materials, the GD coupled analytical methods, high resolution mass spectrometry (MS), time‐of‐flight‐mass spectrometry (TOF‐MS) and optical emission spectrometry (OES) are discussed. Each exemplary study carried out will point out the most suitable GD technique for the problem at hand, at the same time showing ways to increase analytical accuracy and to overcome typical instrumental restrictions. Challenging GD‐MS analyses of thin and ultra thin films (down to 20 nm) as well as GD‐MS and GD‐OES studies of ready‐to‐use modules were carried out, showing the reader the application potential of GD methods in a PV development or production process. For the first time, novel cell concepts based on crystalline silicon on glass and silicon nanowires are analyzed by GD‐OES, revealing precise chemical information on the devices. Copyright © 2012 John Wiley & Sons, Ltd.     

A method for determining buildings’ material composition prior to demolition

A prerequisite of the efficient recycling of demolition waste and its evaluation in terms of the material specific recycling rates is information on the composition of the building material stock (as the source of future demolition waste). A practical method is presented that characterizes the material composition of buildings prior to their demolition. The characterization method is based on the analysis of available construction documents and different approaches of on-site investigation. The method is tested in different buildings and the results from four case studies indicate that the documents are useful to quantify bulk materials (e.g. bricks, concrete, sand/gravel, iron/steel and timber). However, on-site investigations are necessary to locate and determine the trace materials such as metals (e.g. copper and aluminium), or different types of plastics. The overall material intensity of the investigated buildings ranges from 270 to 470?kg/m³ gross volume. With ongoing surveys about the composition of different buildings, the collected data will be used to establish a building-specific database about the amount of materials contained in Vienna's building stock.     

Studying Organizational Creativity as Process: Fluidity or Duality?

This paper contributes to process studies on organizational creativity by developing two competing research agendas. The first perspective, the ‘becoming’ view, depicts creativity as a constant flow of activity that crystallizes every once in a while in unpredictable moments of creativity. The second perspective, the ‘practice’ view, understands creativity as a practised social process, in which structures play the important role of both enabling and constraining individual agents in pursuing creativity as a collective phenomenon. We compare and contrast these two theoretical perspectives, which are based on different process ontologies, and discuss their methodological implications. We argue that the practice perspective offers particular promise, because it allows us to address the important yet paradoxical question of how creativity may be organized and managed.     

A Generalization of Short-Cut Fusion and its Correctness Proof

Short-cut fusion is a program transformation technique that uses a single, local transformation—called the foldr-build rule—to remove certain intermediate lists from modularly constructed functional programs. Arguments that short-cut fusion is correct typically appeal either to intuition or to free theorems—even though the latter have not been known to hold for the languages supporting higher-order polymorphic functions and fixed point recursion in which short-cut fusion is usually applied. In this paper we use Pitts' recent demonstration that contextual equivalence in such languages is relationally parametric to prove that programs in them which have undergone short-cut fusion are contextually equivalent to their unfused counterparts. For each algebraic data type we then define a generalization of build which constructs substitution instances of its associated data structures, and use Pitts' techniques to prove the correctness of a contextual equivalence-preserving fusion rule which generalizes short-cut fusion. These rules optimize compositions of functions that uniformly consume algebraic data structures with functions that uniformly produce substitution instances of those data sructures.     

优化负荷及发电管理

热电系统或水-热电系统的运营商对运营进行长远规划,从而确定自身发电及采用其他可利用能源的供应量,如以合同形式采购能源.该计划的目的是最小化电力系统的运行成本,或最大化利润.     

Privacy4DRM: Nutzer-und datenschutz-freundliches Digital Rights Management

Zusammenfassung  Die DRM-Diskussion ist festgefahren: Weil die Verwertungsindustrie ihre digitalen Rechte mit Hilfe von Technik und staatlichem Zwang zu verteidigen versucht, verweigern sich die Nutzer. Diese Blockade ist nur aufzul?sen, wenn die digitalen Rechte der Urheber auch an den Interessen der Nutzer und damit dem Datenschutz ausgerichtet werden.     

Spectroscopic ellipsometry of anisotropic materials: application to the optical constants of HgI2

A variable angle-of-incidence spectroscopic fixed-polarizer, rotating-polarizer, fixed-analyzer ellipsometer (PRPSE) across a spectral range from 300 to 800 nm is used to determine the optical properties of anisotropic uniaxial tetragonal red mercuric iodide (HgI(2)). For the first time, to our knowledge, the bulk crystal HgI(2) surface measured by ellipsometry was not subjected to potassium iodide cutting or etching. Measurements were made at an air-HgI(2) interface with the optic axis parallel to the sample surface. To determine the optical constants, we varied both the angle of incidence and the azimuth of the optic axis with the plane of incidence. The detailed formulas needed for reliable procedures for analyzing the data are presented. The ordinary and extraordinary complex indices of refraction, (n(o) - ik(o)) and (n(e) - ik(e)), respectively, are determined. Good agreement between PRPSE and the prism technique for the refractive index is observed. The surface aging effects of the ellipsometric parameters of HgI(2), during 30 h of exposure to air, were detected by PRPSE.